#
#Single point
#
! wb97x-d3bj def2-TZVPPD def2/J defgrid3 verytightscf
%pal nprocs 8 end
%maxcore 4000
%cpcm smd true
smdsolvent "dichloromethane"
end

* xyz 1 1
  C          -3.25769703199249     -0.89749778720281     -0.61709488603150
  H          -2.72027771092091     -1.76833259283213     -0.24004960960049
  H          -4.26136425878364     -1.23059375024224     -0.89475504575894
  C          -2.59594441525265     -0.45490202671896     -1.84872861558685
  C          -2.15264870656413     -0.08755401193272     -2.92357472891428
  H          -1.97325921979241      0.20895432344187     -3.93854278435059
  C          -1.62500777749504      1.93136966429053      0.19816504150871
  H          -0.66557944988431      2.39425786904166      0.39689427720363
  H          -2.24983362389009      2.40316736150368     -0.55274881595824
  C          -2.04616236665251      0.83648512496487      0.83840015245260
  C          -3.36786032006137      0.21567925434642      0.44665504760696
  H          -3.86763734047082     -0.21409070531594      1.31684683767510
  H          -4.01423848310393      0.99917335941978      0.04894660209079
  Au         -0.32119991013117     -0.08636308507445     -1.61544716635070
  P           1.84899952932793     -0.05197688870064     -0.90053532479582
  C           3.03283029559092     -0.36713138081493     -2.22855120154674
  C           2.34781038097773      1.52299072944791     -0.17097978165906
  C           2.17058052385691     -1.30543439934054      0.35862743438937
  H           1.98445631769096     -2.29567252636812     -0.06064138705298
  H           3.20888296120963     -1.23722641495831      0.69171024212669
  H           1.50294023483549     -1.14741329738767      1.20635963502157
  H           2.82825480499414     -1.34193798930817     -2.67428826431487
  H           4.04892600993094     -0.35335705337293     -1.82726014266759
  H           2.93257747497990      0.40289600016822     -2.99538357560025
  H           2.20680845586981      2.32336983144154     -0.89935021046047
  H           3.39942458208837      1.47474916027536      0.12139416927626
  H           1.73629126270600      1.72748621791603      0.70818108711154
  C          -1.21902009448026      0.18392804662618      1.89273352125718
  C          -1.41144559796337     -1.15132112515848      2.25167656179917
  C          -0.22017798638074      0.89587951090698      2.56417871988725
  C          -0.61606910174756     -1.76793281310620      3.21622819558634
  H          -2.19262777590829     -1.73547586216617      1.78299388709864
  C           0.57433077248534      0.28590676979286      3.52514532888346
  H          -0.06281182284257      1.94836488254087      2.35541748063001
  C           0.38516673233627     -1.05761125739524      3.85289864296407
  H          -0.78953111896353     -2.80905032132490      3.46460535092405
  H           1.01427133620411     -1.52044904418843      4.60447191059882
  C           1.62861409644128      1.09176037759542      4.18542627354941
  O           2.41094534846353      0.65665838244508      5.00179741881712
  H           1.66797791329253      2.15339452674474      3.87628097219052
*

