#
#Opt
#
! opt freq wb97x-d3bj def2-tzvp(-f) def2/J tightopt verytightscf
%pal nprocs 8 end
%maxcore 8000
%basis NewGTO Au "def2-TZVP" end
newecp Au "def2-ECP" end end
%cpcm smd true
smdsolvent "dichloromethane"
end

* xyz 1 1
  C          -0.03273713363842     -1.45367177203603      0.53356548584731
  H           1.04352028782506     -1.33692452252222      0.75447714024629
  H          -0.11074283690514     -2.36751973453805     -0.07495654883073
  C          -0.53378574037832     -0.24876843932115     -0.23223641645452
  C          -1.26380571341717      0.66556737235674      0.43191620886538
  H          -1.66442561883090      1.55401883374827     -0.06923076282977
  C          -1.57264004765873      0.62900151795574      1.92212443566629
  H          -1.37750910762199      1.61284047295808      2.36649554091415
  H          -2.65717284666180      0.44623438792619      2.06891559652161
  C          -0.88429080865277     -0.47160762220392      2.64331655599412
  C          -0.81287370122274     -1.71638948525388      1.84351807924364
  H          -0.39329018186476     -2.57117165963304      2.38189686452854
  H          -1.85175257920793     -1.96557129794565      1.56369755448122
  Au         -0.05826838232976     -0.04534408015595     -2.23205655016326
  P           0.47807489900479      0.19379661030629     -4.50107368024754
  C          -0.59163892748489      1.36576679999558     -5.39608392198893
  C           2.16952479750450      0.79852354222854     -4.80671103429377
  C           0.36872835728018     -1.35058804837466     -5.46094012246663
  H          -0.65059498896189     -1.75779640759962     -5.39150902441249
  H           0.61547439761384     -1.16879611604226     -6.51800560805406
  H           1.06923393518700     -2.09124578389100     -5.04801757888511
  H          -1.63742107023797      1.03015762016901     -5.33781726816541
  H          -0.29208595402506      1.43626112434244     -6.45274129529520
  H          -0.51798940022133      2.35988490510905     -4.93132152379119
  H           2.30385174803912      1.77769329269712     -4.32415942364154
  H           2.35705636227015      0.89841157223713     -5.88662695166015
  H           2.89657120836584      0.09414238963066     -4.37667933857317
  C          -0.34836393668646     -0.33105082836355      3.93600436164609
  C           0.31703183975880     -1.41860372575464      4.57911445638285
  C          -0.45788246281063      0.90621578604860      4.65504654803093
  C           0.84225584304419     -1.29076704774696      5.84373377704399
  H           0.42324999298338     -2.37690384946702      4.07198554941649
  C           0.05611041625903      1.03294003656478      5.91619467287267
  H          -0.95857950080473      1.76804952840243      4.21172815933708
  C           0.71973897887497     -0.07178676347011      6.52678249440712
  H           1.35405551706242     -2.11862552997400      6.33697388859435
  O           1.21727195843474      0.05890757725708      7.73618922215379
  H           1.04868187014116      0.95991586089703      8.06677070885570
  O           0.01406629819159      2.13355534178756      6.69157617942091
  H          -0.43114035821736      2.87034455167538      6.24719317928297
*

