! wb97x-d3
! def2-TZVPP
! def2/J RIJCOSX GRIDX6 NOFINALGRIDX
! grid4 nofinalgrid
! scfconv7
! smallprint printgap noloewdin
! NOSOSCF
%MaxCore 8000
%output
       print[P_BondOrder_M] 1
       print[P_Mayer] 1
       print[P_basis] 2
end
%pal
    nprocs 8
end
%cpcm
    smd    true
    smdsolvent "WATER"
end
*xyz 0 1
Si  -3.1589645538  -0.1178184297  -0.0456192535
F    2.1252405774  -4.0760555158   0.4321586870
O   -0.5540454679   1.5149343648   0.9467739549
N    1.7745394225   2.0641499580  -0.5987300241
N    1.9549985500   3.1335132975   0.1805780759
N    3.7951086645   1.8494910122   0.1784950003
C   -1.7647090825   0.7531241101  -1.0028141214
C   -0.4073659602   0.9010408226  -0.3115621750
C    0.4999235891   1.7745555252  -1.2078795026
C   -4.6063558513  -0.1935167388  -1.2521953656
C   -3.6946407704   0.8702194483   1.4669527724
C   -2.7025774685  -1.8684753347   0.4754775173
C    0.2654547960  -0.4410839196  -0.0877257162
C    0.4021835701  -1.3353214999  -1.1480212508
C    0.7962746873  -0.7987126326   1.1470477271
C    1.0267467206  -2.5610431007  -0.9853524011
C    1.4240484071  -2.0239380096   1.3313274491
C    2.8717348861   1.3063535330  -0.5775782937
C    1.5237999322  -2.8864320875   0.2610736577
C    3.1757006488   2.9619176531   0.6152907641
H   -2.1348146236   1.7541990638  -1.2606318362
H   -1.6494447433   0.2460520726  -1.9650822273
H    0.0113062443   2.7255020648  -1.4200270701
H    0.6767387158   1.2818845038  -2.1633973029
H   -5.4835667180  -0.6564584305  -0.7951728669
H   -4.3589500913  -0.7735847738  -2.1438443238
H   -4.9020107075   0.8038337551  -1.5851929972
H   -4.6236075212   0.4648730533   1.8748100810
H   -3.8816558906   1.9178049908   1.2214843390
H   -2.9510145884   0.8442495454   2.2635804531
H   -3.5715960626  -2.3694877824   0.9093731266
H   -1.9077945214  -1.8861643521   1.2222291503
H   -2.3682992113  -2.4703059454  -0.3712873105
H   -1.0774317913   2.3164336514   0.8368664107
H    0.0177437952  -1.0892076400  -2.1298565108
H    0.7248329053  -0.1292472064   1.9914312364
H    1.1219262699  -3.2489388545  -1.8150425135
H    1.8293512023  -2.2967822942   2.2968465946
H    2.9640193321   0.3900673492  -1.1389398121
H    3.6447155147   3.6763204601   1.2735923897
*