#
#Opt
#
! opt freq wb97x-d3bj def2-tzvp(-f) def2/J tightopt verytightscf
%pal nprocs 8 end
%maxcore 8000
%basis NewGTO Au "def2-TZVP" end
newecp Au "def2-ECP" end end
%cpcm smd true
smdsolvent "dichloromethane"
end

* xyz 1 1
  C          -2.78599579045055     -1.18849870075125      0.36624134128101
  H          -1.89597040440499     -1.75516949879750      0.67857463127853
  H          -3.54627828228638     -1.93339619475102      0.08350633138501
  C          -2.47128363512821     -0.41460305183903     -0.84352988663659
  C          -2.40505071699583      0.27936389052056     -1.85992927398190
  H          -2.59766298204027      0.86337683893042     -2.75229313132455
  C          -2.83868076751855      2.10169085060555      1.80851897661903
  H          -2.21891079882579      2.95034782193255      2.11187585464723
  H          -3.84635725283181      2.32692176891491      1.44663160855501
  C          -2.40499901460560      0.83593406076004      1.89551623195883
  C          -3.31712645423024     -0.30737540039544      1.51012602571738
  H          -3.49222682293494     -0.96964581197994      2.37293475041817
  H          -4.29705247388616      0.10016050580974      1.22347465788187
  Au         -0.27162560151562     -0.00936678710479     -1.34663415638794
  P           2.04378636647372     -0.06938089853031     -1.37209303010434
  C           2.69233658284583     -0.57805029351518     -2.98919670470612
  C           2.82105715742985      1.52861440900326     -1.00950593528543
  C           2.71928610175608     -1.25108073798471     -0.17272833808542
  H           2.34846183879636     -2.26047174624223     -0.40100405777303
  H           3.81846840601448     -1.24398564539000     -0.22178426588551
  H           2.39578990513491     -0.97274333405714      0.84021611559172
  H           2.30860001368901     -1.57591848028108     -3.24533587226440
  H           3.79183560329181     -0.60637643831497     -2.95728912107743
  H           2.36855806790396      0.13660347577384     -3.75932664811547
  H           2.49555221273278      2.27300889879450     -1.75006093447845
  H           3.91609324539196      1.42835944142923     -1.04765165964847
  H           2.51936540693158      1.86663299765868     -0.00842278479434
  C          -1.02208054306312      0.51423793120633      2.35778883828339
  C          -0.73575726922458     -0.67783240610279      3.04084735679865
  C           0.04260264810983      1.39953929405519      2.12622088555276
  C           0.55231209008054     -0.95942768959778      3.49118128820956
  H          -1.53121882104274     -1.40038202858100      3.24128875378038
  C           1.32682747229461      1.11896594463658      2.58635261695588
  H          -0.13286154445487      2.32172308150738      1.56560975703843
  C           1.60862533977248     -0.06473077142604      3.27987533069449
  H           0.73882482344995     -1.89739886345548      4.02272722373989
  H           2.13248962997570      1.83406421710289      2.39382984954490
  C           2.99519027203299     -0.36475487175420      3.78374570714023
  H           3.08934761665917     -0.10488468714354      4.85098625882804
  H           3.23481398791711     -1.43430126189599      3.68862361598928
  H           3.75589754932286      0.21055922813722      3.23645858015446
*

