%chk=CoII_acac.chk
%Mem=57428MB
%NProc=16
#p scrf(smd,solvent=acetonitrile) opt freq wB97xD/def2SVP  nosymm SCF=(XQC)

coments

1 2
Co                 1.77869600   -0.00964600   -0.00687400
 C                 -0.87708700   -0.73715000   -0.01571300
 C                 -2.01538300   -1.54355300   -0.01384800
 C                 -1.85777300   -2.92150000   -0.02218100
 C                 -0.56645200   -3.46023300   -0.03374200
 C                  0.51528200   -2.59932700   -0.03349100
 N                  0.37882600   -1.25753600   -0.02242800
 H                 -3.00817100   -1.09180700   -0.00568100
 H                 -0.39911700   -4.53738600   -0.04432700
 H                  1.54283900   -2.96341700   -0.04216400
 C                 -0.87528800    0.72024500   -0.00975600
 C                 -2.01515900    1.52857000   -0.01402200
 N                  0.37982200    1.23752700    0.00153900
 C                 -1.85583000    2.90291000   -0.00088100
 H                 -3.00696400    1.07735600   -0.02658500
 C                  0.51857900    2.58148400    0.01339000
 C                 -0.56074800    3.44113800    0.01376600
 H                  1.54687700    2.94313200    0.02368000
 H                 -0.39293700    4.51921600    0.02594800
 C                 -3.07517100   -3.80700000    0.01989900
 F                 -3.62469400   -3.82629600    1.24246300
 F                 -2.79198900   -5.07070300   -0.30296900
 F                 -4.02516200   -3.38215200   -0.82151600
 C                 -3.04174500    3.82948500   -0.00968900
 F                 -4.20244000    3.17338500    0.05128400
 F                 -3.00813300    4.67679700    1.02675900
 F                 -3.06776400    4.58009100   -1.11905000
 C                  5.01713400   -0.00986900    0.00989300
 H                  6.10757600   -0.00998000    0.01618800
 C                  4.34522300    1.22462300    0.02906500
 O                  3.08287100    1.35032100    0.02234500
 C                  4.34524700   -1.24422100   -0.01660400
 O                  3.08279700   -1.36968000   -0.02423000
 C                  5.13026300    2.50829400    0.06071400
 H                  6.21480800    2.34110200    0.06070800
 H                  4.85962700    3.12251100   -0.81233600
 H                  4.85380700    3.08145600    0.95956700
 C                  5.13084800   -2.52779900   -0.03817600
 H                  4.86208700   -3.10392200   -0.93745000
 H                  6.21528600   -2.35998400   -0.02966500
 H                  4.85356300   -3.13958200    0.83454100

--link1--
%chk=CoII_acac.chk
%Mem=57428MB
%NProc=16
#p wB97xD/Def2TZVPP scrf(smd,solvent=acetonitrile) scf=(XQC) geom=allcheck guess=read

--link1--
%chk=CoII_acac.chk
%Mem=57428MB
%NProc=16
#p M06L/Def2TZVPP scrf(smd,solvent=acetonitrile) scf=(XQC) geom=allcheck guess=read

--link1--
%chk=CoII_acac.chk
%Mem=57428MB
%NProc=16
#p M06/Def2TZVPP scrf(smd,solvent=acetonitrile) scf=(XQC) geom=allcheck guess=read

--link1--
%chk=CoII_acac.chk
%Mem=57428MB
%NProc=16
#p PBE1PBE/Def2TZVPP EmpiricalDispersion=GD3BJ scrf(smd,solvent=acetonitrile) scf=(XQC) geom=allcheck guess=read