%NProcShared=64
%Mem=60GB
%Chk=Pyrr_Me-TS1_restart_init_DZ.chk
# WB97XD/GenECP SCRF=(Solvent=toluene,PCM) OptCyc=300 SCFCyc=300 NoSymm
Opt=(MaxStep=6,ModRedundant) Pop=(Regular,Orbitals=20)

Pyrr_Me-TS1 restart init DZ

0 1
 H                  0.38557200    0.52076100    0.05463500
 C                  1.46203000    0.38413200    0.10144000
 C                  2.30960500    1.47200700   -0.08259700
 C                  1.99217700   -0.88080300    0.35000700
 C                  3.70425500    1.34107700   -0.03111300
 H                  1.87664500    2.45192700   -0.27024900
 C                  3.37108700   -1.04453100    0.40786900
 H                  1.33595600   -1.73303100    0.49672100
 C                  4.20705500    0.05573900    0.21633700
 H                  3.79724600   -2.02645300    0.59659100
 B                  4.65578200    2.61386200   -0.28689600
 H                  5.98034300    2.35377600    0.21519300
 H                  5.88173300    1.50952500    0.20312400
 C                  4.96021300    2.91889900   -1.84015700
 H                  5.71237300    3.70306400   -1.98564800
 H                  5.27679000    2.03434800   -2.40536100
 H                  4.03302000    3.27364800   -2.30958000
 C                  4.36729300    3.88527300    0.66002600
 H                  5.10171800    4.68897700    0.53323500
 H                  3.39035800    4.30837700    0.38877300
 H                  4.31675500    3.63209300    1.72478600
 N                  5.64029200   -0.07519600    0.26760300
 C                  6.23129300   -0.63917400    1.48586100
 C                  6.27666400   -0.75501500   -0.87628900
 C                  7.70823100   -0.73187700    1.11476900
 H                  5.81982600   -1.63439100    1.71387400
 H                  6.02484000    0.01797500    2.33494400
 C                  7.68350800   -1.14232200   -0.37335800
 H                  6.29144400   -0.07728600   -1.73431700
 H                  5.69793000   -1.64306800   -1.16300800
 H                  8.17671000    0.24981600    1.23325700
 H                  8.25258000   -1.44176200    1.74077600
 H                  8.47118500   -0.64397100   -0.94241500
 H                  7.83684000   -2.21917000   -0.48074700

11 12 F
12 13 F
13 22 F

B C H N 0
6-31g(d,p)
****


--Link1--
%NProcShared=64
%Mem=60GB
%OldChk=Pyrr_Me-TS1_restart_init_DZ.chk
%Chk=Pyrr_Me-TS1_restart_DZ.chk
# WB97XD/GenECP SCRF=(Solvent=toluene,PCM) OptCyc=300 SCFCyc=300 NoSymm
Freq Opt=(MaxStep=6,CalcFC,TS,NoEigenTest,NoFreeze) Pop=(Regular,Orbitals=20)
Guess=TCheck Geom=Check 

Pyrr_Me-TS1 restart DZ

0 1

B C H N 0
6-31g(d,p)
****


--Link1--
%NProcShared=64
%Mem=60GB
%OldChk=Pyrr_Me-TS1_restart_DZ.chk
%Chk=Pyrr_Me-TS1_restart.chk
# WB97XD/GenECP SCRF=(Solvent=toluene,PCM) OptCyc=300 SCFCyc=300 NoSymm
Freq Opt=(MaxStep=6,ReadFC,TS,NoEigenTest) Pop=(Regular,Orbitals=20,CHelpG)
Guess=TCheck Geom=Check 

Pyrr_Me-TS1 restart

0 1

B C H N 0
6-311++g(d,p)
****