%nprocshared=12
%mem=22GB
#p opt freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024) 

opt freq

1 1
  C           0.10007477545671     -3.29512313898097      0.39013522955294
  C           0.43289667063283     -2.51738306504468      1.53228737689590
  C           0.72002971286307     -1.18409549207348      1.41724841058080
  C           0.68902921395528     -0.54867357699396      0.12767814848409
  C           0.34473389455969     -1.33896466543015     -1.02404877801584
  C           0.05888389465148     -2.66996158627144     -0.88718054364438
  H           0.46009782794417     -3.00021283242633      2.51107989846054
  H           0.97806870024869     -0.58621268819058      2.29429981730044
  H           0.31783498403538     -0.85717541217655     -2.00402545585664
  H          -0.19925813480692     -3.25438258878319     -1.77251744374862
  C           0.98164043282897      0.76810738381822      0.00058109102778
  H           2.36662649199846      2.20024691000767     -0.28900635863038
  C           0.40698557817852      3.20217990473188     -0.06268751631465
  C          -0.97780052838486      3.07086741356719      0.11954372385628
  C           0.97450136724337      4.47495240403565     -0.19530386262900
  C          -1.78050961745231      4.20315107361489      0.16720810203939
  H          -1.42978227856551      2.07990348679614      0.22215594765024
  C           0.16454054476981      5.60654393721407     -0.14591358095642
  H           2.05301018019418      4.58279838286741     -0.33711906265927
  C          -1.21021985498301      5.47165131325783      0.03449366209740
  H          -2.85844853875093      4.09908527113927      0.30769804772742
  H           0.61117463384685      6.59759766438020     -0.24919020067036
  H          -1.84437472879202      6.36028206669604      0.07135439317894
  C           1.29252166554512      2.02375624336908     -0.12046627237685
  C          -0.18555823507890     -4.71618768907733      0.56663537676162
  C          -1.22206094870424     -5.42117691132213     -0.30746270965657
  C           0.20579243283577     -5.72727871414258     -0.51079474601039
  H          -0.11484008990183     -5.06622390286970      1.59886623157336
  H          -1.74921935191315     -4.81393520409614     -1.04805809920293
  H          -1.85288944827986     -6.14712060694361      0.21015574457793
  H           0.60463375952758     -6.67434852865666     -0.14079032559586
  H           0.71321562429761     -5.34020539201602     -1.39829260579688





