Orca 5.0.4 RELEASE 1 2 8s4p1d 4s 4s2p1d 2s 0 1 2 C H H 1 2 2 12.0107 AuxInfo=1/0/N:1/CRV:1.2/rA:3nC2HH/rB:s1;s1;/rC:-6.5538,2.6205,0;-5.4838,2.6205,0;-7.368,2.8109,-.679; Method DFT(GTOs) Exchange PBE PBE kappa parameter XKappa 1.024500 XMuePBE 0.123457 Correlation PBE PBE beta parameter CBetaPBE 0.030000 LDAOpt PW91-LDA PostSCFGGA off Hybrid DFT is turned on ScalHFX 0.420000 ScalDFX 0.580000 ScalDFC 1.000000 ScalLDAC 1.000000 Perturbative correction 0.000000 Density functional embedding theory OFF RI-approximation to the Coulomb term is turned on functions 71 RIJ-ON(X) (HFX calculated with O(N)) on functions 71 RIJ-COSX (HFX calculated with COS-X)) on IntName CH2_opt_orca HFTyp RHF Charge -2 Mult 1 NEL 10 Dim 19 ENuc 6.1779345899 Eh CNVDIIS on DIISMaxIt 12 DIISStart 0.200000 DIISMaxEq 5 DIISBfac 1.050 DIISMaxC 10.000 CNVTRAH auto Auto Start mean grad. ratio tolernc. 1.125000 Auto Start start iteration 20 Auto Start num. interpolation iter. 10 iterations 16 iterations Maxiter - #DIIS iter Number of Davidson start vectors 2 Converg. threshold I (grad. norm) 1.000e-05 Converg. threshold II (energy diff.) 1.000e-08 Micro threshold 0.100 Minimum threshold for Micro iter. 0.010 NR start threshold (gradient norm) 0.001 Initial trust radius 0.400 Minimum AH scaling param. (alpha) 1.000 Maximum AH scaling param. (alpha) 1000.000 Orbital update algorithm Taylor David. guess on Maximum white noise 0.010 Quad. conv. algorithm NR COSX micro iterations for RIJONX calc off CNVSOSCF on SOSCFMaxIt 150 SOSCFStart 0.003300 CNVShift on LevelShift 0.2500 ShiftErr 0.0010 CNVZerner off CNVDamp on DampFac 0.7000 DampMax 0.9800 DampMin 0.0000 DampErr 0.1000 CNVRico off MaxIter 250 SCFMode Direct Integral package SHARK and LIBINT hybrid scheme DirectResetFreq 20 Thresh 2.500e-11 Eh TCut 2.500e-12 Eh ConvCheckMode Total+1el-Energy ConvForced 0 TolE 1.000e-08 Eh 1-El. energy change 1.000e-05 Eh TolG 1.000e-05 TolX 1.000e-05 TolErr 5.000e-07 Smallest eigenvalue 3.782e-02 Time for diagonalization 0.000 sec Threshold for overlap eigenvalues 1.000e-08 Number of eigenvalues below threshold 0 Time for construction of square roots 0.001 sec Total time needed 0.001 sec Method DFT(GTOs) Exchange PBE PBE kappa parameter XKappa 1.024500 XMuePBE 0.123457 Correlation PBE PBE beta parameter CBetaPBE 0.030000 LDAOpt PW91-LDA PostSCFGGA off Hybrid DFT is turned on ScalHFX 0.420000 ScalDFX 0.580000 ScalDFC 1.000000 ScalLDAC 1.000000 Perturbative correction 0.000000 Density functional embedding theory OFF RI-approximation to the Coulomb term is turned on functions 71 RIJ-ON(X) (HFX calculated with O(N)) on functions 71 RIJ-COSX (HFX calculated with COS-X)) on IntName CH2_opt_orca HFTyp RHF Charge -2 Mult 1 NEL 10 Dim 19 ENuc 5.6464137847 Eh CNVDIIS on DIISMaxIt 12 DIISStart 0.200000 DIISMaxEq 5 DIISBfac 1.050 DIISMaxC 10.000 CNVTRAH auto Auto Start mean grad. ratio tolernc. 1.125000 Auto Start start iteration 1 Auto Start num. interpolation iter. 10 iterations 16 iterations Maxiter - #DIIS iter Number of Davidson start vectors 2 Converg. threshold I (grad. norm) 1.000e-05 Converg. threshold II (energy diff.) 1.000e-08 Micro threshold 0.100 Minimum threshold for Micro iter. 0.010 NR start threshold (gradient norm) 0.001 Initial trust radius 0.400 Minimum AH scaling param. (alpha) 1.000 Maximum AH scaling param. (alpha) 1000.000 Orbital update algorithm Taylor David. guess on Maximum white noise 0.010 Quad. conv. algorithm NR COSX micro iterations for RIJONX calc off CNVSOSCF on SOSCFMaxIt 150 SOSCFStart 0.003300 CNVShift on LevelShift 0.2500 ShiftErr 0.0010 CNVZerner off CNVDamp on DampFac 0.7000 DampMax 0.9800 DampMin 0.0000 DampErr 0.1000 CNVRico off MaxIter 250 SCFMode Direct Integral package SHARK and LIBINT hybrid scheme DirectResetFreq 20 Thresh 2.500e-11 Eh TCut 2.500e-12 Eh ConvCheckMode Total+1el-Energy ConvForced 0 TolE 1.000e-08 Eh 1-El. energy change 1.000e-05 Eh TolG 1.000e-05 TolX 1.000e-05 TolErr 5.000e-07 Smallest eigenvalue 3.635e-02 Time for diagonalization 0.000 sec Threshold for overlap eigenvalues 1.000e-08 Number of eigenvalues below threshold 0 Time for construction of square roots 0.001 sec Total time needed 0.001 sec 6 1 1 12.0107 AuxInfo=1/0/N:1/CRV:1.2/rA:3nC2HH/rB:s1;s1;/rC:-6.5538,2.6205,0;-5.4838,2.6205,0;-7.368,2.8109,-.679; -2 1 Opt RIJCOSX PBEh-3c output xyzfile=True scf maxiter 250 output Print[P_Hirshfeld] = 1 maxcore 4800 %pal nprocs 2 12.0107 AuxInfo=1/0/N:1/CRV:1.2/rA:3nC2HH/rB:s1;s1;/rC:-6.5826,2.6013,.0686;-5.4849,2.6319,-.0405;-7.3381,2.8188,-.7072; 12.0107 AuxInfo=1/0/N:1/CRV:1.2/rA:3nC2HH/rB:s1;s1;/rC:-6.6191,2.5752,.1617;-5.5167,2.65,-.1051;-7.2698,2.8268,-.7356; 12.0107 AuxInfo=1/0/N:1/CRV:1.2/rA:3nC2HH/rB:s1;s1;/rC:-6.6542,2.5497,.2525;-5.567,2.6696,-.1749;-7.1844,2.8327,-.7567; 12.0107 AuxInfo=1/0/N:1/CRV:1.2/rA:3nC2HH/rB:s1;s1;/rC:-6.6533,2.5502,.2509;-5.5581,2.6684,-.1706;-7.1941,2.8334,-.7593; 12.0107 AuxInfo=1/0/N:1/CRV:1.2/rA:3nC2HH/rB:s1;s1;/rC:-6.6542,2.5495,.2534;-5.5519,2.6681,-.1698;-7.1994,2.8344,-.7627; 12.0107 AuxInfo=1/0/N:1/CRV:1.2/rA:3nC2HH/rB:s1;s1;/rC:-6.6545,2.5494,.2538;-5.5516,2.6682,-.1699;-7.1995,2.8344,-.7629; -38.633394133893 -38.648808240373 -38.664753367847 -38.670581528979 -38.670698270495 -38.670738119494 -38.670738419378 0 1 2 C H H -1.928854 -0.034502 -0.036643 0 1 2 C H H 7.7015 1.1471 1.1514 6.0000 1.0000 1.0000 -1.7015 -0.1471 -0.1514 1.8324 0.9352 0.9342 1.8324 0.9352 0.9342 0.0000 0.0000 0.0000 0.9167 0.9157 0 1 0 2 -2.0000000 0 1 2 C H H -1.701531 -0.147071 -0.151398 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 2.0000 2.0000 2.0000 2.0000 2.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 -264.8582 -0.8257 4.3560 11.8873 12.3723 19.4612 22.3750 30.9416 31.9554 33.0785 36.0787 44.9814 48.0066 66.9992 68.6774 68.7718 76.2562 82.1069 385.2645 12.0107 AuxInfo=1/0/N:1/CRV:1.2/rA:3nC2HH/rB:s1;s1;/rC:-6.6547,2.5494,.2538;-5.5515,2.6682,-.17;-7.1994,2.8344,-.7628; -38.63366810 6.17793459 -44.81160269 -69.45174624 24.64014355 -77.56387549 38.93020739 1.99238280 5.000052949041 5.000052949041 10.000105898081 -3.485699347622 -0.397206095098 -3.882905442720 -0.000282707 -0.000283106 -0.000284097 -0.000285469 -0.000285534 -0.000285706 -0.000285725 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 2.0000 2.0000 2.0000 2.0000 2.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 -265.8016 -0.8772 6.1610 9.9469 12.0649 19.3043 20.5787 31.0685 32.3739 32.6650 40.3644 42.2770 43.6276 66.8754 67.5899 67.9085 74.2074 78.8688 384.5432 -2.0000000 0 1 2 C H H -1.505220 -0.247251 -0.247529 0 1 2 C H H -1.752068 -0.123876 -0.124056 0 1 2 C H H 7.5052 1.2473 1.2475 6.0000 1.0000 1.0000 -1.5052 -0.2473 -0.2475 1.7937 0.8815 0.8814 1.7937 0.8815 0.8814 -0.0000 -0.0000 0.0000 0.8969 0.8968 0 1 0 2 -0.000285727 -38.670738456181 0.44861 -0.29752 0.15109 0.32447 -0.21566 0.10880 -1.15714 0.76907 -0.38808 0.43043 1.09407