#
#Opt
#
! opt freq wb97x-d3bj def2-tzvp(-f) def2/J tightopt verytightscf
%pal nprocs 8 end
%maxcore 8000
%basis NewGTO Au "def2-TZVP" end
newecp Au "def2-ECP" end end
%cpcm smd true
smdsolvent "dichloromethane"
end

* xyz 1 1
  C          -2.90453414009318     -0.97020550406826     -0.37232343544476
  H          -2.16059695978165     -1.67047979063366      0.03409531334624
  H          -3.58239137166024     -1.57119415176755     -0.99827469800477
  C          -2.22443281464819     -0.01343248223816     -1.25749463333004
  C          -1.82829395211534      0.86894639706540     -2.02036340033611
  H          -1.71674426721837      1.66285368999808     -2.74949697320322
  C          -3.51802693781132      2.01973800432248      1.64105979507099
  H          -3.02464506805155      2.81969249123711      2.20079926782469
  H          -4.50449316491463      2.24057989432753      1.22243922494644
  C          -2.95814892613502      0.81152677686358      1.48789682014816
  C          -3.70054344970035     -0.28579318734560      0.75489967681527
  H          -4.00563212210713     -1.07770310202652      1.45838168060330
  H          -4.62671570398541      0.13646555753557      0.33961967797807
  Au          0.07961027493713      0.05989315600424     -1.22211967419836
  P           2.33011543222001     -0.41261817817553     -0.93648673326854
  C           3.08705763093398     -0.90319725814413     -2.51296615349682
  C           3.30028779087169      0.99943168319554     -0.34195648823172
  C           2.67708977290015     -1.77393036433274      0.21261950763944
  H           2.04294925739181     -2.64015781181850     -0.02204693395074
  H           3.73572320303689     -2.06013183058277      0.12005355918299
  H           2.48792430397512     -1.44835577966351      1.24483073496937
  H           2.60709848841217     -1.82003120749177     -2.88471226853112
  H           4.16216156067040     -1.08773517364947     -2.36768498687153
  H           2.95151638960176     -0.10501932852836     -3.25676938207300
  H           3.21601474687610      1.83049594030167     -1.05703571787818
  H           4.35697610094911      0.70899897047794     -0.24209491242442
  H           2.91546229548772      1.32995456207917      0.63355141703164
  C          -1.59271416508900      0.51050488881351      2.00736523929219
  C          -1.25034443262209     -0.76541128631711      2.47140429188926
  C          -0.60283767635620      1.50985158535947      2.01652596317108
  C           0.03589882983221     -1.03937981418348      2.93874322396432
  H          -1.99500871143277     -1.56480386864075      2.48487693117920
  C           0.67449676934288      1.24205404965815      2.48782933665890
  H          -0.82305855729480      2.50892108158112      1.62890807416267
  C           1.00483320042252     -0.04282844715154      2.95288018023536
  H           0.30201633669105     -2.03501047423862      3.30158135471923
  O           1.68916721164585      2.14466996213307      2.51465264824832
  H           1.39107998785843      3.00960087886863      2.19924841721135
  O           2.25981550464718     -0.31483971481711      3.37154064002822
  H           2.78269494231307      0.50067043599285      3.34261447492667
*

