#
#Single point
#
! wb97x-d3bj def2-TZVPPD def2/J defgrid3 verytightscf
%pal nprocs 8 end
%maxcore 4000
%cpcm smd true
smdsolvent "dichloromethane"
end

* xyz 1 1
  C          -2.51856097829192     -0.64347714495689      0.06527029235238
  H          -2.46143225725709     -1.54606049322035     -0.54146684889906
  H          -3.46888747636580     -0.15462363642889     -0.18647934632946
  C          -1.39819109675598      0.32536985958437     -0.23764411835030
  C          -1.20072013285344      1.24766224041260      0.73254205022085
  H          -0.33245746000631      1.89147183916047      0.79893945803118
  C          -2.26030165663929      1.44729895335141      1.85205532671218
  H          -2.01030228621201      2.30121908417995      2.46943130043575
  H          -3.27451842921323      1.47343335249456      1.46092003446738
  C          -1.78492245690023      0.15364701337853      2.27560722225820
  C          -2.42547444127380     -0.99678060378360      1.55593640729435
  H          -1.85853381096043     -1.91493029269310      1.69106744315549
  H          -3.40989926026586     -1.14821522314337      2.01444405789164
  Au         -0.27084732949553      0.21258889740045     -1.94992524776276
  P           0.99431130921275      0.07782492104578     -3.87903698361047
  C           0.19815988556696      0.82064141846394     -5.32669823212074
  C           2.60296884125472      0.90270469990687     -3.76293554919701
  C           1.38280299751949     -1.61781788426519     -4.38466467512436
  H           0.45550751051633     -2.16771660389337     -4.55634642393701
  H           1.97770717907280     -1.61226025896442     -5.30106723912107
  H           1.94342941251627     -2.11432870471087     -3.59033653345856
  H          -0.75261796943416      0.31871091488139     -5.51593654511633
  H           0.84244449576084      0.72309385585403     -6.20366350701399
  H           0.00494749536184      1.87741931877665     -5.13273042393401
  H           2.45390120210527      1.96031564012493     -3.53711859999649
  H           3.14610289552941      0.80476740842484     -4.70588073396098
  H           3.18635962728443      0.45062860770098     -2.95856907575900
  C          -0.82278497518249     -0.02649724713215      3.34523053089154
  C          -0.02169329976419     -1.18277869921253      3.41517657815875
  C          -0.67679192374617      0.93788577886870      4.35105107653823
  C           0.88121502778070     -1.35776791987780      4.43571405249597
  H          -0.08734180866781     -1.93753177855659      2.64150118486526
  C           0.21653353341687      0.76795690124862      5.39358143505656
  H          -1.29176351115283      1.82918172654546      4.34260288143577
  C           1.00666835672516     -0.38457961058881      5.43909959026943
  H           1.50887016838769     -2.24013309383370      4.48206870078534
  H           0.28759458763645      1.52568648320166      6.16177981701668
  O           1.90810355216575     -0.64698041471283      6.39955527943169
  C           2.08131749030715      0.31724727731227      7.44378468286668
  H           2.85059616514645     -0.09122557606023      8.09667937882501
  H           2.41560241331865      1.27479730851409      7.03662252366366
  H           1.15441641385259      0.45034568520217      8.00738577857164
*

