%maxcore 4000
%pal nprocs 16 end
! r2SCAN DEF2-TZVP CPCM(DMSO) def2/j verytightscf rijcosx DefGrid3 FREQ
*xyz 0 1
  S           0.72768088642832      2.46566397905185     -4.03181678413313
  C           1.43494325828526      1.76266260091527     -1.89365686588690
  N          -0.49722775207645      2.02594636939939     -3.09146122349378
  O           0.10561604439984      1.78561178498571     -1.80209869179700
  C           0.70297760328340      1.43498526106283     -5.45230401230826
  N           1.96679341741984      2.02200288577354     -3.06072823825735
  O           0.84567411015756      3.83266322803684     -4.49906951290857
  C           0.51698407839961      0.06220951912300     -5.28408968161872
  H           0.37679195138066     -0.35215058721970     -4.29214217023088
  C           0.51326097948300     -0.75566585626407     -6.40068147625995
  H           0.37214877354409     -1.82469731086482     -6.27894494029702
  C           0.68525598219551     -0.22482995261666     -7.68641534952027
  C           0.86914281928647      1.15365513262279     -7.82383821708644
  H           1.00622126069605      1.57819327594678     -8.81279840110681
  C           0.88112479299473      1.99081683010380     -6.71612045746405
  H           1.02507386306213      3.05813482491415     -6.82546957650063
  C           0.65209297617131     -1.12259487364919     -8.88431275364657
  H           1.01699916001838     -0.61162932209062     -9.77539951693701
  H           1.25189657616474     -2.01991743797472     -8.71650720268593
  H          -0.37245315308774     -1.45523729867593     -9.07937185695697
  C           2.17639012017686      1.45641723976339     -0.68015737541376
  C           1.50327941027844      1.11075550592864      0.49895188959941
  H           0.42110330733178      1.06934992829883      0.51470904844003
  C           2.22977096484375      0.81808981152906      1.64361764222487
  H           1.70879390687232      0.55008624867752      2.55566402821903
  C           3.62198964045964      0.86567122837334      1.62175472564994
  H           4.18519070630935      0.63531733424622      2.51933930502932
  C           4.29205935001651      1.20845510614752      0.44936660576807
  H           5.37528033354963      1.24657354229669      0.43264852273647
  C           3.57584265762794      1.50505102149421     -0.70043699262059
  H           4.08798397432690      1.77717598066421     -1.61537747053623
*
