%nprocshared=12
%mem=22GB
#p opt freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024) 

opt freq

1 1
  C          -0.24816199492683     -4.03718370423105      0.07531797618484
  C           0.29353965810008     -3.36956169164537      1.20771819893844
  C           0.66247098515440     -2.06092674956866      1.10247281595361
  C           0.50686577847646     -1.35326045719231     -0.14545130090713
  C          -0.04438399529132     -2.05532094595335     -1.27631617653963
  C          -0.41353025413007     -3.36581587095523     -1.16728380158841
  H           0.39822879330152     -3.93116588340860      2.13742182979072
  H           1.08180649382902     -1.52985891991777      1.95997036231636
  H          -0.16187523186879     -1.52144851314999     -2.22209994054456
  H          -0.83366802777621     -3.90146367762556     -2.02258297855429
  C           0.86150343265962     -0.05244565761817     -0.25216486508089
  H           2.26965084203563      1.33245873806597     -0.66163293270024
  C           0.41164788250463      2.40174086245899     -0.11413447850244
  C          -0.93560377626121      2.31793716744783      0.26853238875674
  C           1.01344751216929      3.65553100351387     -0.27462510778104
  C          -1.66724748286883      3.47771267505671      0.48706291347261
  H          -1.41387301937117      1.34211630077617      0.39464280605738
  C           0.27474022508589      4.81506207883720     -0.05359334844516
  H           2.06284840182296      3.72585116445247     -0.57246619424420
  C          -1.06265403590306      4.72704228656081      0.32638116823027
  H          -2.71589936556226      3.41142787634555      0.78442245681130
  H           0.74753810430641      5.79137004812693     -0.17846283667414
  H          -1.64112816178523      5.63721576575403      0.49945067787137
  C           1.22129880947466      1.19250800533582     -0.35501082749907
  O          -0.58129885564960     -5.28989609015521      0.24152922134217
  H          -0.94254471752601     -5.69348202131106     -0.56043477666460





