#
#Opt
#
! opt freq wb97x-d3bj def2-tzvp(-f) def2/J tightopt verytightscf
%pal nprocs 8 end
%maxcore 8000
%basis NewGTO Au "def2-TZVP" end
newecp Au "def2-ECP" end end
%cpcm smd true
smdsolvent "dichloromethane"
end

* xyz 1 1
  C          -2.41257140387499     -0.70956448507239     -1.42682311796626
  H          -2.42657813198988     -1.71959366055051     -1.86302134133727
  H          -3.22526349116087     -0.17217561489830     -1.95833534045848
  C          -1.15647931621097      0.00769806342735     -1.77293450774323
  C          -0.74913737064187      0.81101501282734     -0.67654937306770
  H           0.26089349458446      1.21489382672241     -0.58686917882917
  C          -1.87577177686774      1.71152984120460     -0.07175524399192
  H          -1.45680837098754      2.61661671921552      0.37367589822349
  H          -2.77569974602866      1.85734131667335     -0.67388303415217
  C          -1.63120590097363      0.42723038286792      0.56983990809861
  C          -2.54591932173899     -0.70116539300394      0.10256345030462
  H          -2.19793721083337     -1.65930976100545      0.51468661882633
  H          -3.57768083099150     -0.54206031516164      0.44795794879368
  Au         -0.15119818403319     -0.18051233195119     -3.52759685542245
  P           1.01356123568902     -0.41092432901308     -5.55698594348078
  C           0.21536920758677      0.45984206383334     -6.93910402714637
  C           2.71346776118453      0.23012083561553     -5.49706041043860
  C           1.17054982142408     -2.13817740979478     -6.10263664403492
  H           0.17109826501758     -2.57812748212198     -6.23199739142299
  H           1.71706432369667     -2.18756008594922     -7.05638230285871
  H           1.71449579870237     -2.71692880131056     -5.34209698219570
  H          -0.80176285106159      0.06777303611569     -7.08355051496904
  H           0.79480452179280      0.31768517109344     -7.86365874491554
  H           0.15097652542494      1.53377543580577     -6.71199427622393
  H           2.69663868844626      1.29902383938450     -5.23958893892180
  H           3.20562718558519      0.09869983078438     -6.47244074655528
  H           3.28327300427997     -0.30880360387890     -4.72626056623100
  C          -0.97153605751788      0.33045468549452      1.90818521759534
  C          -1.24915841850118      1.25035146959539      2.91734391166020
  C          -0.07988690722358     -0.71249437721613      2.16672782413375
  C          -0.64492127538072      1.14551810047715      4.16897585371452
  H          -1.95661355967770      2.06102118091882      2.73535759203942
  C           0.52731543074734     -0.84516887860125      3.41035473311704
  H           0.15646381134178     -1.43074119657592      1.37897317139012
  C           0.23689287428086      0.09187463704844      4.40450876633670
  C          -0.96828246528841      2.18786488758610      5.22399857373783
  C           1.48756603296949     -1.99885806144733      3.63527858799606
  N           0.87342448799104     -0.03991044055290      5.72967593920466
  F          -2.11407273419849      2.81068404645201      4.94477421248126
  F          -0.02046067982526      3.12186452735683      5.30384905057061
  F          -1.10036836057461      1.63737252182139      6.43538242064839
  F           1.95371578118285     -2.46567691956784      2.47593432528582
  F           0.89997982025216     -3.01734462598508      4.26353202999047
  F           2.54322152863604     -1.62406530217163      4.36518620151429
  O           1.59965326577200      0.85727006273569      6.08166767690969
  O           0.62004081899443     -1.03704675922744      6.36057837979038
*

