#
#Single point
#
! wb97x-d3bj def2-TZVPPD def2/J defgrid3 verytightscf
%pal nprocs 8 end
%maxcore 4000
%cpcm smd true
smdsolvent "dichloromethane"
end

* xyz 1 1
  Au         -0.03367013896967     -2.45329406296702      0.13747094684493
  C           1.20753242829644     -0.36770933139971      1.25627010980826
  C          -0.02017477427804     -0.63522962959923      1.22217211552078
  C           0.44683851393384      1.90510265302987      2.17793250549890
  C           1.62138848897815      1.38666400629869      2.61607357070061
  H           1.63403200966456      0.71613501807759      3.46748424112602
  C          -1.22548138552919      0.07367695780300      1.70432414792673
  H          -1.89699739233861     -0.60213788552733      2.23523919872736
  H          -1.76888476283469      0.44518778978837      0.83291583933309
  C          -0.80826227083186      1.24764236221861      2.65066060550490
  P          -0.20851266751722     -4.41639850123644     -1.02948259342775
  C           0.62551706962652     -4.37602523810608     -2.63368702133124
  C           0.49031651968339     -5.83969506222667     -0.16013802910900
  H           2.24634051444062     -0.47901946863244      1.00688176910335
  C          -1.92184790371850     -4.86694711798507     -1.39224135306421
  H          -2.38694975877876     -4.07777506669762     -1.98569839564729
  H          -1.94934842557460     -5.80660040650299     -1.94888561183984
  H          -2.47503820447643     -4.97993610040019     -0.45818511585122
  H           0.20042883598012     -3.57781547948761     -3.24473871365683
  H           0.49734154171549     -5.33401988130564     -3.14325802413122
  H           1.68913920758105     -4.18074298033441     -2.48584297351640
  H           1.55118078456770     -5.66566953659343      0.02836753226956
  H           0.36988329888318     -6.74116012572436     -0.76556180553535
  H          -0.02225578143474     -5.96996955799136      0.79461777203333
  H           2.58047888969342      1.74312651003218      2.25967133361685
  H          -1.64221706200371      1.94719398354813      2.71385176130643
  H          -0.63424036835118      0.82689237959151      3.64106780178804
  C           0.38311087453994      2.96812621417590      1.15308792670456
  C          -0.79915559988525      3.21513275380612      0.44579763863270
  C           1.49090726886855      3.76100710869720      0.84806619570380
  C          -0.83468407935519      4.18977507473646     -0.52192407945194
  H          -1.70201747875548      2.64225035414452      0.61250446321377
  C           1.42921068062134      4.75252131440423     -0.11859788323251
  H           2.41893296019175      3.63198582668433      1.39112134557420
  C           0.25768522941983      5.00720268833315     -0.84249765004767
  H           2.30946805037390      5.35308871995853     -0.30498293255325
  N           0.16383394107239      5.97031645581494     -1.85316345270067
  C           1.42026802831073      6.55605932115650     -2.29802188987900
  C          -0.86034669874308      6.99965295296737     -1.65803601403022
  H           1.22067223198081      7.14798794276764     -3.19298976100829
  H           1.87376556768835      7.21634419933293     -1.54479443966543
  H           2.13319807885653      5.77154561350729     -2.55649282351631
  H          -0.55567771964849      7.72077001345501     -0.88628488459204
  H          -1.00253869108875      7.53704457173844     -2.59758865974888
  H          -1.81015720021311      6.55792964722528     -1.36777494532637
  F          -1.98992732064203      4.33334729942364     -1.22220808807524
*

