Orca 5.0.4 RELEASE 1 2 3 4 5 7s6p5d1f 7s4p1d 4s1p 7s4p1d 7s4p1d 5s3p2d1f 3s2p1d 2s1p 3s2p1d 3s2p1d 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 Ru C C C C C C H H H H H H O C N C H C C C C C H H H H H C H H H O C C H H H N C H C C C C C H H H H H 1 2 2 2 2 2 2 3 3 3 3 3 3 4 2 5 2 3 2 2 2 2 2 3 3 3 3 3 2 3 3 3 4 2 2 3 3 3 5 2 3 2 2 2 2 2 3 3 3 3 3 1 Ru ECP SD(28,MWB) 0 Ru 1 425.3175999999998 AuxInfo=1/0/N:35,45,44,46,43,42,34,40,39,33;29,21,20,22,19,23,15,17,16,14;2,3,6,4,7,5;1/E:(3,4)(5,6);;(1,2,3,4,5,6);/CRV:2.3,3.3,4.3,5.3,6.3,7.3,8.3;2.3,3.3,4.3,5.3,6.2,7.3,8.3,10-1;1.3,2.3,3.3,4.3,5.3,6.3;/rA:51nRuCCCCCCHHHHHHOC3NC3HC3C3C3C3C3HHHHHCHHHOC3CHHHNC3HC3C3C3C3C3HHHHH/rB:s1;s1s2;s1s3;s1s4;s1s2;s1s5s6;s2;s3;s4;s5;s6;s7;s1;s14;s15;s16;s16;s17;s19;s20;s21;s1s17s22;;s19;s20;s21;s22;s15;s29;s29;s29;s24;s33;s34;s35;s35;s35;s34;s39;s39;s40;s40;s43;s44;s42s45;s42;s43;s44;s45;s46;/rC:.5304,-.6812,1.8432;1.7461,-.4219,3.6556;.421,-.6501,4.0913;-.2885,-1.7462,3.5515;.3307,-2.6464,2.6407;2.4013,-1.3314,2.7776;1.6954,-2.4488,2.2852;2.269,.4856,3.9679;-.0781,.0602,4.7524;-1.3539,-1.8558,3.7678;-.2403,-3.4656,2.2006;3.4211,-1.1312,2.4435;2.1634,-3.1111,1.5547;-1.3639,-.0072,1.3661;-2.1366,-.3274,.433;-1.7398,-1.0037,-.6456;-.4421,-1.3925,-1.0194;-2.4652,-1.2241,-1.3202;-.3327,-2.0722,-2.2368;.9145,-2.4512,-2.7164;2.0691,-2.1452,-1.9922;1.9495,-1.4915,-.7734;.7001,-1.1004,-.2358;.8923,.3538,.0251;-1.2296,-2.3019,-2.8182;.9857,-2.9826,-3.6686;3.0525,-2.4245,-2.3772;2.8594,-1.2472,-.2181;-3.5741,.0553,.5349;-4.0277,-.4809,1.3827;-4.148,-.1619,-.3745;-3.6444,1.1279,.766;1.1007,1.2497,.7317;.4615,2.3701,.7423;.4936,3.1749,1.9858;1.5403,3.4263,2.2175;.1029,2.5697,2.8173;-.0852,4.1031,1.9048;-.1655,2.8088,-.3222;-.2506,2.1774,-1.6031;-.6373,3.7067,-.2263;.9042,1.7333,-2.2502;-1.5056,2.0686,-2.2041;-1.6042,1.487,-3.4659;-.4596,1.0218,-4.1137;.7901,1.1478,-3.5077;1.8866,1.8695,-1.7942;-2.3959,2.4542,-1.7006;-2.578,1.4182,-3.9555;-.5391,.581,-5.1098;1.6895,.8121,-4.027;/R:/0/N:29,20,21,19,22,15,17,23,2,3,6,4,7,5,16,14,1;35,45,44,46,43,42,34,40,39,33/E:(9,10,11,12,13,14);(3,4)(5,6)/CRV:2.3,3.3,4.3,5.3,6.3,7.3,8.3,17.8;2.3,3.3,4.3,5.3,6.3,7.3,8.3 Method DFT(GTOs) Exchange PBE PBE kappa parameter XKappa 0.804000 XMuePBE 0.219520 Correlation PBE PBE beta parameter CBetaPBE 0.066725 LDAOpt PW91-LDA PostSCFGGA off Hybrid DFT is turned on ScalHFX 0.250000 ScalDFX 0.750000 ScalDFC 1.000000 ScalLDAC 1.000000 Perturbative correction 0.000000 Density functional embedding theory OFF NL short-range parameter 6.900000 RI-approximation to the Coulomb term is turned on functions 1627 RIJ-COSX (HFX calculated with COS-X)) on IntName dhs_Ru_CH_activation_freq_high_sp_Compound_1 HFTyp RHF Charge 2 Mult 1 NEL 200 Dim 515 ENuc 2888.6120634873 Eh CNVDIIS on DIISMaxIt 12 DIISStart 0.200000 DIISMaxEq 5 DIISBfac 1.050 DIISMaxC 10.000 CNVTRAH auto Auto Start mean grad. ratio tolernc. 1.125000 Auto Start start iteration 20 Auto Start num. interpolation iter. 10 iterations 16 iterations Maxiter - #DIIS iter Number of Davidson start vectors 2 Converg. threshold I (grad. norm) 1.000e-05 Converg. threshold II (energy diff.) 1.000e-08 Micro threshold 0.100 Minimum threshold for Micro iter. 0.010 NR start threshold (gradient norm) 0.001 Initial trust radius 0.400 Minimum AH scaling param. (alpha) 1.000 Maximum AH scaling param. (alpha) 1000.000 Orbital update algorithm Taylor David. guess on Maximum white noise 0.010 Quad. conv. algorithm NR CNVSOSCF off CNVShift on LevelShift 0.2500 ShiftErr 0.0010 CNVZerner off CNVDamp on DampFac 0.7000 DampMax 0.9800 DampMin 0.0000 DampErr 0.1000 CNVRico off MaxIter 125 SCFMode Direct Integral package SHARK and LIBINT hybrid scheme DirectResetFreq 20 Thresh 2.500e-11 Eh TCut 2.500e-12 Eh ConvCheckMode Total+1el-Energy ConvForced 0 TolE 1.000e-08 Eh 1-El. energy change 1.000e-05 Eh TolErr 5.000e-07 Smallest eigenvalue 2.116e-04 Time for diagonalization 0.068 sec Threshold for overlap eigenvalues 1.000e-08 Number of eigenvalues below threshold 0 Time for construction of square roots 0.032 sec Total time needed 0.102 sec PBE0 D3BJ def2-SVP def2/J TightSCF defgrid3 RIJCOSX Freq EnGrad %basis newECP Ru "SDD" end end 2 1 freq temp 333.15 end 0.00 0.00 0.00 0.00 0.00 0.00 -933.43 -15.71 21.26 45.77 55.96 61.40 70.25 79.87 82.06 88.51 95.01 115.35 132.41 139.31 175.38 194.21 202.46 216.29 226.95 244.96 263.65 302.82 307.53 351.38 366.09 374.84 380.11 401.38 406.09 418.21 423.94 438.19 444.36 493.27 503.03 533.88 568.23 597.49 619.01 621.10 625.08 633.05 639.25 646.49 657.25 678.61 700.57 709.42 715.49 733.88 762.07 780.95 801.41 855.67 857.69 872.50 873.42 903.91 921.57 936.39 952.31 983.95 997.46 1000.54 1002.10 1003.77 1007.71 1010.82 1017.46 1019.71 1028.50 1033.50 1035.63 1038.45 1041.81 1043.06 1044.19 1045.20 1045.63 1047.52 1058.00 1080.38 1112.47 1142.13 1160.22 1164.11 1166.26 1168.11 1181.90 1186.80 1190.15 1257.32 1259.50 1279.23 1298.45 1328.71 1341.39 1342.34 1381.84 1382.63 1408.95 1411.89 1427.19 1430.56 1436.01 1449.35 1463.95 1468.75 1474.01 1480.78 1485.82 1500.43 1526.03 1534.32 1573.26 1581.19 1588.27 1605.20 1653.77 1668.72 1674.55 1679.80 1692.55 1730.65 3076.09 3078.82 3171.83 3172.83 3201.51 3203.43 3205.11 3205.93 3209.43 3224.31 3225.71 3227.44 3228.93 3232.03 3236.43 3236.64 3239.63 3244.79 3246.31 3249.86 3253.54 3585.07 3628.28 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RELEASE 1 2 3 4 5 7s7p5d1f 11s6p2d1f 5s1p 11s6p2d1f 11s6p2d1f 6s4p3d1f 5s3p2d1f 3s1p 5s3p2d1f 5s3p2d1f 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 Ru C C C C C C H H H H H H O C N C H C C C C C H H H H H C H H H O C C H H H N C H C C C C C H H H H H 1 2 2 2 2 2 2 3 3 3 3 3 3 4 2 5 2 3 2 2 2 2 2 3 3 3 3 3 2 3 3 3 4 2 2 3 3 3 5 2 3 2 2 2 2 2 3 3 3 3 3 1 Ru ECP SD(28,MWB) 0 Ru 1 425.3175999999998 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Method DFT(GTOs) Exchange PBE PBE kappa parameter XKappa 0.804000 XMuePBE 0.219520 Correlation PBE PBE beta parameter CBetaPBE 0.066725 LDAOpt PW91-LDA PostSCFGGA off Hybrid DFT is turned on ScalHFX 0.250000 ScalDFX 0.750000 ScalDFC 1.000000 ScalLDAC 1.000000 Perturbative correction 0.000000 Density functional embedding theory OFF NL short-range parameter 6.900000 RI-approximation to the Coulomb term is turned on functions 1627 RIJ-COSX (HFX calculated with COS-X)) on IntName dhs_Ru_CH_activation_freq_high_sp_Compound_2 HFTyp RHF Charge 2 Mult 1 NEL 200 Dim 990 ENuc 2888.6120634873 Eh CNVDIIS on DIISMaxIt 12 DIISStart 0.200000 DIISMaxEq 5 DIISBfac 1.050 DIISMaxC 10.000 CNVTRAH auto Auto Start mean grad. ratio tolernc. 1.125000 Auto Start start iteration 1 Auto Start num. interpolation iter. 10 iterations 16 iterations Maxiter - #DIIS iter Number of Davidson start vectors 2 Converg. threshold I (grad. norm) 1.000e-05 Converg. threshold II (energy diff.) 1.000e-08 Micro threshold 0.100 Minimum threshold for Micro iter. 0.010 NR start threshold (gradient norm) 0.001 Initial trust radius 0.400 Minimum AH scaling param. (alpha) 1.000 Maximum AH scaling param. (alpha) 1000.000 Orbital update algorithm Taylor David. guess on Maximum white noise 0.010 Quad. conv. algorithm NR CNVSOSCF off CNVShift on LevelShift 0.2500 ShiftErr 0.0010 CNVZerner off CNVDamp on DampFac 0.7000 DampMax 0.9800 DampMin 0.0000 DampErr 0.1000 CNVRico off MaxIter 125 SCFMode Direct Integral package SHARK and LIBINT hybrid scheme DirectResetFreq 20 Thresh 2.500e-11 Eh TCut 2.500e-12 Eh ConvCheckMode Total+1el-Energy ConvForced 0 TolE 1.000e-08 Eh 1-El. energy change 1.000e-05 Eh TolErr 5.000e-07 Smallest eigenvalue 5.069e-06 Time for diagonalization 0.240 sec Threshold for overlap eigenvalues 1.000e-08 Number of eigenvalues below threshold 0 Time for construction of square roots 0.140 sec Total time needed 0.385 sec PBE0 D4 def2-TZVP def2/J TightSCF defgrid3 RIJCOSX SP %basis newECP Ru "SDD" end end 2 1 cpcm smd true smdsolvent "1,2-DICHLOROETHANE" 425.3175999999998 AuxInfo=1/0/N:35,45,44,46,43,42,34,40,39,33;29,21,20,22,19,23,15,17,16,14;2,3,6,4,7,5;1/E:(3,4)(5,6);;(1,2,3,4,5,6);/CRV:2.3,3.3,4.3,5.3,6.3,7.3,8.3;2.3,3.3,4.3,5.3,6.2,7.3,8.3,10-1;1.3,2.3,3.3,4.3,5.3,6.3;/rA:51nRuCCCCCCHHHHHHOC3NC3HC3C3C3C3C3HHHHHCHHHOC3CHHHNC3HC3C3C3C3C3HHHHH/rB:s1;s1s2;s1s3;s1s4;s1s2;s1s5s6;s2;s3;s4;s5;s6;s7;s1;s14;s15;s16;s16;s17;s19;s20;s21;s1s17s22;;s19;s20;s21;s22;s15;s29;s29;s29;s24;s33;s34;s35;s35;s35;s34;s39;s39;s40;s40;s43;s44;s42s45;s42;s43;s44;s45;s46;/rC:.5304,-.6812,1.8432;1.7461,-.4219,3.6556;.421,-.6501,4.0913;-.2885,-1.7462,3.5515;.3307,-2.6464,2.6407;2.4013,-1.3314,2.7776;1.6954,-2.4488,2.2852;2.269,.4856,3.9679;-.0781,.0602,4.7524;-1.3539,-1.8558,3.7678;-.2403,-3.4656,2.2006;3.4211,-1.1312,2.4435;2.1634,-3.1111,1.5547;-1.3639,-.0072,1.3661;-2.1366,-.3274,.433;-1.7398,-1.0037,-.6456;-.4421,-1.3925,-1.0194;-2.4652,-1.2241,-1.3202;-.3327,-2.0722,-2.2368;.9145,-2.4512,-2.7164;2.0691,-2.1452,-1.9922;1.9495,-1.4915,-.7734;.7001,-1.1004,-.2358;.8923,.3538,.0251;-1.2296,-2.3019,-2.8182;.9857,-2.9826,-3.6686;3.0525,-2.4245,-2.3772;2.8594,-1.2472,-.2181;-3.5741,.0553,.5349;-4.0277,-.4809,1.3827;-4.148,-.1619,-.3745;-3.6444,1.1279,.766;1.1007,1.2497,.7317;.4615,2.3701,.7423;.4936,3.1749,1.9858;1.5403,3.4263,2.2175;.1029,2.5697,2.8173;-.0852,4.1031,1.9048;-.1655,2.8088,-.3222;-.2506,2.1774,-1.6031;-.6373,3.7067,-.2263;.9042,1.7333,-2.2502;-1.5056,2.0686,-2.2041;-1.6042,1.487,-3.4659;-.4596,1.0218,-4.1137;.7901,1.1478,-3.5077;1.8866,1.8695,-1.7942;-2.3959,2.4542,-1.7006;-2.578,1.4182,-3.9555;-.5391,.581,-5.1098;1.6895,.8121,-4.027;/R:/0/N:29,20,21,19,22,15,17,23,2,3,6,4,7,5,16,14,1;35,45,44,46,43,42,34,40,39,33/E:(9,10,11,12,13,14);(3,4)(5,6)/CRV:2.3,3.3,4.3,5.3,6.3,7.3,8.3,17.8;2.3,3.3,4.3,5.3,6.3,7.3,8.3 Epsilon 10.1250 Refrac 1.4448 Rsolv 1.3000 Surface type GAUSSIAN VDW Epsilon function type CPCM Ru C H O N 2.0700 1.8500 1.2000 2.1140 1.8900 Solvent: 1,2-DICHLOROETHANE Soln 1.4448 Soln25 1.4425 Sola 0.1000 Solb 0.1100 Solg 45.8600 Solc 0.0000 Solh 0.5000 Calculating surface done! ( 0.0s) GEPOL surface points 2847 GEPOL Volume 2668.4809 GEPOL Surface-area 1381.1156 Calculating surface distance matrix done! ( 0.1s) Performing Cholesky decomposition & store done! ( 0.4s) Overall time for CPCM initialization 0.4s -1206.51483042 2888.61206349 -4095.12689390 -7371.52322921 3276.39633530 -0.23627986 -2346.16841477 1139.65358436 2.05866804 100.000010212077 100.000010212077 200.000020424154 -120.678885610453 -6.884006388634 -127.562891999087 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200 201 202 203 204 205 206 207 208 209 210 211 212 213 214 215 216 217 218 219 220 221 222 223 224 225 226 227 228 229 230 231 232 233 234 235 236 237 238 239 240 241 242 243 244 245 246 247 248 249 250 251 252 253 254 255 256 257 258 259 260 261 262 263 264 265 266 267 268 269 270 271 272 273 274 275 276 277 278 279 280 281 282 283 284 285 286 287 288 289 290 291 292 293 294 295 296 297 298 299 300 301 302 303 304 305 306 307 308 309 310 311 312 313 314 315 316 317 318 319 320 321 322 323 324 325 326 327 328 329 330 331 332 333 334 335 336 337 338 339 340 341 342 343 344 345 346 347 348 349 350 351 352 353 354 355 356 357 358 359 360 361 362 363 364 365 366 367 368 369 370 371 372 373 374 375 376 377 378 379 380 381 382 383 384 385 386 387 388 389 390 391 392 393 394 395 396 397 398 399 400 401 402 403 404 405 406 407 408 409 410 411 412 413 414 415 416 417 418 419 420 421 422 423 424 425 426 427 428 429 430 431 432 433 434 435 436 437 438 439 440 441 442 443 444 445 446 447 448 449 450 451 452 453 454 455 456 457 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