#
#Opt
#
! opt freq wb97x-d3bj def2-tzvp(-f) def2/J tightopt verytightscf
%pal nprocs 8 end
%maxcore 8000
%basis NewGTO Au "def2-TZVP" end
newecp Au "def2-ECP" end end
%cpcm smd true
smdsolvent "dichloromethane"
end

* xyz 1 1
  C          -2.19010726158865     -0.98515608124575      0.12798515962588
  H          -2.10512953665228     -1.94633805883779     -0.39916123789372
  H          -3.12437278376532     -0.53188470760425     -0.26336607039514
  C          -1.09073080410365     -0.04949294945937     -0.24837558549588
  C          -0.74891700746623      0.76221983451635      0.85036504217352
  H           0.17644354920757      1.33981695665425      0.89133257402523
  C          -1.93720755618168      1.36318968224606      1.67005463933013
  H          -1.63663537362213      2.29076898150162      2.16201110501299
  H          -2.90708704723077      1.39113094610781      1.16686352334114
  C          -1.41011074943928      0.10514862085001      2.16131633791211
  C          -2.15739759621758     -1.12440660129562      1.65569624160483
  H          -1.61062177389212     -2.03596413682467      1.93609471766145
  H          -3.15786496776628     -1.18357838772306      2.10949418628378
  Au         -0.17927800853593      0.00514413940349     -2.06691289396237
  P           0.86643863209082      0.08697016017088     -4.16944236789136
  C           0.16302633733005      1.35078442196649     -5.27199623526690
  C           2.64244063213844      0.46694908135181     -4.08060536359083
  C           0.75536740228494     -1.47107120976615     -5.10025041028318
  H          -0.30149802211036     -1.72843936853125     -5.26196547010250
  H           1.25773581525955     -1.37169838198276     -6.07428039911355
  H           1.23155576146911     -2.28000055564301     -4.52745814449708
  H          -0.90373963278497      1.14337555598011     -5.43981291181800
  H           0.69041049275426      1.34823909619035     -6.23777015464895
  H           0.26041349547188      2.34264897618335     -4.80729562381465
  H           2.78705378686964      1.44034185737947     -3.58994500116200
  H           3.07628534497545      0.50095140783852     -5.09128605672512
  H           3.15702493050940     -0.30527764895624     -3.49062179613669
  C          -0.58658663080039      0.02602683674127      3.40374991749804
  C           0.44065585772831     -0.92722510625531      3.51476366632611
  C          -0.82793688617827      0.86546590002165      4.49241846249662
  C           1.19613315499756     -1.03027577761560      4.67037047297985
  H           0.65740855396122     -1.59259748707439      2.67364753786757
  C          -0.07714274618475      0.77277065159888      5.66630237886670
  H          -1.62897516819419      1.60758169305454      4.43858781838319
  C           0.94332315901062     -0.17978015056766      5.76124465340908
  H           1.99840987932938     -1.76667564794749      4.75762017126803
  H          -0.30145946562982      1.44341761162370      6.49686704403912
  O           1.72356102019744     -0.35366747456371      6.84179438361149
  C           1.53278679757176      0.47303149959364      7.96925244001711
  H           2.26936354263580      0.15417052057837      8.71711436771208
  H           1.70661239019919      1.53524468637146      7.72874543214067
  H           0.52187057235228      0.35633663396999      8.39440002921117
*

