! wb97m-v ma-def2-qzvp SP TIGHTSCF SMD(benzene)

%pal
nprocs 10
end

%maxcore 3500

*xyz 0 1
  C          -1.84225322459890      0.50904813915598      0.03542709438627
  C          -0.82682954305904      1.25025270313506      0.93547141738263
  C           0.98476022697361     -1.24073175908565      0.25346238213668
  C           0.33158098409120      1.83660300957679      0.17777022379433
  C           1.99597981516828     -0.13519501454552     -0.05903095155190
  C           1.46172251761597      1.25008308821055     -0.20182070891520
  H          -1.88768785003843      1.01748102300736     -0.93688840880033
  H          -0.48892288920510      0.59364806325706      1.74270561260588
  H           1.54882406242160     -2.18043041680251      0.25668935405670
  H           2.49501299390861     -0.37379545415512     -1.00908316450229
  H          -2.84016623631025      0.60311922819147      0.48164388908410
  H          -1.33866559655988      2.08638980488258      1.42364235341642
  H           0.60203348856127     -1.13211139746297      1.27289525668719
  H           2.79134169957029     -0.12816533266228      0.70058912354307
  C          -1.56064303887887     -0.97969153550178     -0.17745037628939
  H          -2.33565484634607     -1.37100994875319     -0.84923623015166
  H          -1.69178636520020     -1.50962174057527      0.77748956978302
  C          -0.18568156952361     -1.34434773579546     -0.75092530342269
  H          -0.24228451858232     -2.37502938151992     -1.11940538304478
  H           0.02147531793177     -0.71987756546552     -1.63093511537732
  H           0.22110308640450      2.87547546222408     -0.12937965092917
  O           2.34361183813015      2.07851271439130     -0.98200421877126
  S           3.50508527548005      2.92469197188117     -0.19009195679265
  C           5.01939044505717      2.10934896362190     -0.99329257242819
  O           3.47262853355114      4.29104182176486     -0.68329723422034
  O           3.52036125453760      2.57963217587677      1.22524067756746
  F           5.05880086504294      0.81021421201741     -0.68130953547647
  F           6.11541215110340      2.70851202375335     -0.52527795004320
  F           4.96535612275310      2.24558887737746     -2.31715019372687
*