! wb97x-d3
! def2-TZVPP
! def2/J RIJCOSX GRIDX6 NOFINALGRIDX
! grid4 nofinalgrid
! scfconv7
! smallprint printgap noloewdin
! NOSOSCF
%MaxCore 8000
%output
       print[P_BondOrder_M] 1
       print[P_Mayer] 1
       print[P_basis] 2
end
%pal
    nprocs 8
end
%cpcm
    smd    true
    smdsolvent "WATER"
end
*xyz 0 1
Si  -2.5473255959   0.3735496911   0.0720058174
F    1.0435701280  -5.2610867439  -0.2013690207
O    0.3038669518   0.7050130426   1.4513529284
N    1.7917960281   2.3491133199  -0.3711874087
N    1.3362967453   3.1872758553  -1.3084459445
N    2.0764083357   4.3344889054   0.4731748129
C   -0.8460285668   0.7920390795  -0.6732515022
C    0.3934070274   0.3291999226   0.0926988925
C    1.7025785829   0.9136103486  -0.4965221339
C   -2.7036919290  -1.4100387066   0.6484665170
C   -3.7916646173   0.7002042987  -1.3051734219
C   -2.9276853310   1.5348682895   1.5095182900
C    0.5479619851  -1.1816686328   0.0368425919
C    0.7134215154  -1.9476307803   1.1865298825
C    0.5660997159  -1.8309588379  -1.1964399556
C    0.8771267882  -3.3245653549   1.1146631166
C    0.7326716658  -3.2041133013  -1.2888464940
C    2.2226760567   3.0476488669   0.6803639964
C    0.8831166959  -3.9293584227  -0.1240697141
C    1.5317499063   4.3573273526  -0.7566134696
H   -0.8260811602   1.8829182204  -0.7872063903
H   -0.8126761023   0.4142895502  -1.6986965738
H    1.8033958566   0.6608430373  -1.5502969343
H    2.5566776664   0.4856121979   0.0282671568
H   -3.7398028686  -1.6220802713   0.9236341789
H   -2.0855689254  -1.6116185873   1.5235299800
H   -2.4174646813  -2.1223946678  -0.1275616375
H   -4.8178810707   0.5617858022  -0.9571911230
H   -3.6397306368   0.0257201116  -2.1510988157
H   -3.7117629354   1.7213537811  -1.6850203714
H   -2.7457660955   2.5787547809   1.2414329571
H   -2.3368831882   1.3133122797   2.4000949713
H   -3.9789975425   1.4561883821   1.7975302776
H   -0.0708719042   1.5895475034   1.5108003716
H    0.7066654624  -1.4864006918   2.1633410252
H    0.4479554880  -1.2721310885  -2.1163023726
H    0.9967008983  -3.9127565180   2.0151954843
H    0.7452876306  -3.6962827061  -2.2524691520
H    2.6505263267   2.5863678602   1.5567623803
H    1.2700466082   5.2705471049  -1.2685034479
*