#
#Single point
#
! wb97x-d3bj def2-TZVPPD def2/J defgrid3 verytightscf
%pal nprocs 8 end
%maxcore 4000
%cpcm smd true
smdsolvent "dichloromethane"
end

* xyz 1 1
  C           0.23246552197786      2.26035414827675     -0.93694796441943
  H          -0.67314623076001      2.61663631840761     -1.43155250038671
  H           1.05817873024464      2.79387160162332     -1.43048123452959
  C           0.44196029277494      0.81374339089274     -1.21386144485103
  C           0.94194334466589      0.17563322984292     -0.06553114840131
  H           0.96722168352729     -0.89782093367010      0.04227605125849
  C           2.18155894790596      0.93076086505146      0.54947160353650
  H           2.84485491423663      0.23214520645806      1.04350873513003
  H           2.65186578897209      1.67662373449992     -0.07939981363912
  C           0.87369659427298      1.18175695967755      1.14070360592723
  C           0.19943587480149      2.43187928775767      0.58982859365565
  H          -0.83335859516157      2.47555861084316      0.93999122794381
  H           0.71213426256211      3.33645933864196      0.92135750246739
  Au          0.03759238209396     -0.08570111284290     -2.99155463142629
  P          -0.41674370025664     -1.09894620856630     -5.02775426803241
  C          -1.60020909193345     -0.18055932739921     -6.04324786383444
  C           1.05030816367545     -1.29576122274648     -6.06935626718058
  C          -1.11455191914731     -2.76138695554504     -4.87170369232799
  H          -2.04946915090282     -2.71303432660256     -4.31026618496643
  H          -1.30540797948360     -3.18188820875967     -5.86180691285557
  H          -0.41248651726291     -3.40075749612992     -4.33337553941301
  H          -2.54564021943018     -0.08846589770424     -5.50541488542013
  H          -1.76784561773071     -0.70192995109046     -6.98851618132925
  H          -1.20916542014788      0.81886935585647     -6.24268693204162
  H           1.48843510858896     -0.31633390707874     -6.27007083716990
  H           0.77718102589136     -1.77345019620885     -7.01316479759855
  H           1.78600779793010     -1.91156903288669     -5.54878465551456
  C           0.52746816001677      0.70185238814773      2.51343049422645
  C           0.54686355612470      1.61394698667339      3.57016738561901
  C           0.18182080361929     -0.61439826031212      2.80530528073244
  C           0.23884977939135      1.23541651087657      4.86548391389734
  H           0.80657626591951      2.65080803262757      3.37931583948877
  C          -0.12594416863541     -1.01632226798203      4.09719326594680
  H           0.14416800869140     -1.35648413456684      2.01537872037930
  C          -0.10602514896789     -0.09865619642031      5.16444493909127
  H           0.25507550695413      1.98053837400493      5.65098909067245
  H          -0.38508854609857     -2.05200482902783      4.27740844708218
  N          -0.41973046805649     -0.48011035661148      6.43644931186524
  C          -0.79283505989747     -1.84306435947649      6.79617948827148
  C          -0.22066233934563      0.37436712222081      7.60425006646746
  H          -1.61102471604096     -2.20372746173421      6.16692617205211
  H           0.05549893599737     -2.53075434152603      6.67565426229706
  C          -1.20103200888927     -1.71595165870363      8.26227615923901
  H           0.74297210025012      0.88936716204168      7.55348899186816
  H          -1.00703387573463      1.13682930076819      7.66948337354297
  C          -0.28763781883371     -0.60267090842764      8.77927445681049
  H          -2.24727067628468     -1.40384013003921      8.32775845184128
  H          -1.08654453236191     -2.65441533047360      8.80649171926068
  H           0.70931954248525     -1.00408930853892      8.98173163831005
  H          -0.65804451220783     -0.12909886411886      9.68948621645650
*

