%chk=fwd_ener_opt_freq.chk
%nprocshared=16
%mem=64GB
#p freq b3lyp/6-31g(d) nosymm int=superfinegrid opt=(tight,CalcFC) scrf=(cpcm,solvent=water,read) iop(7/90=-1)

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-4 1
 C               -1   -3.41800100   -4.57239100    0.19111100
 H                0   -4.06754400   -5.40736400    0.48490500
 H                0   -2.38893100   -4.76057900    0.49432300
 C                0   -3.90709400   -3.29757500    0.82491900
 O                0   -4.54841700   -2.43372400    0.25911900
 O                0   -3.59511400   -3.21752300    2.14149600
 C               -1    3.11779900    0.06875900    3.45776100
 H                0    2.47806200    0.12018000    4.35007900
 H                0    4.13197100    0.35631200    3.75337800
 C                0    2.58187800    1.07072500    2.43111200
 O                0    1.36770300    0.94237200    2.06003000
 O                0    3.35876200    1.99060400    2.06677100
 C               -1   -1.55095100    0.81865900    4.15506100
 H                0   -1.59527700    1.90830800    4.07773200
 H                0   -0.73205700    0.43779100    3.54348600
 C                0   -2.91144200    0.25178800    3.78605500
 O                0   -3.93981400    0.64996500    4.31349100
 O                0   -2.93018000   -0.69746600    2.85925800
 H                0   -3.78147400   -2.29379700    2.43886800
 O                0   -0.90831600   -3.08701200    0.08404100
 P                0   -0.12079200   -2.01381100    0.81951100
 O                0   -0.48835000   -0.55782600    0.38242900
 O                0    1.32553500   -2.28800300    1.15745600
 O                0    2.47574700   -1.49034600   -2.55793400
 P                0    2.48920400    0.02171900   -2.49455300
 O                0    2.22247400    0.62039500   -1.06756400
 O                0    3.61676200    0.75507900   -3.20853100
 O                0    1.04730100    0.45796100   -3.37463700
 P                0   -0.06553400    1.60349100   -3.19851300
 O                0   -0.31331000    1.88907800   -1.70775800
 O                0   -1.25572700    1.31080100   -4.06669000
 O                0    0.63126700    2.95134300   -3.87940400
 C               -1    1.83494900    3.48070900   -3.32088900
 H                0    2.49308200    2.68538100   -2.95887500
 H                0    1.61275000    4.18158500   -2.50622400
 Mg              -1    0.56429900    1.12565900   -0.02003900
 O                0   -0.93451900   -2.04693000    2.42469600
 H                0   -1.44438900   -2.87630400    2.39387900
 H                0   -1.97970000   -1.13728800    2.62347400
 O                0   -1.03262800    1.93518300    1.28112400
 H                0   -0.34798400    1.86939100    1.97822500
 H                0   -1.34625300    1.00387800    1.20377400
 O                0    1.86583600    2.99835200    0.05678000
 H                0    2.42594700    2.76402400    0.84838600
 H                0    2.27878600    2.43982800   -0.64383400
 H               -1   -1.34780100    0.57375900    5.17671100
 H               -1    3.12849900   -0.96029100    3.16491100
 H               -1    2.38014900    3.98935900   -4.08833900
 H               -1   -3.44905100   -4.43719100   -0.86993900

eps=4.0