#
#Opt
#
! opt freq wb97x-d3bj def2-tzvp(-f) def2/J tightopt verytightscf
%pal nprocs 8 end
%maxcore 8000
%basis NewGTO Au "def2-TZVP" end
newecp Au "def2-ECP" end end
%cpcm smd true
smdsolvent "dichloromethane"
end

* xyz 1 1
  C          -2.98091993959095     -0.97396309180266     -0.68107098291137
  H          -2.29952824436589     -1.69020106307711     -0.19740783967656
  H          -3.75821164181979     -1.57162296952352     -1.18267811914475
  C          -2.26009259091335     -0.24813735822680     -1.73622323084917
  C          -1.84241197670550      0.43007417922380     -2.67673185208155
  H          -1.71530330325409      1.00515989347593     -3.58655670002899
  C          -2.74404691629749      2.20221424431088      0.91825643834904
  H          -2.09069266261234      2.89568153784826      1.45464379407666
  H          -3.49318559922777      2.64291526663357      0.25409698973936
  C          -2.66646008897640      0.87280213740536      1.07592737987593
  C          -3.63357724861664     -0.03090126273348      0.34457166180115
  H          -4.19016629252810     -0.66002626369070      1.05670745815175
  H          -4.37964746315778      0.59121342187950     -0.16962473915822
  Au          0.00981993332087      0.02067916500883     -1.53943172936642
  P           2.21244750151963     -0.15594316368002     -0.84449705245488
  C           3.32516837703874     -0.61254600231279     -2.20356838435479
  C           2.87305786446007      1.38945122101776     -0.16261890906936
  C           2.43980650861419     -1.42978511109084      0.42653985883745
  H           2.13946575514602     -2.40725295879120      0.02280512275867
  H           3.49593320707847     -1.46613625569144      0.73257928701847
  H           1.81432990444400     -1.20153669765677      1.30012475647315
  H           3.02093282743479     -1.58459616027503     -2.61725216160084
  H           4.35871086614233     -0.67985964091942     -1.83198468167847
  H           3.27083891759830      0.14545592028333     -2.99795876054829
  H           2.93061427650405      2.14219180576509     -0.96220017483373
  H           3.87716312514270      1.22167910919172      0.25472188729813
  H           2.20585300537157      1.76556873258365      0.62430410079068
  C          -1.63550094829814      0.24814191516556      1.95992667323156
  C          -1.83326587422159     -1.01695357100389      2.53363919775761
  C          -0.43398786231860      0.91374975045105      2.25171322751907
  C          -0.87914834390170     -1.59347886121381      3.37667342058242
  H          -2.75560891025888     -1.56828655603715      2.33649021829523
  C           0.51868971066388      0.34426096033770      3.09658942770602
  H          -0.22488227283198      1.89083400527799      1.80583009289409
  C           0.30007460001457     -0.91855144224135      3.66223139630089
  H          -1.06836476913292     -2.57803717502812      3.81126361611646
  H           1.06196379750960     -1.35140201796375      4.31510162406253
  C           1.78498881491086      1.07296170152623      3.36432086993235
  O           2.71971029978747      0.60770698965123      3.97224967352775
  H           1.82512857632776      2.11162272592242      2.95660039466095
*

