%nprocshared=12
%mem=22GB
#p opt freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024) 

opt freq

1 1
  C          -0.20804057741327     -4.11589148717589     -0.57525223277151
  C          -0.29772659393969     -3.57468725479519      0.72311691989450
  C           0.06347368353007     -2.24703154300232      0.91318579075591
  C           0.50970323872895     -1.47210909699151     -0.19779771509614
  C           0.58962620156494     -2.04279237414089     -1.50588643003826
  C           0.22711094285064     -3.36402308861790     -1.67291328507975
  H           0.00330693141100     -1.80567126609520      1.90986371696242
  H           0.93184663766852     -1.43047528552682     -2.34203086212390
  H           0.27728704124915     -3.83307251155916     -2.65712229760112
  C           0.86008097237286     -0.16247689703769     -0.01053247893957
  H           2.29624781196971      1.16274210900951      0.40735692460702
  C           0.42085412811622      2.30277032933150      0.09857160887804
  C          -0.95331849404709      2.26452043209324     -0.18315741401207
  C           1.05772134910287      3.53000586369315      0.31861134587094
  C          -1.67825522985855      3.44698091134400     -0.24330772546606
  H          -1.45761127504325      1.30873174390212     -0.35319974368815
  C           0.32404408098586      4.71158929592445      0.25624327222330
  H           2.12777730801330      3.56318531081766      0.53900988616131
  C          -1.04010053482750      4.67055901146428     -0.02407859701445
  H          -2.74768142834684      3.41810843283282     -0.46194424005033
  H           0.82170579104682      5.66833191694192      0.42682002433571
  H          -1.61404333692537      5.59869397193810     -0.07157253059188
  C           1.22306933897283      1.06792971164327      0.16926292105510
  H          -0.48848756445791     -5.16286310013564     -0.73188742928541
  O          -0.71050280079449     -4.26875796433412      1.78363949995735
  H          -0.93794549192976     -5.17854522152366      1.56045057105698





