%nprocshared=12
%mem=22GB
#p opt freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024) 

opt freq

1 1
  C          -0.06533576055681     -3.60275314879266     -0.11393170756980
  C           0.31011202872814     -2.96903263001284      1.09009309095175
  C           0.64252318058931     -1.63716841185950      1.06773630364751
  C           0.60654501194619     -0.90551177923552     -0.16604248609133
  C           0.22118597480923     -1.57944119609903     -1.37279871536070
  C          -0.11027042472074     -2.91136075836899     -1.34362830760498
  H           0.33013694732522     -3.54430242959300      2.01705305734305
  H           0.93670439211408     -1.11989463979237      1.98382458836863
  H           0.19567418315010     -1.01846976290358     -2.30983247698151
  H          -0.40609241159640     -3.44361800006625     -2.24901225164416
  C           0.92535709866216      0.41792968469208     -0.19012333068604
  H           2.32793031361952      1.83757167567137     -0.40115563860578
  C           0.39637453070536      2.86034544505370     -0.04606891979293
  C          -0.98062814112423      2.73927585391588      0.19584911910976
  C           0.98325030393856      4.12879777856195     -0.12932383007098
  C          -1.75752580832204      3.87928271462872      0.35136232543236
  H          -1.44654707512884      1.75171228028529      0.26309860715150
  C           0.19794596896728      5.26776656243411      0.02741738983030
  H           2.05558991918638      4.22781053925575     -0.31665701786088
  C          -1.16893490052476      5.14380051416256      0.26680732186351
  H          -2.82907891467232      3.78488715091947      0.53903790295579
  H           0.65748011273839      6.25602775264915     -0.03831789381707
  H          -1.78345290238785      6.03847131263496      0.38898055222640
  C           1.25301983383596      1.67310033720979     -0.21890408358326
  Cl         -0.47713598128189     -5.24794771535110     -0.08262094921114





