#
#Opt
#
! opt freq wb97x-d3bj def2-tzvp(-f) def2/J tightopt verytightscf
%pal nprocs 8 end
%maxcore 8000
%basis NewGTO Au "def2-TZVP" end
newecp Au "def2-ECP" end end
%cpcm smd true
smdsolvent "dichloromethane"
end

* xyz 1 1
  C          -0.53331600118762     -1.32489135568435      0.72477765610636
  H           0.53172303271087     -1.49938841031968      0.95855517011894
  H          -0.85328342871867     -2.19054496433642      0.12482144092285
  C          -0.69026948878934     -0.03736042610214     -0.04878193234200
  C          -1.20378371489404      1.03444417260865      0.57863302403426
  H          -1.34213070127691      1.99417712307419      0.06864126571916
  C          -1.60133692104092      1.08104180014168      2.05795905351586
  H          -1.27096894652061      2.02624302976687      2.50246463913002
  H          -2.70609981741580      1.06191099937877      2.13550038546821
  C          -1.10996526555507     -0.11290121536755      2.77834230704756
  C          -1.37103309877481     -1.35997498866548      2.03703181150954
  H          -1.16807098641310     -2.27422938400172      2.60230492982480
  H          -2.43286826661479     -1.35442620917210      1.74221525704377
  Au         -0.07765052776056      0.02420096240274     -2.02168798828469
  P           0.61946157936789      0.08994151062670     -4.25749825136622
  C          -0.69644581808667      0.54912988193835     -5.43003817231535
  C           1.96192156910934      1.27635750905604     -4.58558686252376
  C           1.25391939553832     -1.50054164061601     -4.87866355794803
  H           0.47549292730923     -2.27143677582789     -4.78159998479070
  H           1.55172097235326     -1.41531760743206     -5.93472613614597
  H           2.12456651305062     -1.80675926643356     -4.28023748252155
  H          -1.52140789766525     -0.17468726134256     -5.35683198198120
  H          -0.31259207466794      0.55962843602099     -6.46140192691743
  H          -1.08392221713844      1.54674145805994     -5.17673155280404
  H           1.63425960441083      2.29011515549114     -4.31246785916030
  H           2.24457733867049      1.26059295622793     -5.64910189188563
  H           2.83820850985853      1.01705936565302     -3.97343987149172
  C          -0.38446501612899     -0.05937782281809      3.99693132221070
  C           0.14581755717619     -1.24239810371406      4.58924279198892
  C          -0.15178958959623      1.17361004830994      4.66797914695597
  C           0.86577624880304     -1.18611012877639      5.76210640984985
  H          -0.00415837940477     -2.21190878354501      4.11420206096130
  C           0.55977731222551      1.21612595512070      5.84986942410177
  H          -0.54184401176106      2.10613256702546      4.26023170541225
  C           1.08571129096539      0.04205521845986      6.41769461920347
  H           1.27040675649897     -2.10474698665330      6.19382119280871
  H           0.71910626999548      2.17374932366567      6.35054083735099
  C           1.86917081918378      0.08103977219182      7.69053424700815
  H           1.91893156168804      1.09362946712707      8.11118974409391
  H           1.42050895877627     -0.59358325108959      8.43628332945353
  H           2.89532688171950     -0.27852437044953      7.51313724063769
*

