#
#Opt
#
! opt freq wb97x-d3bj def2-tzvp(-f) def2/J tightopt verytightscf
%pal nprocs 8 end
%maxcore 8000
%basis NewGTO Au "def2-TZVP" end
newecp Au "def2-ECP" end end
%cpcm smd true
smdsolvent "dichloromethane"
end

* xyz 1 1
  C           0.05471193855856     -1.26216279749572     -0.04019862602463
  H           1.05291065670513     -0.89218565305799      0.25509003999804
  H           0.23974759093453     -2.17360251630159     -0.62911523779942
  C          -0.65733715212201     -0.21706391878546     -0.87112300390842
  C          -1.65018498672679      0.48713593124479     -0.29818450263198
  H          -2.20579560896961      1.25025543342971     -0.85513164194364
  C          -2.08995821925341      0.36727833530375      1.15702134325280
  H          -2.23551707853574      1.36689294125515      1.58266444347868
  H          -3.07989684426629     -0.12947723329617      1.19855261795446
  C          -1.16866850610975     -0.47937253934101      1.95877459050753
  C          -0.73891787756783     -1.68977572269938      1.22013744066824
  H          -0.16013086257483     -2.39837293102099      1.82080224006101
  H          -1.65502484455941     -2.19883260704241      0.87538021827852
  Au         -0.07063153995455      0.10415245784226     -2.82551690233382
  P           0.57736989687284      0.48017679441841     -5.04632639031997
  C          -0.71903469720454      0.09557672587529     -6.26736625193685
  C           1.04121539326923      2.20515428195541     -5.40576140685880
  C           2.01638237754301     -0.50079813163458     -5.58104316883025
  H           1.79207303009969     -1.57237214055671     -5.47589374573920
  H           2.26594528827538     -0.28365694677042     -6.63073282736085
  H           2.88166703704605     -0.26140306814333     -4.94568689242059
  H          -1.00299091697343     -0.96357891176977     -6.18228412827255
  H          -0.36372452457688      0.29479954369919     -7.28977615119613
  H          -1.60745212582207      0.71190846667535     -6.06593181621394
  H           0.19392614530694      2.86919074276449     -5.18030929156596
  H           1.32096681139740      2.32084830948653     -6.46389689440371
  H           1.89124865119841      2.49745928163278     -4.77183779228378
  C          -0.71844334345066     -0.14780424327991      3.24657304009568
  C           0.20294130926494     -0.99238526054319      3.95601478840404
  C          -1.16507668350219      1.03756168511079      3.89711302040862
  C           0.64470764082633     -0.67305592264958      5.21396297344486
  H           0.56515248778726     -1.90453910458520      3.48683348482379
  C          -0.73719156743825      1.36654627476781      5.16326969177722
  H          -1.86583129519936      1.70917090806335      3.40255374330462
  C           0.16918498792752      0.53073482445963      5.84113448351208
  H          -1.10026814296829      2.27864899064222      5.63629657643277
  O           0.63833732268399      0.76151663106540      7.04085025565545
  C           0.24361555999095      1.92585398874200      7.76278283662719
  H          -0.84135212377563      1.92204966658930      7.94368400013445
  H           0.77578563184988      1.88030865498453      8.71902111919892
  H           0.53735919528641      2.83698604370311      7.22083648242223
  O           1.50254445867326     -1.38772459522319      5.95061931072192
  C           2.02134039896885     -2.58520114286772      5.40953582555461
  H           2.69832151018000     -2.99983838272898      6.16576065833743
  H           1.22011744064388     -3.31476023819863      5.20444923987671
  H           2.59007518026109     -2.39521912571930      4.48388568711255
*

