! wb97m-v ma-def2-qzvp SP TIGHTSCF SMD(benzene)

%pal
nprocs 10
end

%maxcore 3500

*xyz 0 1
  C           1.89835739436377      0.84144268280537      0.37501540253483
  C           3.27785850332852      2.57925645307215     -0.05828592540362
  C           2.25424463029657      3.40315458522608     -0.50682460534162
  C           0.97507483484067      2.86422152694170     -0.50393064929395
  C           0.78960995287550      1.56031053616165     -0.05374075087408
  H           1.79747561713361     -0.18015582977136      0.73640451898810
  H           2.46008142284400      4.41249258388101     -0.84344882217595
  H           0.13359981823659      3.45863334674796     -0.84651348216984
  H          -0.19648198405640      1.10806415905370     -0.03414805402345
  O           4.58621273138565      3.09556056826256      0.03350220382184
  S           5.47815196092755      3.27410351762564     -1.34178950369362
  O           4.61146274135746      3.56782705296694     -2.47436045944400
  O           6.61136352670948      4.08942111816513     -0.95141134456259
  C           6.11522506006791      1.49306614879795     -1.57132143118625
  F           7.04666913152507      1.52103596781647     -2.52732131498104
  F           5.11383649813643      0.70097307700859     -1.94860038035140
  F           6.64709923157328      1.04932186349527     -0.43872072028104
  N           3.13976653179634      1.34374444943419      0.37045463815093
*