%nprocshared=12
%mem=22GB
#p opt freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024) 

opt freq

1 1
  C           0.01698255026830     -3.24408157521158      0.02504755376523
  C           0.94182664999175     -2.50967053782131      0.85831505053127
  C           1.18234840252606     -1.19323307396919      0.63516198540062
  C           0.52199754359682     -0.47715811104276     -0.43584212325459
  C          -0.40597427196644     -1.21906510277002     -1.26285171495354
  C          -0.64737652026062     -2.53640042683308     -1.04591279041335
  H           1.45573337063241     -3.01040076570785      1.67691447380135
  H           1.88308148907451     -0.64689773148857      1.27052078442825
  H          -0.91341872824573     -0.69489040047442     -2.07582383807391
  H          -1.35070691598361     -3.05933406539733     -1.69142304568534
  C           0.75934276908336      0.82734663831538     -0.64772813436841
  H           1.82804359926790      2.29820824063562     -1.55223353812821
  C           0.31116888062602      3.24917188322764     -0.25588315878913
  C          -0.73085502233321      3.08568739664697      0.66856336965856
  C           0.71308710853489      4.53849852876864     -0.62350491648560
  C          -1.35801879796753      4.19826387204670      1.21477404635394
  H          -1.05023822025064      2.08179662647941      0.96344443958531
  C           0.08101328971818      5.65131649763337     -0.07377115139104
  H           1.52424409162465      4.67391451887219     -1.34387276647030
  C          -0.95267108186509      5.48275668604035      0.84457945923169
  H          -2.16731517055104      4.06587379708299      1.93614564421755
  H           0.39919691362330      6.65463984331257     -0.36473152045123
  H          -1.44593524361806      6.35586635447846      1.27759539422286
  C           1.00495315795279      2.09030431460433     -0.85315549797046
  N          -0.21710094849547     -4.53424795409763      0.23772730138582
  C           0.45287487502747     -5.25140531332888      1.32298535855383
  C          -1.15517594050635     -5.27782525520112     -0.60382130491351
  H           0.13423251856464     -6.29784571701033      1.30857617143221
  H           1.54500878109550     -5.22452586871098      1.19852769480769
  H           0.18642208677438     -4.82497442283149      2.30117000150892
  H          -1.19776742368178     -6.31515781288260     -0.25919535685519
  H          -2.16699572785185     -4.85211759827649     -0.53757675797012
  H          -0.82810032440553     -5.27843409508896     -1.65373975271117





