Orca 5.0.4 RELEASE 1 2 3 4 15s8p3d2f1g 15s8p3d2f1g 15s8p3d2f1g 7s3p2d1f 7s4p3d2f1g 7s4p3d2f1g 7s4p3d2f1g 4s3p2d1f 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 F C N C C C C C C C C C C C C F N C C C C C C C C C C C C H H H H H H H H H H H H H H H H H H H H 1 2 3 2 2 2 2 2 2 2 2 2 2 2 2 1 3 2 2 2 2 2 2 2 2 2 2 2 2 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 366.2777063999998 AuxInfo=1/0/N:7,13,21,27,6,8,12,14,20,22,26,28,5,9,11,15,19,23,25,29,4,10,18,24,2,1,16,3,17/E:(1,2,3,4)(5,6,7,8,9,10,11,12)(13,14,15,16,17,18,19,20)(21,22,23,24)(26,27)(28,29)/CRV:1.3,2.3,3.3,4.3,5.3,6.3,7.3,8.3,9.3,10.3,11.3,12.3,13.3,14.3,15.3,16.3,17.3,18.3,19.3,20.3,21.3,22.3,23.3,24.3/rA:49nFCNC3C3C3C3C3C3C3C3C3C3C3C3FNC3C3C3C3C3C3C3C3C3C3C3C3HHHHHHHHHHHHHHHHHHHH/rB:s1;s2;s3;s4;s5;s6;s7;s4s8;s3;s10;s11;s12;s13;s10s14;s2;s2;s17;s18;s19;s20;s21;s18s22;s17;s24;s25;s26;s27;s24s28;s5;s6;s7;s8;s9;s11;s12;s13;s14;s15;s19;s20;s21;s22;s23;s25;s26;s27;s28;s29;/rC:-.4724,1.9558,-.957;-.0446,.6589,-.8797;1.0414,.6024,.0107;1.4907,-.6563,.4896;1.6613,-1.7609,-.3386;2.0745,-2.9719,.197;2.3461,-3.0857,1.5516;2.1992,-1.9772,2.3729;1.7666,-.7721,1.8475;1.9805,1.6732,.0412;1.7118,2.821,.7761;2.644,3.8454,.8294;3.8528,3.7257,.1603;4.1258,2.5756,-.5657;3.1915,1.5545,-.6301;.3114,.3858,-2.172;-1.0652,-.2313,-.5011;-2.0493,-.6211,-1.4548;-1.7714,-1.6092,-2.391;-2.746,-2.0039,-3.2941;-4.0066,-1.4269,-3.2598;-4.289,-.4494,-2.3171;-3.3133,-.0432,-1.4211;-1.4197,-.3505,.8678;-1.6248,-1.6293,1.3752;-1.9693,-1.808,2.7035;-2.0964,-.713,3.5463;-1.8925,.5623,3.0428;-1.5681,.7489,1.7069;1.4766,-1.6803,-1.4005;2.1972,-3.8273,-.4547;2.6733,-4.0308,1.9641;2.4047,-2.0547,3.4323;1.6224,.0864,2.4904;.7786,2.9028,1.3163;2.427,4.737,1.4028;4.5813,4.5242,.2083;5.0675,2.4745,-1.0889;3.4047,.6557,-1.1941;-.7978,-2.0793,-2.4034;-2.5212,-2.7723,-4.022;-4.7674,-1.7408,-3.9619;-5.2704,.0048,-2.2822;-3.5326,.7168,-.6825;-1.4914,-2.4826,.7235;-2.1207,-2.8087,3.0858;-2.3541,-.8527,4.5877;-1.9989,1.4243,3.6884;-1.4378,1.7513,1.3243; Method DFT(GTOs) Exchange B88 XAlpha 0.666667 XBeta 0.004200 Correlation LYP LDAOpt VWN-5 PostSCFGGA off Hybrid DFT is turned on ScalHFX 0.690000 ScalDFX 0.310000 ScalDFC 0.540000 ScalLDAC 0.540000 Perturbative correction 1.000000 Density functional embedding theory OFF NL short-range parameter 12.000000 RI-approximation to the Coulomb term is turned on functions 1641 RIJ-COSX (HFX calculated with COS-X)) on IntName C25F2H20N2_sp_orca HFTyp RHF Charge 0 Mult 1 NEL 202 Dim 2253 ENuc 2801.0680033104 Eh CNVDIIS on DIISMaxIt 12 DIISStart 0.200000 DIISMaxEq 5 DIISBfac 1.050 DIISMaxC 10.000 CNVTRAH auto Auto Start mean grad. ratio tolernc. 1.125000 Auto Start start iteration 20 Auto Start num. interpolation iter. 10 iterations 16 iterations Maxiter - #DIIS iter Number of Davidson start vectors 2 Converg. threshold I (grad. norm) 1.000e-05 Converg. threshold II (energy diff.) 1.000e-08 Micro threshold 0.100 Minimum threshold for Micro iter. 0.010 NR start threshold (gradient norm) 0.001 Initial trust radius 0.400 Minimum AH scaling param. (alpha) 1.000 Maximum AH scaling param. (alpha) 1000.000 Orbital update algorithm Taylor David. guess on Maximum white noise 0.010 Quad. conv. algorithm NR CNVSOSCF on SOSCFMaxIt 150 SOSCFStart 0.003300 CNVShift on LevelShift 0.2500 ShiftErr 0.0010 CNVZerner off CNVDamp on DampFac 0.7000 DampMax 0.9800 DampMin 0.0000 DampErr 0.1000 CNVRico off MaxIter 250 SCFMode Direct Integral package SHARK and LIBINT hybrid scheme DirectResetFreq 20 Thresh 2.500e-11 Eh TCut 2.500e-12 Eh ConvCheckMode Total+1el-Energy ConvForced 0 TolE 1.000e-08 Eh 1-El. energy change 1.000e-05 Eh TolG 1.000e-05 TolX 1.000e-05 TolErr 5.000e-07 Smallest eigenvalue 4.644e-06 Time for diagonalization 0.703 sec Threshold for overlap eigenvalues 1.000e-08 Number of eigenvalues below threshold 0 Time for construction of square roots 0.658 sec Total time needed 1.378 sec 9 6 7 6 6 6 6 6 6 6 6 6 6 6 6 9 7 6 6 6 6 6 6 6 6 6 6 6 6 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 366.2777063999998 AuxInfo=1/0/N:7,13,21,27,6,8,12,14,20,22,26,28,5,9,11,15,19,23,25,29,4,10,18,24,2,1,16,3,17/E:(1,2,3,4)(5,6,7,8,9,10,11,12)(13,14,15,16,17,18,19,20)(21,22,23,24)(26,27)(28,29)/CRV:1.3,2.3,3.3,4.3,5.3,6.3,7.3,8.3,9.3,10.3,11.3,12.3,13.3,14.3,15.3,16.3,17.3,18.3,19.3,20.3,21.3,22.3,23.3,24.3/rA:49nFCNC3C3C3C3C3C3C3C3C3C3C3C3FNC3C3C3C3C3C3C3C3C3C3C3C3HHHHHHHHHHHHHHHHHHHH/rB:s1;s2;s3;s4;s5;s6;s7;s4s8;s3;s10;s11;s12;s13;s10s14;s2;s2;s17;s18;s19;s20;s21;s18s22;s17;s24;s25;s26;s27;s24s28;s5;s6;s7;s8;s9;s11;s12;s13;s14;s15;s19;s20;s21;s22;s23;s25;s26;s27;s28;s29;/rC:-.4724,1.9558,-.957;-.0446,.6589,-.8797;1.0414,.6024,.0107;1.4907,-.6563,.4896;1.6613,-1.7609,-.3386;2.0745,-2.9719,.197;2.3461,-3.0857,1.5516;2.1992,-1.9772,2.3729;1.7666,-.7721,1.8475;1.9805,1.6732,.0412;1.7118,2.821,.7761;2.644,3.8454,.8294;3.8528,3.7257,.1603;4.1258,2.5756,-.5657;3.1915,1.5545,-.6301;.3114,.3858,-2.172;-1.0652,-.2313,-.5011;-2.0493,-.6211,-1.4548;-1.7714,-1.6092,-2.391;-2.746,-2.0039,-3.2941;-4.0066,-1.4269,-3.2598;-4.289,-.4494,-2.3171;-3.3133,-.0432,-1.4211;-1.4197,-.3505,.8678;-1.6248,-1.6293,1.3752;-1.9693,-1.808,2.7035;-2.0964,-.713,3.5463;-1.8925,.5623,3.0428;-1.5681,.7489,1.7069;1.4766,-1.6803,-1.4005;2.1972,-3.8273,-.4547;2.6733,-4.0308,1.9641;2.4047,-2.0547,3.4323;1.6224,.0864,2.4904;.7786,2.9028,1.3163;2.427,4.737,1.4028;4.5813,4.5242,.2083;5.0675,2.4745,-1.0889;3.4047,.6557,-1.1941;-.7978,-2.0793,-2.4034;-2.5212,-2.7723,-4.022;-4.7674,-1.7408,-3.9619;-5.2704,.0048,-2.2822;-3.5326,.7168,-.6825;-1.4914,-2.4826,.7235;-2.1207,-2.8087,3.0858;-2.3541,-.8527,4.5877;-1.9989,1.4243,3.6884;-1.4378,1.7513,1.3243; 0 1 SP DSD-BLYP D3BJ def2-QZVPP def2-QZVPP/C def2/J TightSCF output xyzfile=True scf maxiter 250 output Print[P_Hirshfeld] = 1 maxcore 4800 %pal nprocs 8 366.2777063999998 AuxInfo=1/0/N:7,13,21,27,6,8,12,14,20,22,26,28,5,9,11,15,19,23,25,29,4,10,18,24,2,1,16,3,17/E:(1,2,3,4)(5,6,7,8,9,10,11,12)(13,14,15,16,17,18,19,20)(21,22,23,24)(26,27)(28,29)/CRV:1.3,2.3,3.3,4.3,5.3,6.3,7.3,8.3,9.3,10.3,11.3,12.3,13.3,14.3,15.3,16.3,17.3,18.3,19.3,20.3,21.3,22.3,23.3,24.3/rA:49nFCNC3C3C3C3C3C3C3C3C3C3C3C3FNC3C3C3C3C3C3C3C3C3C3C3C3HHHHHHHHHHHHHHHHHHHH/rB:s1;s2;s3;s4;s5;s6;s7;s4s8;s3;s10;s11;s12;s13;s10s14;s2;s2;s17;s18;s19;s20;s21;s18s22;s17;s24;s25;s26;s27;s24s28;s5;s6;s7;s8;s9;s11;s12;s13;s14;s15;s19;s20;s21;s22;s23;s25;s26;s27;s28;s29;/rC:-.4724,1.9558,-.957;-.0446,.6589,-.8797;1.0414,.6024,.0107;1.4907,-.6563,.4896;1.6613,-1.7609,-.3386;2.0745,-2.9719,.197;2.3461,-3.0857,1.5516;2.1992,-1.9772,2.3729;1.7666,-.7721,1.8475;1.9805,1.6732,.0412;1.7118,2.821,.7761;2.644,3.8454,.8294;3.8528,3.7257,.1603;4.1258,2.5756,-.5657;3.1915,1.5545,-.6301;.3114,.3858,-2.172;-1.0652,-.2313,-.5011;-2.0493,-.6211,-1.4548;-1.7714,-1.6092,-2.391;-2.746,-2.0039,-3.2941;-4.0066,-1.4269,-3.2598;-4.289,-.4494,-2.3171;-3.3133,-.0432,-1.4211;-1.4197,-.3505,.8678;-1.6248,-1.6293,1.3752;-1.9693,-1.808,2.7035;-2.0964,-.713,3.5463;-1.8925,.5623,3.0428;-1.5681,.7489,1.7069;1.4766,-1.6803,-1.4005;2.1972,-3.8273,-.4547;2.6733,-4.0308,1.9641;2.4047,-2.0547,3.4323;1.6224,.0864,2.4904;.7786,2.9028,1.3163;2.427,4.737,1.4028;4.5813,4.5242,.2083;5.0675,2.4745,-1.0889;3.4047,.6557,-1.1941;-.7978,-2.0793,-2.4034;-2.5212,-2.7723,-4.022;-4.7674,-1.7408,-3.9619;-5.2704,.0048,-2.2822;-3.5326,.7168,-.6825;-1.4914,-2.4826,.7235;-2.1207,-2.8087,3.0858;-2.3541,-.8527,4.5877;-1.9989,1.4243,3.6884;-1.4378,1.7513,1.3243; -1270.43621506 2801.06800331 -4071.50421837 -7302.96616004 3231.46194167 -2537.79447386 1267.35825879 2.00242864 100.999923882524 100.999923882524 201.999847765047 -52.953596022978 -3.747752229241 -56.701348252219 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200 201 202 203 204 205 206 207 208 209 210 211 212 213 214 215 216 217 218 219 220 221 222 223 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974 975 976 977 978 979 980 981 982 983 984 985 986 987 988 989 990 991 992 993 994 995 996 997 998 999 1000 1001 1002 1003 1004 1005 1006 1007 1008 1009 1010 1011 1012 1013 1014 1015 1016 1017 1018 1019 1020 1021 1022 1023 1024 1025 1026 1027 1028 1029 1030 1031 1032 1033 1034 1035 1036 1037 1038 1039 1040 1041 1042 1043 1044 1045 1046 1047 1048 1049 1050 1051 1052 1053 1054 1055 1056 1057 1058 1059 1060 1061 1062 1063 1064 1065 1066 1067 1068 1069 1070 1071 1072 1073 1074 1075 1076 1077 1078 1079 1080 1081 1082 1083 1084 1085 1086 1087 1088 1089 1090 1091 1092 1093 1094 1095 1096 1097 1098 1099 1100 1101 1102 1103 1104 1105 1106 1107 1108 1109 1110 1111 1112 1113 1114 1115 1116 1117 1118 1119 1120 1121 1122 1123 1124 1125 1126 1127 1128 1129 1130 1131 1132 1133 1134 1135 1136 1137 1138 1139 1140 1141 1142 1143 1144 1145 1146 1147 1148 1149 1150 1151 1152 1153 1154 1155 1156 1157 1158 1159 1160 1161 1162 1163 1164 1165 1166 1167 1168 1169 1170 1171 1172 1173 1174 1175 1176 1177 1178 1179 1180 1181 1182 1183 1184 1185 1186 1187 1188 1189 1190 1191 1192 1193 1194 1195 1196 1197 1198 1199 1200 1201 1202 1203 1204 1205 1206 1207 1208 1209 1210 1211 1212 1213 1214 1215 1216 1217 1218 1219 1220 1221 1222 1223 1224 1225 1226 1227 1228 1229 1230 1231 1232 1233 1234 1235 1236 1237 1238 1239 1240 1241 1242 1243 1244 1245 1246 1247 1248 1249 1250 1251 1252 1253 1254 1255 1256 1257 1258 1259 1260 1261 1262 1263 1264 1265 1266 1267 1268 1269 1270 1271 1272 1273 1274 1275 1276 1277 1278 1279 1280 1281 1282 1283 1284 1285 1286 1287 1288 1289 1290 1291 1292 1293 1294 1295 1296 1297 1298 1299 1300 1301 1302 1303 1304 1305 1306 1307 1308 1309 1310 1311 1312 1313 1314 1315 1316 1317 1318 1319 1320 1321 1322 1323 1324 1325 1326 1327 1328 1329 1330 1331 1332 1333 1334 1335 1336 1337 1338 1339 1340 1341 1342 1343 1344 1345 1346 1347 1348 1349 1350 1351 1352 1353 1354 1355 1356 1357 1358 1359 1360 1361 1362 1363 1364 1365 1366 1367 1368 1369 1370 1371 1372 1373 1374 1375 1376 1377 1378 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