Orca 5.0.4 RELEASE 1 2 3 4 5 8s4p2d 8s4p2d 4s2p 8s5p2d 7s6p5d 4s2p2d 4s2p2d 2s2p 4s3p2d 6s5p4d 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 C C C C C N C C C C H H H C N C C H C O C O N N C H H H C H H H C H H H C H H H Ce N O O O N O O O N O O O H H 1 1 1 1 1 2 1 1 1 1 3 3 3 1 2 1 1 3 1 4 1 4 2 2 1 3 3 3 1 3 3 3 1 3 3 3 1 3 3 3 5 2 4 4 4 2 4 4 4 2 4 4 4 3 3 1 Ce ECP 40 Ce 1 630.3489000000002 AuxInfo=1/0/N:25,29,33,37,7,8,1,14,2,17,3,9,4,16,5,10,19,21,6,15,23,24,20,22;41;42,43,44,45;46,47,48,49;50,51,52,53/E:(1,2,3,4)(5,6)(7,8)(9,10)(11,12)(13,14)(15,16)(17,18)(19,20)(21,22)(23,24);;3*(2,3,4)/CRV:5.3,6.3,7.3,8.3,9.3,10.3,11.3,12.3,13.3,14.3,15.3,16.3,17.3,18.3,19-1,20-1,23-1,24-1;;3*2.1,3-1,4-1/rA:55nC3C3C3C3C3NC3C3C3C3HHHC3NC3C3HC3OC3ONNCHHHCHHHCHHHCHHHCeNO1OONO1OONO1OOHH/rB:s1;s1;s2;s3;s4s5;s3;s7;s8;s5s9;s2;s7;s8;s9;s10;s15;s14s16;s17;s4;s19;s16;s21;s19;s21;s23;s25;s25;s25;s23;s29;s29;s29;s24;s33;s33;s33;s24;s37;s37;s37;s6s15s20s22;;s42;s41s42;s41s42;;s46;s41s46;s41s46;;s50;s41s50;s41s50;s14;s1;/rC:-.3925,-.452,-4.0632;-.522,.9117,-4.3032;-.3349,-.9349,-2.7323;-.6068,1.7954,-3.2009;-.409,.0357,-1.6862;-.5419,1.3558,-1.9378;-.173,-2.3243,-2.397;-.0576,-2.7288,-1.088;-.096,-1.7752,-.0123;-.2892,-.3905,-.306;-.5242,1.2957,-5.3293;-.1315,-3.057,-3.2145;.0779,-3.7905,-.8405;.0826,-2.1215,1.35;-.3304,.5532,.657;-.2137,.2047,1.9434;.026,-1.1373,2.3306;.1973,-1.3988,3.38;-.6096,3.303,-3.2901;.0231,3.9252,-2.3863;-.2479,1.3987,2.8678;.1286,2.5082,2.3858;-1.2395,3.9429,-4.2852;-.6556,1.2925,4.1421;-2.2166,3.3388,-5.1892;-1.7939,3.2206,-6.2053;-2.5636,2.3671,-4.8072;-3.0881,4.0155,-5.2479;-1.0997,5.3937,-4.3929;-.1661,5.7154,-3.9076;-1.0854,5.6647,-5.4632;-1.9589,5.8967,-3.9073;-1.3901,.1614,4.7079;-1.8308,-.4613,3.9152;-.7371,-.4521,5.3579;-2.213,.5684,5.3222;-.5237,2.4514,5.0234;-1.4819,3.0049,5.0748;-.2659,2.0907,6.0348;.265,3.1203,4.6476;-.3865,3.1657,.0042;2.6752,3.26,.0323;3.9063,3.2969,.0643;1.9644,4.2695,.3732;2.0445,2.2125,-.3426;-3.3982,2.7803,-.4988;-4.6101,2.6538,-.6917;-2.6931,3.5958,-1.1888;-2.7857,2.1036,.394;-1.5488,5.8644,.9567;-2.0451,6.9359,1.3168;-1.8524,4.7612,1.5284;-.7091,5.8037,-.0044;.2762,-3.168,1.623;-.3129,-1.159,-4.9004;/R:/0/N:25,29,33,37,7,8,1,14,2,17,3,9,4,16,5,10,19,21,41,23,24,6,15,42,46,50,43,47,51,20,22,44,45,48,49,52,53/E:(1,2,3,4)(5,6)(7,8)(9,10)(11,12)(13,14)(15,16)(17,18)(20,21)(22,23)(24,25,26)(27,28,29)(30,31)(32,33,34,35,36,37)/CRV:5.3,6.3,7.3,8.3,9.3,10.3,11.3,12.3,13.3,14.3,15.3,16.3,17.3,18.3,19.10,27.1,28.1,29.1 Method DFT(GTOs) Exchange PBE PBE kappa parameter XKappa 0.804000 XMuePBE 0.219520 Correlation PBE PBE beta parameter CBetaPBE 0.066725 LDAOpt PW91-LDA PostSCFGGA off Density functional embedding theory OFF NL short-range parameter 6.400000 RI-approximation to the Coulomb term is turned on functions 2173 IntName 2_F_Ce_opt_freq_freq_freq HFTyp RHF Charge 0 Mult 1 NEL 274 Dim 938 ENuc 4577.6482546125 Eh CNVDIIS on DIISMaxIt 12 DIISStart 0.200000 DIISMaxEq 5 DIISBfac 1.050 DIISMaxC 10.000 CNVTRAH auto Auto Start mean grad. ratio tolernc. 1.125000 Auto Start start iteration 20 Auto Start num. interpolation iter. 10 iterations 16 iterations Maxiter - #DIIS iter Number of Davidson start vectors 2 Converg. threshold I (grad. norm) 2.000e-06 Converg. threshold II (energy diff.) 1.000e-09 Micro threshold 0.100 Minimum threshold for Micro iter. 0.010 NR start threshold (gradient norm) 0.001 Initial trust radius 0.400 Minimum AH scaling param. (alpha) 1.000 Maximum AH scaling param. (alpha) 1000.000 Orbital update algorithm Taylor David. guess on Maximum white noise 0.010 Quad. conv. algorithm NR CNVSOSCF on SOSCFMaxIt 150 SOSCFStart 0.010000 CNVShift on LevelShift 0.2500 ShiftErr 0.0010 CNVZerner off CNVDamp on DampFac 0.7000 DampMax 0.9800 DampMin 0.0000 DampErr 0.1000 CNVRico off MaxIter 800 SCFMode Direct Integral package SHARK and LIBINT hybrid scheme DirectResetFreq 5 Thresh 1.000e-12 Eh TCut 1.000e-14 Eh UseCheapInts on CheapIntThresh 1.000e-05 CheapIntOff 1.000e-03 ConvCheckMode Total+1el-Energy ConvForced 0 TolE 1.000e-09 Eh 1-El. energy change 1.000e-06 Eh TolG 2.000e-06 TolX 2.000e-06 TolErr 1.000e-08 Smallest eigenvalue 3.194e-06 Time for diagonalization 0.166 sec Threshold for overlap eigenvalues 1.000e-08 Number of eigenvalues below threshold 0 Time for construction of square roots 0.146 sec Total time needed 0.317 sec def2-SVPD def2/JK def2/J def2-SVPD/C PBE rijcosx rhf hcore XYZFile VeryTightSCF freq cpcm(water) D3 defgrid3 freq QuasiRRHO true #CutOffFreq 35 scf CNVSOSCF TRUE SCFmode Direct SOSCFStart 0.01 AutoTRAH true Maxiter 800 UseCheapInts true DirectResetFreq 5 MaxCore 10000 %pal nprocs 9 %basis NewGTO La S 2 1 3.0726097 0.49908249 2 1.8074175 -1.4940047 S 1 1 1.0631868 1.0 S 1 1 0.36751856 1.0 S 1 1 0.15000000 1.0 S 1 1 0.034707994 1.0 S 1 1 0.0074193141 1.0 P 2 1 3.6285927 0.093502512 2 2.1344663 -0.33431269 P 1 1 0.68695878 1.0 P 1 1 0.32913905 1.0 P 1 1 0.15000000 1.0 P 1 1 0.060241305 1.0 D 2 1 1.4998229 -0.080321192 2 0.88224877 0.092893357 D 1 1 0.40189112 1.0 D 1 1 0.15000000 1.0 D 1 1 0.052124881 1.0 end 0 1 0.00 0.00 0.00 0.00 0.00 0.00 15.25 20.55 31.58 32.43 34.48 41.17 44.08 47.53 67.58 70.27 74.23 79.67 81.14 92.72 95.45 100.33 100.87 105.31 111.59 116.33 125.00 138.31 149.14 157.07 162.58 166.42 167.34 176.54 179.59 188.61 194.19 198.86 203.83 205.16 233.94 240.17 254.09 276.95 290.79 295.69 319.77 330.30 338.19 366.92 413.80 420.98 430.84 433.43 447.59 471.59 493.99 531.13 570.86 581.80 587.63 597.42 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AuxInfo=1/0/N:25,29,33,37,7,8,1,14,2,17,3,9,4,16,5,10,19,21,6,15,23,24,20,22;41;42,43,44,45;46,47,48,49;50,51,52,53/E:(1,2,3,4)(5,6)(7,8)(9,10)(11,12)(13,14)(15,16)(17,18)(19,20)(21,22)(23,24);;3*(2,3,4)/CRV:5.3,6.3,7.3,8.3,9.3,10.3,11.3,12.3,13.3,14.3,15.3,16.3,17.3,18.3,19-1,20-1,23-1,24-1;;3*2.1,3-1,4-1/rA:55nC3C3C3C3C3NC3C3C3C3HHHC3NC3C3HC3OC3ONNCHHHCHHHCHHHCHHHCeNO1OONO1OONO1OOHH/rB:s1;s1;s2;s3;s4s5;s3;s7;s8;s5s9;s2;s7;s8;s9;s10;s15;s14s16;s17;s4;s19;s16;s21;s19;s21;s23;s25;s25;s25;s23;s29;s29;s29;s24;s33;s33;s33;s24;s37;s37;s37;s6s15s20s22;;s42;s41s42;s41s42;;s46;s41s46;s41s46;;s50;s41s50;s41s50;s14;s1;/rC:-.3925,-.452,-4.0632;-.522,.9117,-4.3032;-.3349,-.9349,-2.7323;-.6068,1.7954,-3.2009;-.409,.0357,-1.6862;-.5419,1.3558,-1.9378;-.173,-2.3243,-2.397;-.0576,-2.7288,-1.088;-.096,-1.7752,-.0123;-.2892,-.3905,-.306;-.5242,1.2957,-5.3293;-.1315,-3.057,-3.2145;.0779,-3.7905,-.8405;.0826,-2.1215,1.35;-.3304,.5532,.657;-.2137,.2047,1.9434;.026,-1.1373,2.3306;.1973,-1.3988,3.38;-.6096,3.303,-3.2901;.0231,3.9252,-2.3863;-.2479,1.3987,2.8678;.1286,2.5082,2.3858;-1.2395,3.9429,-4.2852;-.6556,1.2925,4.1421;-2.2166,3.3388,-5.1892;-1.7939,3.2206,-6.2053;-2.5636,2.3671,-4.8072;-3.0881,4.0155,-5.2479;-1.0997,5.3937,-4.3929;-.1661,5.7154,-3.9076;-1.0854,5.6647,-5.4632;-1.9589,5.8967,-3.9073;-1.3901,.1614,4.7079;-1.8308,-.4613,3.9152;-.7371,-.4521,5.3579;-2.213,.5684,5.3222;-.5237,2.4514,5.0234;-1.4819,3.0049,5.0748;-.2659,2.0907,6.0348;.265,3.1203,4.6476;-.3865,3.1657,.0042;2.6752,3.26,.0323;3.9063,3.2969,.0643;1.9644,4.2695,.3732;2.0445,2.2125,-.3426;-3.3982,2.7803,-.4988;-4.6101,2.6538,-.6917;-2.6931,3.5958,-1.1888;-2.7857,2.1036,.394;-1.5488,5.8644,.9567;-2.0451,6.9359,1.3168;-1.8524,4.7612,1.5284;-.7091,5.8037,-.0044;.2762,-3.168,1.623;-.3129,-1.159,-4.9004;/R:/0/N:25,29,33,37,7,8,1,14,2,17,3,9,4,16,5,10,19,21,41,23,24,6,15,42,46,50,43,47,51,20,22,44,45,48,49,52,53/E:(1,2,3,4)(5,6)(7,8)(9,10)(11,12)(13,14)(15,16)(17,18)(20,21)(22,23)(24,25,26)(27,28,29)(30,31)(32,33,34,35,36,37)/CRV:5.3,6.3,7.3,8.3,9.3,10.3,11.3,12.3,13.3,14.3,15.3,16.3,17.3,18.3,19.10,27.1,28.1,29.1 Epsilon 80.4000 Refrac 1.3300 Rsolv 1.3000 Surface type GAUSSIAN VDW Epsilon function type CPCM C N H O Ce 2.0400 1.8600 1.3200 1.8240 2.4000 Calculating surface done! ( 0.0s) GEPOL surface points 2922 GEPOL Volume 3784.9517 GEPOL Surface-area 1806.3406 Calculating surface distance matrix done! ( 0.1s) Performing Cholesky decomposition & store done! ( 0.4s) Overall time for CPCM initialization 0.4s -1936.48803821 4577.64825461 -6514.13629283 -11775.78388820 5261.64759538 -0.09430096 -3831.38564836 1894.89761014 2.02194864 137.000175985287 137.000175985287 274.000351970575 -239.513822649925 -9.359759866944 -248.873582516869 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200 201 202 203 204 205 206 207 208 209 210 211 212 213 214 215 216 217 218 219 220 221 222 223 224 225 226 227 228 229 230 231 232 233 234 235 236 237 238 239 240 241 242 243 244 245 246 247 248 249 250 251 252 253 254 255 256 257 258 259 260 261 262 263 264 265 266 267 268 269 270 271 272 273 274 275 276 277 278 279 280 281 282 283 284 285 286 287 288 289 290 291 292 293 294 295 296 297 298 299 300 301 302 303 304 305 306 307 308 309 310 311 312 313 314 315 316 317 318 319 320 321 322 323 324 325 326 327 328 329 330 331 332 333 334 335 336 337 338 339 340 341 342 343 344 345 346 347 348 349 350 351 352 353 354 355 356 357 358 359 360 361 362 363 364 365 366 367 368 369 370 371 372 373 374 375 376 377 378 379 380 381 382 383 384 385 386 387 388 389 390 391 392 393 394 395 396 397 398 399 400 401 402 403 404 405 406 407 408 409 410 411 412 413 414 415 416 417 418 419 420 421 422 423 424 425 426 427 428 429 430 431 432 433 434 435 436 437 438 439 440 441 442 443 444 445 446 447 448 449 450 451 452 453 454 455 456 457 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