#
#Opt
#
! opt freq wb97x-d3bj def2-tzvp(-f) def2/J tightopt verytightscf
%pal nprocs 8 end
%maxcore 8000
%basis NewGTO Au "def2-TZVP" end
newecp Au "def2-ECP" end end
%cpcm smd true
smdsolvent "dichloromethane"
end

* xyz 1 1
  C          -2.08686244868857     -1.13803994100234      0.29075292430345
  H          -1.92322097567360     -2.09949710472249     -0.21746100672356
  H          -3.05220446649627     -0.76971846740989     -0.11492991831379
  C          -1.06861670704539     -0.12550708668181     -0.10653825643898
  C          -0.78043092118672      0.72009198066245      0.98819400197247
  H           0.10120705558423      1.36294967245133      1.01801653577854
  C          -2.02048440824643      1.26162090234442      1.77424110585827
  H          -1.79328329497114      2.21917385745470      2.24796776103652
  H          -2.98553798867942      1.20617077610822      1.26439221141509
  C          -1.40065720791325      0.05551346315560      2.29410917917820
  C          -2.05008826711239     -1.24132325410129      1.82153997862540
  H          -1.43268481755674     -2.09925946489148      2.12404339670068
  H          -3.04481699739485     -1.36892116327308      2.27336817745522
  Au         -0.17506280335074     -0.01752374892169     -1.92980102411667
  P           0.86856952979087      0.10908358787559     -4.03197111786431
  C           0.13765720117243      1.36295430493291     -5.12756570737170
  C           2.63466908931387      0.53077917093429     -3.93465445028940
  C           0.79758181095632     -1.44538218179505     -4.97242155533017
  H          -0.25225868444644     -1.72656639750112     -5.14002494907297
  H           1.30143554643338     -1.32830010790877     -5.94371313611803
  H           1.29038201889246     -2.24637210699288     -4.40251152240756
  H          -0.92368160910753      1.13203829728158     -5.29896423831958
  H           0.66703180065659      1.37823521987817     -6.09211753315388
  H           0.21153790664736      2.35381865328001     -4.65649694960195
  H           2.75476685968836      1.50427744340628     -3.43765233750389
  H           3.07069376069852      0.58122688153501     -4.94370582436102
  H           3.16561452981813     -0.23254241199308     -3.34759478490954
  C          -0.58477468896098      0.06581723407745      3.54751964045899
  C           0.55865795091098     -0.73870633332894      3.64337083088112
  C          -0.95745449218394      0.84833142866072      4.64519545428521
  C           1.31804511007274     -0.75705480489247      4.80613331172488
  H           0.86388481600197     -1.35058651764160      2.78972721374236
  C          -0.20416505916502      0.83309760629126      5.81574143619623
  H          -1.85335676311612      1.47195420035019      4.59125675124019
  C           0.94270919583591      0.03127809800696      5.90711465356685
  H           2.21281172045307     -1.38055858129008      4.86724748396577
  H          -0.50516539164993      1.44599292319048      6.66834876711617
  C           1.72716089368618      0.01738694106165      7.11555885455191
  C           2.38434494171729      0.00802527648276      8.13302629980950
  H           2.96984601461480      0.00057114492603      9.03876722203396
*

