Orca 5.0.3 RELEASE 1 2 3 4 5 7s7p5d1f 11s6p2d1f 11s6p2d1f 11s6p2d1f 5s1p 6s4p3d1f 5s3p2d1f 5s3p2d1f 5s3p2d1f 3s1p 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 Y N N O O O O O O O C C C C C C H C C H H H H C C C C C H H C H H C H H C H H O O O O H H H H C N H 1 2 2 3 3 3 3 3 3 3 4 4 4 4 4 4 5 4 4 5 5 5 5 4 4 4 4 4 5 5 4 5 5 4 5 5 4 5 5 3 3 3 3 5 5 5 5 4 2 5 1 Y ECP Def2-ECP 0 Y 1 1 Y ECP Def2-ECP 0 Y 1 511.10124999999977 AuxInfo=1/0/N:13,15,48,19,18,26,27,24,25,14,12,16,34,37,28,31,11,49,3,2,5,42,7,43,10,40,4,41,6;8;9;1/E:(1,2)(4,5)(6,7,8,9)(11,12)(13,14,15,16)(19,20)(21,22,23,24,25,26,27,28);;;/CRV:1.3,2.3,3.2,10.3,11.3,12.3,13.3,14.3,15.3,16.3,17.3,18.1,21-1,22.1,23-1,24.1,25-1,26.1,27-1,28.1,29-1;;;/rA:50nYN4N4OOOOO3O3OC3C3C3C3C3C3HCCHHHHCCCCC3HHC3HHC3HHC3HHO1O1O1O1HHHHC2N1H/rB:s1;s1;s1;s1;s1;s1;s1;s1;s1;s6;s11;s12;s13;s14;s11s15;s15;s2s16;s3s12;s18;s18;s19;s19;s2;s2;s3;s3;s10s24;s24;s24;s4s25;s25;s25;s5s26;s26;s26;s7s27;s27;s27;s28;s31;s34;s37;s8;s9;s8;s9;s14;s48;s13;/rC:-6.8363,-7.2507,-8.5827;-9.0848,-6.4354,-7.4958;-4.6868,-7.0263,-7.1414;-8.4532,-8.8001,-8.9732;-6.3783,-9.2124,-7.4901;-6.8684,-6.0995,-6.9817;-5.1072,-6.228,-9.6886;-7.3224,-7.0729,-10.842;-5.7102,-8.7661,-9.9228;-7.3991,-5.1173,-9.2765;-6.7705,-5.4071,-5.9717;-5.5231,-5.1721,-5.5191;-5.4339,-4.4876,-4.2991;-6.6367,-4.0824,-3.6524;-7.9077,-4.3706,-4.2341;-7.9588,-5.0782,-5.4441;-8.8285,-4.0773,-3.7466;-9.2337,-5.5488,-6.2073;-4.3958,-5.6931,-6.4425;-9.8057,-4.6183,-6.4237;-9.8487,-6.0746,-5.4426;-3.4294,-5.7085,-5.8914;-4.2933,-4.9135,-7.2284;-9.666,-5.6991,-8.6317;-9.7927,-7.7041,-7.2443;-4.7531,-8.0707,-6.1006;-3.5942,-7.2994,-8.0958;-8.6554,-4.6861,-9.0483;-10.6661,-5.2625,-8.4087;-9.788,-6.3671,-9.5086;-9.6584,-8.6394,-8.403;-10.8619,-7.5508,-6.9699;-9.2785,-8.2019,-6.3921;-5.319,-9.3139,-6.6746;-5.4896,-7.7704,-5.326;-3.7782,-8.2394,-5.5882;-3.8361,-6.4789,-9.3197;-3.5969,-8.362,-8.4193;-2.5885,-7.0994,-7.6605;-8.9444,-3.507,-9.1713;-10.6298,-9.2312,-8.8445;-4.8184,-10.4029,-6.4445;-2.9075,-6.083,-10.0051;-8.232,-7.4348,-10.981;-6.2208,-9.6126,-9.9046;-6.7198,-7.7243,-11.2795;-5.8512,-8.4232,-10.8406;-6.564,-3.3907,-2.3983;-6.5084,-2.8381,-1.3836;-4.4711,-4.2653,-3.8608;/R:/0/N:13,15,48,19,18,26,27,24,25,14,12,16,34,37,28,31,11,49,3,2,42,43,40,41,8,9,5,7,10,4,6,1/E:(1,2)(4,5)(6,7,8,9)(11,12)(13,14,15,16)(19,20)(21,22,23,24)(25,26)(27,28,29,30)/CRV:1.3,2.3,3.2,10.3,11.3,12.3,13.3,14.3,15.3,16.3,17.3,18.1,19.4,20.4,21.1,22.1,23.1,24.1,25.3,26.3,32.9 B 1 0 2.6271 0.060156 B 2 0 2.5977 0.067021 B 3 0 2.2732 0.220757 B 4 0 2.2917 0.206237 B 5 0 1.9721 0.667197 B 6 0 2.2931 0.205161 B 7 0 2.3178 0.187379 B 8 0 2.3152 0.189164 B 9 0 2.3129 0.190792 Method DFT(GTOs) Exchange WB88 Correlation LYP LDAOpt VWN-5 PostSCFGGA off Hybrid DFT is turned on ScalHFX 0.190000 ScalDFX 0.350000 ScalDFC 0.810000 ScalLDAC 1.000000 Perturbative correction 0.000000 Density functional embedding theory OFF Long-range corrected/Screened/Range-Separated Hybrid DFT is turned on Amount of maximum screened exact exchange 0.460000 Range separation parameter mu (erf(mu*r12)/r12) 0.330000 RI-approximation to the Coulomb term is turned on functions 1806 RIJ-COSX (HFX calculated with COS-X)) on IntName lig40_opt_S_camb3 HFTyp RHF Charge -2 Mult 1 NEL 242 Dim 1109 ENuc 3830.1573024812 Eh CNVDIIS on DIISMaxIt 12 DIISStart 0.200000 DIISMaxEq 5 DIISBfac 1.050 DIISMaxC 10.000 CNVTRAH auto Auto Start mean grad. ratio tolernc. 1.125000 Auto Start start iteration 20 Auto Start num. interpolation iter. 10 iterations 16 iterations Maxiter - #DIIS iter Number of Davidson start vectors 2 Converg. threshold I (grad. norm) 1.000e-05 Converg. threshold II (energy diff.) 1.000e-08 Micro threshold 0.100 Minimum threshold for Micro iter. 0.010 NR start threshold (gradient norm) 0.001 Initial trust radius 0.400 Minimum AH scaling param. (alpha) 1.000 Maximum AH scaling param. (alpha) 1000.000 Orbital update algorithm Taylor David. guess on Maximum white noise 0.010 Quad. conv. algorithm NR CNVSOSCF off CNVShift on LevelShift 0.2500 ShiftErr 0.0010 CNVZerner off CNVDamp on DampFac 0.7000 DampMax 0.9800 DampMin 0.0000 DampErr 0.1000 CNVRico off MaxIter 125 SCFMode Direct Integral package SHARK and LIBINT hybrid scheme DirectResetFreq 20 Thresh 2.500e-11 Eh TCut 2.500e-12 Eh ConvCheckMode Total+1el-Energy ConvForced 0 TolE 1.000e-08 Eh 1-El. energy change 1.000e-05 Eh TolErr 5.000e-07 Smallest eigenvalue 4.039e-06 Time for diagonalization 0.294 sec Threshold for overlap eigenvalues 1.000e-08 Number of eigenvalues below threshold 0 Time for construction of square roots 0.157 sec Total time needed 0.453 sec Method DFT(GTOs) Exchange WB88 Correlation LYP LDAOpt VWN-5 PostSCFGGA off Hybrid DFT is turned on ScalHFX 0.190000 ScalDFX 0.350000 ScalDFC 0.810000 ScalLDAC 1.000000 Perturbative correction 0.000000 Density functional embedding theory OFF Long-range corrected/Screened/Range-Separated Hybrid DFT is turned on Amount of maximum screened exact exchange 0.460000 Range separation parameter mu (erf(mu*r12)/r12) 0.330000 RI-approximation to the Coulomb term is turned on functions 1806 RIJ-COSX (HFX calculated with COS-X)) on IntName lig40_opt_S_camb3 HFTyp RHF Charge -2 Mult 1 NEL 242 Dim 1109 ENuc 3903.7609792061 Eh CNVDIIS on DIISMaxIt 12 DIISStart 0.200000 DIISMaxEq 5 DIISBfac 1.050 DIISMaxC 10.000 CNVTRAH auto Auto Start mean grad. ratio tolernc. 1.125000 Auto Start start iteration 1 Auto Start num. interpolation iter. 10 iterations 16 iterations Maxiter - #DIIS iter Number of Davidson start vectors 2 Converg. threshold I (grad. norm) 1.000e-05 Converg. threshold II (energy diff.) 1.000e-08 Micro threshold 0.100 Minimum threshold for Micro iter. 0.010 NR start threshold (gradient norm) 0.001 Initial trust radius 0.400 Minimum AH scaling param. (alpha) 1.000 Maximum AH scaling param. (alpha) 1000.000 Orbital update algorithm Taylor David. guess on Maximum white noise 0.010 Quad. conv. algorithm NR CNVSOSCF off CNVShift on LevelShift 0.2500 ShiftErr 0.0010 CNVZerner off CNVDamp on DampFac 0.7000 DampMax 0.9800 DampMin 0.0000 DampErr 0.1000 CNVRico off MaxIter 125 SCFMode Direct Integral package SHARK and LIBINT hybrid scheme DirectResetFreq 20 Thresh 2.500e-11 Eh TCut 2.500e-12 Eh ConvCheckMode Total+1el-Energy ConvForced 0 TolE 1.000e-08 Eh 1-El. energy change 1.000e-05 Eh TolErr 5.000e-07 Smallest eigenvalue 4.916e-06 Time for diagonalization 0.225 sec Threshold for overlap eigenvalues 1.000e-08 Number of eigenvalues below threshold 0 Time for construction of square roots 0.127 sec Total time needed 0.354 sec 39 7 7 8 8 8 8 8 8 8 6 6 6 6 6 6 1 6 6 1 1 1 1 6 6 6 6 6 1 1 6 1 1 6 1 1 6 1 1 8 8 8 8 1 1 1 1 6 7 1 511.10124999999977 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-2 1 RKS CAM-B3LYP D3BJ DEF2-TZVP OPT geom Constraints {B 0 1 C} {B 0 2 C} {B 0 3 C} {B 0 4 C} {B 0 5 C} {B 0 6 C} {B 0 7 C} {B 0 8 C} {B 0 9 C} 511.10124999999977 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