#
#Opt
#
! opt freq wb97x-d3bj def2-tzvp(-f) def2/J tightopt verytightscf
%pal nprocs 8 end
%maxcore 8000
%basis NewGTO Au "def2-TZVP" end
newecp Au "def2-ECP" end end
%cpcm smd true
smdsolvent "dichloromethane"
end

* xyz 1 1
  C          -2.70114044431392     -1.03121920210840      1.27606276568632
  H          -1.86820169450411     -1.75048604743324      1.27689364548574
  H          -3.62278643557642     -1.61782149596275      1.41722943725992
  C          -2.80362329746368     -0.40700359226803     -0.04956567352945
  C          -3.06734336687044      0.17215761122017     -1.10504354812166
  H          -3.54293682294296      0.64397789892023     -1.95685485893939
  C          -1.47974672939944      2.18891700928268      2.08369594173763
  H          -0.63384945550657      2.87964984615621      2.04082323175809
  H          -2.47420345569375      2.62171176544120      1.94084000506514
  C          -1.33362058083290      0.87712779541729      2.32597737750569
  C          -2.56301634037949     -0.00131264516097      2.41112459336438
  H          -2.57414926546108     -0.55961644644251      3.35968336310086
  H          -3.45713075597756      0.63799454677706      2.41606152964298
  Au         -0.86753528698675     -0.03343911547534     -1.22189357891181
  P           1.34696949321209     -0.08699633853386     -1.89587170756755
  C           1.51608955825467     -0.48973628219135     -3.65775528870634
  C           2.21931080783749      1.48549658379858     -1.66578982014099
  C           2.29662943226008     -1.35036107290471     -1.00536699062649
  H           1.85938176309604     -2.33985821671687     -1.20179274808185
  H           3.34385703753909     -1.33987216727008     -1.34240139105301
  H           2.25326601087060     -1.15442592136551      0.07534839579548
  H           1.06320887607937     -1.47127984891033     -3.85798304193062
  H           2.58111480392061     -0.51545593710258     -3.93318023307559
  H           1.00126291567544      0.27032838533120     -4.26259210485926
  H           1.72890499164968      2.26475935154953     -2.26676200553881
  H           3.26789058753470      1.38442137020252     -1.98306299342103
  H           2.18105573299029      1.77995058218712     -0.60822613062719
  C           0.01108089262230      0.24767372479645      2.51569212479675
  C           0.14620258036245     -1.00245438436600      3.13588575015621
  C           1.18308919355062      0.90111199126536      2.09290520738765
  C           1.40791814155143     -1.56529530784453      3.33362555734872
  H          -0.73274586200862     -1.54605251520998      3.48874344927659
  C           2.45382580967151      0.35938754251989      2.29726332536423
  H           1.10764987917123      1.86784601754180      1.58795864980733
  C           2.55372575788135     -0.89190974075799      2.92371942437717
  H           1.49270504412539     -2.53916108382079      3.82306903696858
  H           3.53901416243856     -1.33885813381244      3.08663876200381
  C           3.69115030832871      1.07957551245611      1.82887461438122
  H           4.09107059337196      0.62104650274878      0.90917800214095
  H           3.48655554386984      2.13800551751566      1.61415116200092
  H           4.48889734605218      1.03080763053038      2.58496588271867
*

