#
#Opt
#
! optts freq wb97x-d3bj def2-tzvp(-f) def2/J tightopt verytightscf
%pal nprocs 8 end
%maxcore 8000
%basis NewGTO Au "def2-TZVP" end
newecp Au "def2-ECP" end end
%geom calc_hess true
trust 0.2 end
%cpcm smd true
smdsolvent "dichloromethane"
end

* xyz 1 1
  Au         -0.05355406611282     -1.91554977215534      0.12673055771431
  C           1.15961823017464      0.28548637129717      1.11336120094273
  C          -0.06975628995460     -0.03808692959565      1.09774431795739
  C           0.30773890412361      2.53906852463533      1.99613941576863
  C           1.53953366237099      2.10514975927428      2.38623415344090
  H           1.64211699608021      1.45566584422238      3.25934281725808
  C          -1.28790106394492      0.67093637993611      1.56632157290691
  H          -1.99301664060387     -0.00836574086867      2.06559182275082
  H          -1.80632820265506      1.07355086909517      0.68058301954209
  C          -0.88546035411417      1.82479033722829      2.53555713228927
  P          -0.19316217556484     -3.99116431304239     -0.90226645466372
  C           0.77205683133480     -4.10722611128378     -2.43717320760330
  C           0.39949461486344     -5.34971118624065      0.14905210226150
  H           2.20892234717867      0.19154800643871      0.85377517628062
  C          -1.89302555336061     -4.43974109296674     -1.36172508029216
  H          -2.29486932529905     -3.69484220810187     -2.06359940116150
  H          -1.90664492389761     -5.43208089180136     -1.83698578622856
  H          -2.52612047691846     -4.45736699023747     -0.46288572922763
  H           0.41331039336747     -3.35693418038888     -3.15646216057067
  H           0.66798423907988     -5.11119567419878     -2.87565246174704
  H           1.83248866044100     -3.91184961660825     -2.22206643377318
  H           1.45512374522516     -5.18190455429249      0.40699758260446
  H           0.30201234716698     -6.30981772017661     -0.37971158794990
  H          -0.18993161262639     -5.38237374223482      1.07668505518335
  H           2.45851078560670      2.54729232143388      1.99275739729259
  H          -1.75744691330208      2.48222290458317      2.64984622198043
  H          -0.65081881143823      1.39193330822191      3.51758903709552
  C           0.12620567275294      3.54013971428185      0.91417510163441
  C          -1.02470377082263      4.33855445775247      0.85975402873049
  C           1.09882421499684      3.71856019848540     -0.08654720962341
  C          -1.18705080389875      5.28977254837588     -0.14358074205993
  H          -1.80165170374839      4.23781691368497      1.62053887933109
  C           0.93058773985198      4.66078970293987     -1.09079498051154
  H           1.99469841906829      3.09285002133187     -0.09493713755732
  C          -0.21597387243088      5.47266457746596     -1.13684463748309
  H          -2.08993942617473      5.90688206710476     -0.15547600128445
  H           1.70384251182258      4.75900795571866     -1.85647932035387
  C          -0.43830778940814      6.49693533696224     -2.17948473844465
  C           0.41258256435942      6.85048710980599     -3.14809204885887
  H          -1.40774773915479      7.00544751286810     -2.12145242704071
  H           0.14150371352141      7.62708923971461     -3.86860666149915
  H           1.40062670204401      6.39449586133467     -3.26566045503094
*

