! Freq RIJCOSX PBEh-3c
%output 
xyzfile=True 
end 
%scf 
maxiter 250 
end
%output
Print[P_Hirshfeld] = 1
end
% maxcore
4800
%pal nprocs 8
end
*xyz 0 1
O    0.13769202   0.85442954   3.23513784 
S    0.07770233  -0.35391621   2.39957458 
N   -1.31234384  -0.14900374   1.43094589 
C   -1.69383210   1.12123029   0.99075136 
C   -2.41852709   1.30201492  -0.10832515 
C   -2.86188571   0.18149171  -1.00134529 
C   -2.44757580  -1.14031353  -0.42661130 
C   -1.72261161  -1.25205056   0.68093587 
N    1.37981342  -0.20711383   1.30869398 
C    1.73640038  -1.34870496   0.58984611 
C    2.39698028  -1.29704632  -0.56161653 
C    2.78998976  -0.00871479  -1.22100475 
C    2.40020509   1.15802200  -0.36258577 
C    1.74147630   1.03710144   0.78536763 
H   -1.39978627   1.93814981   1.63392254 
H   -2.71740631   2.31103405  -0.35916302 
H   -2.44793367   0.30814791  -2.00961710 
H   -3.94937012   0.21164741  -1.13733725 
H   -2.76695254  -2.04702065  -0.92237744 
H   -1.44238477  -2.21651475   1.08656750 
H    1.47202131  -2.28972851   1.05635110 
H    2.67838587  -2.22971847  -1.03158419 
H    2.32677924   0.07239910  -2.21229342 
H    3.86953134   0.00526166  -1.41277847 
H    2.68494140   2.15147782  -0.68254246 
H    1.48859111   1.88743867   1.40218778 
*