! wB97X-D3 def2-TZVPP defgrid3
%maxcore 3200

%pal nprocs 16 
end

%tddft
nroots=15
tda false
end

*xyz 1 1
O            -0.393343         0.650325         1.063726
N            -1.539070        -1.670797         1.217475
N             1.546419        -0.400095         0.508299
C             1.277210        -1.682485         1.192405
C             0.554585        -1.572095         2.551057
C             0.558337        -2.695202         0.299263
C            -0.889437        -2.077392         2.496487
C            -0.904928        -2.345773         0.038835
C            -3.019108        -1.844084         1.266154
C            -3.723727        -1.410756        -0.015195
C             2.732326        -0.408693        -0.308679
C             0.735376         0.691245         0.548335
C            -3.447647         0.024147        -0.404244
C             3.984528        -0.356846         0.290932
C             2.614964        -0.492724        -1.689419
C             1.260107         1.952753        -0.016407
C            -3.827320         1.070592         0.433858
C            -2.822322         0.323878        -1.610679
C             5.125192        -0.387716        -0.499252
C             3.758922        -0.516311        -2.477718
C             5.013133        -0.466704        -1.883075
C             0.468510         3.022276        -0.079907
C            -3.588836         2.388245         0.071979
C            -2.580300         1.642557        -1.977044
C            -2.965934         2.677051        -1.136618
C             0.880846         4.355194        -0.605264
H             2.272473        -2.082966         1.381937
H             1.086420        -2.191858         3.275298
H             0.585335        -0.549548         2.920020
H             1.073599        -2.791015        -0.657966
H             0.626289        -3.670128         0.789202
H            -0.946118        -3.165890         2.562402
H            -1.478516        -1.658090         3.311841
H            -1.006433        -1.653877        -0.796472
H            -1.478902        -3.245952        -0.185667
H            -3.215825        -2.897079         1.484256
H            -3.366695        -1.248959         2.111824
H            -3.463106        -2.078066        -0.839313
H            -4.793917        -1.551516         0.161612
H             4.061501        -0.277138         1.370220
H             1.629500        -0.519366        -2.142626
H             2.286404         1.991980        -0.356643
H            -4.335249         0.859668         1.370520
H            -2.547021        -0.479457        -2.288404
H             6.103223        -0.340991        -0.034506
H             3.669424        -0.574373        -3.556326
H             5.905451        -0.486826        -2.497876
H            -0.553181         2.915165         0.273192
H            -3.902219         3.192419         0.728167
H            -2.104747         1.860426        -2.926817
H            -2.792039         3.707586        -1.425881
H             0.236679         4.645735        -1.440857
H             1.918316         4.361498        -0.941674
H             0.755061         5.119448         0.167395
H            -1.281048        -0.647157         1.117040
*