%nprocshared=12
%mem=22GB
#p opt freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024) 

opt freq

1 1
  C          -0.29471429847082     -3.74686559921190     -0.87284084114471
  C          -0.01916028269666     -3.27329757232981      0.42610278408712
  C           0.36868815883373     -1.96197426366682      0.60233586869587
  C           0.48348793893028     -1.10147652062791     -0.53654488325221
  C           0.19618436767501     -1.60905064799197     -1.84487941353309
  C          -0.18960520203601     -2.92592003610326     -2.00117133082597
  H           0.58965111524239     -1.56491049864381      1.59768363874677
  H           0.28782451427962     -0.93985627493772     -2.70372704199016
  H          -0.41033546473896     -3.32491263094100     -2.99277881752902
  C           0.85572543823121      0.20351261254835     -0.37543633197982
  H           2.33138038116075      1.55108816919865     -0.28962357687575
  C           0.42615520932144      2.64175280025883      0.01022178381473
  C          -0.97269018074217      2.57473443496961      0.10389143656234
  C           1.07992532202161      3.87305470234386      0.14146905885722
  C          -1.70524304519065      3.73238003992178      0.32745391227250
  H          -1.48997531063806      1.61608392765825      0.00235369958862
  C           0.33820732517699      5.02974357212650      0.36557738427480
  H           2.16907175979576      3.92933887617224      0.06836676313238
  C          -1.05023079467648      4.95984895076772      0.45853680924663
  H          -2.79348446424909      3.68112825551551      0.40082535043862
  H           0.84831834616297      5.98970838360247      0.46726494903798
  H          -1.63018851364206      5.86847317699776      0.63468499312195
  C           1.23613962933547      1.43360170047048     -0.22542019896229
  H          -0.59850992290917     -4.79463003223839     -0.96956695129768
  C          -0.15761384085660     -4.22019389520404      1.58714421964552
  O          -0.49440041718711     -5.35929746690794      1.43753822917574
  H           0.07235497186662     -3.79160250374746      2.59094036669193





