#
#Opt
#
! opt freq wb97x-d3bj def2-tzvp(-f) def2/J tightopt verytightscf
%pal nprocs 8 end
%maxcore 8000
%basis NewGTO Au "def2-TZVP" end
newecp Au "def2-ECP" end end
%cpcm smd true
smdsolvent "dichloromethane"
end

* xyz 1 1
  C           0.55155380340575     -2.09200262268106     -0.14318322817364
  H           1.53285159003527     -1.63035023465402      0.05958101923239
  H           0.72278257458504     -2.85291244827084     -0.92012151319777
  C          -0.41116447264078     -1.03211578016137     -0.60016502549829
  C          -1.44082075874351     -0.67479155566351      0.18342115669637
  H          -2.12003014761087      0.14721341130013     -0.06608197190077
  C          -1.80032518324503     -1.35628617682165      1.53412965987262
  H          -2.30615435332487     -0.63436839101311      2.18152906949548
  H          -2.48061335497578     -2.20020577515077      1.34321202272824
  C          -0.50797219275225     -1.83377155445243      2.03197330498052
  C           0.09022434206829     -2.84835467776540      1.15965285006176
  H           0.93847192925810     -3.38555915862728      1.59520313455203
  H          -0.68735434608937     -3.56688730644040      0.86560710194960
  Au         -0.08662967166060     -0.11130994472594     -2.42514380829980
  P           0.24597689130213      0.94971580765786     -4.48508683916600
  C          -1.29949590746164      1.29664650732580     -5.38356241505516
  C           1.07418056266166      2.56652454015327     -4.35573950476210
  C           1.26218843500292     -0.00088353683573     -5.65939150434667
  H           0.79098357685668     -0.97656599853731     -5.84815219292155
  H           1.36507030352326      0.54299058470261     -6.61055962442417
  H           2.25971741733044     -0.17137412075808     -5.22862563664966
  H          -1.83169080995907      0.35437802646768     -5.57949093058115
  H          -1.08876646430189      1.80086849565455     -6.33880255027869
  H          -1.94485152643827      1.94068533008596     -4.76842085158304
  H           0.47326354565794      3.23641591766821     -3.72348876230727
  H           1.19705184977491      3.02067451395769     -5.35066629471069
  H           2.06248636409201      2.43967580022858     -3.89006972985261
  C           0.20183780627666     -1.21591583759205      3.11928942948999
  C           1.53754170446587     -1.58260089074404      3.41159420430969
  C          -0.41013888295502     -0.20857273483085      3.90270902582111
  C           2.23566459159553     -0.95722227125334      4.43347378350528
  H           2.03676565798578     -2.36040928542395      2.83319721697054
  C           0.29513187886064      0.40709297753761      4.92130384896875
  H          -1.44253145967137      0.08754947607468      3.71990971949511
  C           1.61888791807909      0.03697401120060      5.18958990261540
  H           3.26612713543164     -1.24485961361989      4.64871064996062
  H           2.16719553913056      0.52493095428769      5.99932604691034
  C          -0.33964620477515      1.50995995956408      5.73324252406725
  F           0.09756538459127      2.71427851397700      5.34275374834175
  F          -0.04661065441776      1.39150275392588      7.03234911358014
  F          -1.67036328094822      1.51653971425316      5.61942091010411
*

