Orca 5.0.4 RELEASE 1 2 3 4 5 6 7s4p1d 7s4p1d 10s7p1d 7s6p5d1f 7s4p1d 4s1p 3s2p1d 3s2p1d 4s3p1d 6s3p2d1f 3s2p1d 2s1p 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 C C N C C C C P Ir P C C C C C C C O O H H H C C H H H H C C H H H H H H H H H H H H H H H H H H H H H H H 1 1 2 1 1 1 1 3 4 3 1 1 1 1 1 1 1 5 5 6 6 6 1 1 6 6 6 6 1 1 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 1 Ir ECP Def2-ECP 8 Ir 1 1 Ir ECP Def2-ECP 8 Ir 1 504.35192199999983 AuxInfo=1/0/N:23,24,29,30,6,1,5,7,11,2,4,3,8,10;15,14,16,13,17,12;9;18;19;36;40;41/E:(1,2)(3,4);(2,3)(4,5);;;;;;/CRV:5.3,6.3,7.3,8.3,10.3,11.3,12-1;1.3,2.3,3.3,4.3,5.3,6.2;;;;;;/rA:53nC3C3NC3C3C3C3P4IrP4CC3C3C3C3C3C3OOHHHCCHHHHCCHHHHHHHHHHH0HHHHHHHHHHHH/rB:s1;s2;s3;s4;s1s5;s2;s7;s3s8;s9;s4s10;s9;s12;s13;s14;s15;s12s16;;;s1;s5;s6;s8;s8;s11;s11;s18;s7;s10;s10;s13;s14;s15;s16;s17;s9;s19;s19;s18;s9;;s23;s23;s23;s24;s24;s24;s30;s30;s30;s29;s29;s29;/rC:3.912,-.9712,-1.0571;2.5496,-1.0474,-.6674;1.8943,.1137,-.3653;2.537,1.2983,-.341;3.8741,1.4087,-.6957;4.5591,.2455,-1.0736;1.8656,-2.287,-.4537;.0804,-2.2316,-.4832;-.2539,.0256,-.1383;-.0489,2.2956,-.0727;1.7692,2.4786,.1913;-2.3077,-.0132,-.1247;-3.0578,-.133,-1.3145;-4.4532,-.127,-1.3231;-5.1679,.0042,-.1335;-4.4595,.1237,1.0608;-3.0636,.1117,1.0594;2.1197,-1.8054,2.1928;1.5181,.5594,2.6901;4.431,-1.8905,-1.3333;4.3733,2.377,-.6596;5.6102,.3035,-1.3698;-.6001,-2.9087,-2.0431;-.4923,-3.4451,.7548;1.8871,2.4438,1.2893;2.1718,3.4342,-.1755;2.0556,-2.1084,1.1378;2.3738,-3.1947,-.7965;-.4509,3.2147,-1.5898;-.815,3.2555,1.2736;-2.5299,-.2306,-2.267;-4.9869,-.222,-2.2737;-6.2608,.0137,-.1374;-4.9981,.2265,2.0077;-2.5436,.2037,2.0184;-.4275,-.2891,1.6004;1.122,.5895,3.5683;1.8483,-.4343,2.5322;3.0082,-2.0053,2.5031;-.3376,.1509,-1.7242;.3137,.1786,1.8319;-.3015,-3.9565,-2.201;-1.6982,-2.8466,-1.9914;-.2585,-2.292,-2.8853;-.199,-4.4663,.4641;-.0216,-3.1892,1.714;-1.586,-3.3908,.8517;-.5605,4.3251,1.2294;-1.9057,3.1276,1.2088;-.4753,2.8316,2.2293;-.2286,4.2883,-1.499;.1277,2.7769,-2.4152;-1.5191,3.0679,-1.8076;/R:/0/N:23,24,29,30,15,14,16,6,13,17,1,5,7,11,12,2,4,9,3,8,10;18;19;41/E:(1,2)(3,4)(6,7)(9,10);;;/CRV:5.3,6.3,7.3,8.3,9.3,10.3,11.3,12.3,13.3,15.3,16.3,17.3,18.6,20.4,21.4;;; Method DFT(GTOs) Exchange PBE PBE kappa parameter XKappa 0.804000 XMuePBE 0.219520 Correlation PBE PBE beta parameter CBetaPBE 0.066725 LDAOpt PW91-LDA PostSCFGGA off Hybrid DFT is turned on ScalHFX 0.250000 ScalDFX 0.750000 ScalDFC 1.000000 ScalLDAC 1.000000 Perturbative correction 0.000000 Density functional embedding theory OFF NL short-range parameter 6.900000 RI-approximation to the Coulomb term is turned on functions 1501 RIJ-COSX (HFX calculated with COS-X)) on IntName reaction-21-dhs-optts HFTyp RHF Charge 0 Mult 1 NEL 202 Dim 498 ENuc 2781.8585516854 Eh CNVDIIS on DIISMaxIt 12 DIISStart 0.200000 DIISMaxEq 5 DIISBfac 1.050 DIISMaxC 10.000 CNVTRAH auto Auto Start mean grad. ratio tolernc. 1.125000 Auto Start start iteration 20 Auto Start num. interpolation iter. 10 iterations 16 iterations Maxiter - #DIIS iter Number of Davidson start vectors 2 Converg. threshold I (grad. norm) 1.000e-05 Converg. threshold II (energy diff.) 1.000e-08 Micro threshold 0.100 Minimum threshold for Micro iter. 0.010 NR start threshold (gradient norm) 0.001 Initial trust radius 0.400 Minimum AH scaling param. (alpha) 1.000 Maximum AH scaling param. (alpha) 1000.000 Orbital update algorithm Taylor David. guess on Maximum white noise 0.010 Quad. conv. algorithm NR CNVSOSCF off CNVShift on LevelShift 0.2500 ShiftErr 0.0010 CNVZerner off CNVDamp on DampFac 0.7000 DampMax 0.9800 DampMin 0.0000 DampErr 0.1000 CNVRico off MaxIter 125 SCFMode Direct Integral package SHARK and LIBINT hybrid scheme DirectResetFreq 20 Thresh 2.500e-11 Eh TCut 2.500e-12 Eh ConvCheckMode Total+1el-Energy ConvForced 0 TolE 1.000e-08 Eh 1-El. energy change 1.000e-05 Eh TolErr 5.000e-07 Smallest eigenvalue 2.705e-04 Time for diagonalization 0.038 sec Threshold for overlap eigenvalues 1.000e-08 Number of eigenvalues below threshold 0 Time for construction of square roots 0.018 sec Total time needed 0.057 sec Method DFT(GTOs) Exchange PBE PBE kappa parameter XKappa 0.804000 XMuePBE 0.219520 Correlation PBE PBE beta parameter CBetaPBE 0.066725 LDAOpt PW91-LDA PostSCFGGA off Hybrid DFT is turned on ScalHFX 0.250000 ScalDFX 0.750000 ScalDFC 1.000000 ScalLDAC 1.000000 Perturbative correction 0.000000 Density functional embedding theory OFF NL short-range parameter 6.900000 RI-approximation to the Coulomb term is turned on functions 1501 RIJ-COSX (HFX calculated with COS-X)) on IntName reaction-21-dhs-optts HFTyp RHF Charge 0 Mult 1 NEL 202 Dim 498 ENuc 2767.3981884959 Eh CNVDIIS on DIISMaxIt 12 DIISStart 0.200000 DIISMaxEq 5 DIISBfac 1.050 DIISMaxC 10.000 CNVTRAH auto Auto Start mean grad. ratio tolernc. 1.125000 Auto Start start iteration 1 Auto Start num. interpolation iter. 10 iterations 16 iterations Maxiter - #DIIS iter Number of Davidson start vectors 2 Converg. threshold I (grad. norm) 1.000e-05 Converg. threshold II (energy diff.) 1.000e-08 Micro threshold 0.100 Minimum threshold for Micro iter. 0.010 NR start threshold (gradient norm) 0.001 Initial trust radius 0.400 Minimum AH scaling param. (alpha) 1.000 Maximum AH scaling param. (alpha) 1000.000 Orbital update algorithm Taylor David. guess on Maximum white noise 0.010 Quad. conv. algorithm NR CNVSOSCF off CNVShift on LevelShift 0.2500 ShiftErr 0.0010 CNVZerner off CNVDamp on DampFac 0.7000 DampMax 0.9800 DampMin 0.0000 DampErr 0.1000 CNVRico off MaxIter 125 SCFMode Direct Integral package SHARK and LIBINT hybrid scheme DirectResetFreq 20 Thresh 2.500e-11 Eh TCut 2.500e-12 Eh ConvCheckMode Total+1el-Energy ConvForced 0 TolE 1.000e-08 Eh 1-El. energy change 1.000e-05 Eh TolErr 5.000e-07 Smallest eigenvalue 2.704e-04 Time for diagonalization 0.036 sec Threshold for overlap eigenvalues 1.000e-08 Number of eigenvalues below threshold 0 Time for construction of square roots 0.018 sec Total time needed 0.055 sec 0 1 PBE0 D3BJ def2-SVP def2/J TightSCF defgrid3 RIJCOSX OptTS TightOpt pal8 geom calc_hess true trust -0.1 maxiter 300 maxcore 4000 504.35192199999983 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47 48 49 50 51 52 C C N C C C C P Ir P C C C C C C C O O H H H C C H H H H C C H H H H H H H H H H H H H H H H H H H H H H H -0.078228 0.040721 -0.013189 0.034597 -0.097672 -0.004771 -0.368847 0.798961 -0.772503 0.804222 -0.166525 -0.074169 -0.057296 -0.049155 -0.069260 -0.049722 -0.058883 -0.026730 0.034531 0.032743 0.031281 0.036122 -0.204114 -0.209230 0.056233 0.035632 0.060645 0.018811 -0.203267 -0.206471 0.026536 0.023266 0.022729 0.022463 0.022133 -0.089149 0.092967 0.028283 0.084610 -0.076726 0.082222 0.028117 0.046100 0.045118 0.030767 0.032458 0.045739 0.031426 0.052831 0.043935 0.029255 0.049621 0.050831 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 C C N C C C C P Ir P C C C C C C C O O H H H C C H H H H C C H H H H H H H H H H H H H H H H H H H H H H H 6.0739 5.8869 7.2753 5.9364 6.0820 5.9460 6.3780 14.8549 16.9860 14.9228 6.0646 6.1368 6.0525 6.0136 6.0435 6.0128 6.0521 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