#
#Opt
#
! opt freq wb97x-d3bj def2-tzvp(-f) def2/J tightopt verytightscf
%pal nprocs 8 end
%maxcore 8000
%basis NewGTO Au "def2-TZVP" end
newecp Au "def2-ECP" end end
%cpcm smd true
smdsolvent "dichloromethane"
end

* xyz 1 1
  C          -1.89686939853920     -1.45970754024321     -0.02524813556405
  H          -1.56738251015538     -2.42067956700972     -0.44810159251908
  H          -2.86826955065282     -1.26051718418866     -0.52325257425978
  C          -0.98876637723123     -0.35528987449678     -0.43847286921309
  C          -0.84470117256681      0.56816617089777      0.62593524265414
  H          -0.04171334558932      1.30654680936538      0.66158388158864
  C          -2.19216747962212      1.02695636163514      1.27902191381234
  H          -2.10090772395805      2.03253310929324      1.69587059417579
  H          -3.10792382182348      0.83205268048713      0.71556724683225
  C          -1.48262891250139     -0.06856862859623      1.92181709832299
  C          -1.95938083009003     -1.45764673600988      1.50864269336837
  H          -1.27903617043679     -2.22054359717225      1.91359736092125
  H          -2.96573422296162     -1.66170789872601      1.90237826730555
  Au         -0.07021377216652     -0.22000895903197     -2.24618787706227
  P           0.97925400967745     -0.06158188622601     -4.34399390101229
  C           0.06194463310282      0.97324150372739     -5.52455198151851
  C           2.64739883350412      0.65734060575982     -4.26409937455390
  C           1.18652550883679     -1.66775436577789     -5.17042427851564
  H           0.20315383476027     -2.13868711775330     -5.31350052115815
  H           1.67264514270088     -1.53555914011879     -6.14874972087647
  H           1.80476152344745     -2.32676411605836     -4.54374280417011
  H          -0.94245190115217      0.55358017681552     -5.68037375052751
  H           0.59340264760920      1.01340178179727     -6.48723466763982
  H          -0.03940572576091      1.99139010042620     -5.12169037094103
  H           2.59421298133558      1.66748480281612     -3.83288733564216
  H           3.08828219420382      0.71342196511656     -5.27072216548836
  H           3.28624549201911      0.03343485594644     -3.62228888310731
  C          -0.78026193427668      0.10664879588525      3.23124089649222
  C           0.46297625136916     -0.50583235474587      3.44143280580107
  C          -1.36842128135413      0.84359492798882      4.26476394413670
  C           1.11495948448130     -0.38391303126761      4.66162615345735
  H           0.93095077570048     -1.07664171464436      2.63515967530938
  C          -0.72932073925993      0.97327281130928      5.49435694780841
  H          -2.34130166015151      1.31689748666348      4.11345430040327
  C           0.50313719460654      0.35582924578832      5.66963620722696
  H           2.08493963156819     -0.84996959117554      4.83624738005147
  H          -1.17870615380302      1.54054148071497      6.30973927786848
  N           1.18651820730441      0.48827373822496      6.96693750432608
  O           0.64404584954972      1.14436811448696      7.82826422285177
  O           2.25448125827583     -0.06671455190355      7.10250048905498
*

