%chk=aldehyde_rad.chk
%Mem=57428MB
%NProc=16
#p scrf(smd,solvent=acetonitrile) opt freq wB97xD/def2SVP  nosymm SCF=(XQC)

coments

0 2
 H                 -2.48982400    0.00266900   -3.42617900
 C                 -0.40217400   -0.59422000   -3.59916900
 H                 -0.37369000   -1.28404400   -4.44472900
 C                 -1.50795800    0.41075200   -3.72919900
 H                 -1.34981300    1.29216700   -3.08526600
 C                 -1.70184700    0.90599000   -5.14092800
 H                 -2.47282200    1.70837200   -5.23760000
 O                 -1.11531400    0.49286600   -6.10968900
 C                  0.97121400   -0.11304400   -3.25193000
 H                  0.98252500    0.61726400   -2.43173800
 H                  1.65139500   -0.94341500   -3.01730400
 H                  1.37498400    0.38894400   -4.15166900

--link1--
%chk=aldehyde_rad.chk
%Mem=57428MB
%NProc=16
#p wB97xD/Def2TZVPP scrf(smd,solvent=acetonitrile) scf=(XQC) geom=allcheck guess=read

--link1--
%chk=aldehyde_rad.chk
%Mem=57428MB
%NProc=16
#p M06L/Def2TZVPP scrf(smd,solvent=acetonitrile) scf=(XQC) geom=allcheck guess=read

--link1--
%chk=aldehyde_rad.chk
%Mem=57428MB
%NProc=16
#p M06/Def2TZVPP scrf(smd,solvent=acetonitrile) scf=(XQC) geom=allcheck guess=read

--link1--
%chk=aldehyde_rad.chk
%Mem=57428MB
%NProc=16
#p PBE1PBE/Def2TZVPP EmpiricalDispersion=GD3BJ scrf(smd,solvent=acetonitrile) scf=(XQC) geom=allcheck guess=read