#
#Lower level of theory opt
#
! opt freq wb97x-d3bj def2-svp def2/J tightopt verytightscf
%pal nprocs 8 end
%maxcore 8000
%basis NewGTO Au "def2-TZVP" end
newecp Au "def2-ECP" end end
%cpcm smd true
smdsolvent "dichloromethane"
end

* xyz 1 1
  C          -0.53880313552833     -1.57979235528905      0.33679016636150
  H           0.49205904874960     -1.45965205477146      0.68646370144224
  H          -0.55702980562204     -2.48810191100137     -0.26970448444771
  C          -0.94552958799343     -0.38074774712560     -0.47986806562886 newgto "def2-tzvp(-f)" end
  C          -1.81280391876831      0.49511835479761      0.03079580933369 newgto "def2-tzvp(-f)" end
  H          -2.12635493356771      1.37901808742030     -0.51752844427831
  C          -2.43727860340930      0.40802002443238      1.43606282680843 newgto "def2-tzvp(-f)" end
  H          -2.50104492404597      1.40358027024802      1.86573631495416
  H          -3.45535899429696      0.00911726907719      1.35005738784094
  C          -1.64051351179504     -0.53873607981920      2.24178218161906 newgto "def2-tzvp(-f)" end
  C          -1.47500029043508     -1.83340848948962      1.56016285614508
  H          -1.07776150888967     -2.62547766066527      2.18748095806888
  H          -2.44732312111055     -2.13671537282618      1.16472087842251
  Au         -0.11244748328493     -0.14128584050457     -2.35409783439259
  P           0.82350288696254      0.12209658936308     -4.44794643152558
  C          -0.24669246557717     -0.40391678454798     -5.81352893565790
  C           1.26606456589280      1.83222437670492     -4.85571082543077
  C           2.35849918196908     -0.81089314622798     -4.69300320193054
  H           2.16406793636778     -1.87540869649149     -4.54819955719516
  H           2.74691353562393     -0.64616027797000     -5.70087257617170
  H           3.10075608025138     -0.48799014970124     -3.96035990286728
  H          -0.49373862153468     -1.46077144595972     -5.69525422377749
  H           0.25703307236455     -0.25338629390268     -6.77139709702860
  H          -1.17171134992226      0.17568042638728     -5.79431486655295
  H           0.37171923592867      2.45738934082774     -4.82017922967340
  H           1.70610355543484      1.88355475324385     -5.85448088960246
  H           1.98371284837313      2.20624095586633     -4.12289892956371
  C          -0.99255442381146     -0.20053236974335      3.44484166739208
  C          -0.10188930623521     -1.11082611421663      4.07658837099147
  C          -1.18803059395130      1.06245645515781      4.06330601082814
  C           0.55743573074077     -0.77376452756970      5.22915492737651
  H           0.07908602519606     -2.08434315765958      3.64224484176033
  C          -0.53589143638592      1.38598019631910      5.22582222294892
  H          -1.86721768646074      1.78365752832429      3.63054054708958
  C           0.35338070928978      0.48162315599233      5.83089326943609
  H           1.23736411937273     -1.48760524591262      5.67779014694719
  H          -0.70230468185225      2.35183373632505      5.68893964277994
  C           1.03842134627955      0.87483177323125      7.07057414094275
  C           1.35610931977715     -0.16440042772865      8.12961737881422
  C           2.46320553904022      0.41852967916112      7.32789834231007
  H           0.78004155856309      1.86246760122710      7.43072428306874
  H           1.05407139975313     -1.18395935471855      7.92297797743044
  H           1.23905752545839      0.15529890585708      9.15766197429678
  H           3.11584054492448      1.14348924688108      7.79829338908075
  H           2.92532900798267     -0.19767684568942      6.56608469654346
*

