%mem=12GB
%nprocshared=8
#p opt freq b3lyp/gen pseudo=cards scrf=(smd,solvent=toluene) nosymm cphf=conver=7 empiricaldispersion=gd3 int=(acc2e=11,grid=ultrafine)

Title Card Required

0 1
 C                 -5.52184900    1.14989600    0.03192900
 O                 -5.73720200    1.75063600    1.11876000
 O                 -5.65984500   -0.21979700    0.05029700
 O                 -5.19590400    1.64956700   -1.06594800
 Cs                -5.09506900    4.32861300   -0.03049400
 H                 -5.91124700   -0.43521000    0.96091300

C O H 0
6-31G*
****
Cs 0
SDD
****

Cs 0
SDD