<?xml version="1.0" encoding="UTF-8"?>
<module xmlns="http://www.xml-cml.org/schema" xmlns:cc="http://www.xml-cml.org/dictionary/compchem/" xmlns:cml="http://www.xml-cml.org/schema" xmlns:cmlx="http://www.xml-cml.org/schema/cmlx" xmlns:compchem="http://www.xml-cml.org/dictionary/compchem/" xmlns:convention="http://www.xml-cml.org/convention/" xmlns:g="http://www.iochem-bd.org/dictionary/gaussian/" xmlns:nonsi="http://www.xml-cml.org/unit/nonSi/" xmlns:nonsi2="http://www.iochem-bd.org/unit/nonSi2/" xmlns:si="http://www.xml-cml.org/unit/si/" xmlns:xi="http://www.w3.org/2001/XInclude" xmlns:xsd="http://www.w3.org/2001/XMLSchema" convention="convention:compchem" id="gaussian.log">
<module dictRef="cc:jobList" id="jobList1">
<module cmlx:templateRef="job" dictRef="cc:job" id="job">
<module dictRef="cc:environment" id="environment">
<parameterList>
<parameter dictRef="cc:program">
<scalar dataType="xsd:string">Gaussian 16</scalar>
</parameter>
<parameter dictRef="cc:hostname">
<scalar dataType="xsd:string">GINC-EXP-8-13</scalar>
</parameter>
<parameter dictRef="cc:jobname">
<scalar dataType="xsd:string">YUMCAO</scalar>
</parameter>
<parameter dictRef="cc:title">
<scalar dataType="xsd:string">Title Card Required</scalar>
</parameter>
<parameter dictRef="cc:version">
<scalar dataType="xsd:string">ES64L-G16RevC.01</scalar>
</parameter>
<parameter dictRef="cc:run.date">
<scalar dataType="xsd:string">17-Apr-2025</scalar>
</parameter>
<parameter dictRef="cc:program">
<scalar dataType="xsd:string">Gaussian 16</scalar>
</parameter>
<parameter dictRef="cc:program.date">
<scalar dataType="xsd:string">3-Jul-2019</scalar>
</parameter>
<parameter dictRef="cc:version">
<scalar dataType="xsd:string">ES64L-G16RevC.01</scalar>
</parameter>
</parameterList>
</module>
<module dictRef="cc:initialization" id="initialization">
<parameterList>
<parameter dictRef="cc:nactiveatoms">
<scalar dataType="xsd:integer">69</scalar>
</parameter>
<parameter dictRef="cc:natoms">
<scalar dataType="xsd:integer">69</scalar>
</parameter>
<parameter dictRef="cc:betae">
<scalar dataType="xsd:integer">144</scalar>
</parameter>
<parameter dictRef="cc:alphae">
<scalar dataType="xsd:integer">144</scalar>
</parameter>
<parameter dictRef="cc:basiscount">
<scalar dataType="xsd:integer">723</scalar>
</parameter>
<parameter dictRef="cc:diffuse">
<scalar dataType="xsd:string">(5D, 7F)</scalar>
</parameter>
<parameter dictRef="cc:basis">
<scalar dataType="xsd:string">def2SVP</scalar>
</parameter>
<parameter dictRef="cc:method">
<scalar dataType="xsd:string">RB3LYP</scalar>
</parameter>
<parameter dictRef="cc:basis">
<scalar dataType="xsd:string">def2SVP</scalar>
</parameter>
<parameter dictRef="g:operation">
<scalar dataType="xsd:string">FTS</scalar>
</parameter>
<parameter dictRef="g:keyword">
<scalar dataType="xsd:string">#</scalar>
</parameter>
<parameter dictRef="g:keyword">
<scalar dataType="xsd:string">opt=(ts,modredundant,noeigen,gdiis,maxstep=10,recalc=30)</scalar>
</parameter>
<parameter dictRef="g:keyword">
<scalar dataType="xsd:string">freq</scalar>
</parameter>
<parameter dictRef="g:keyword">
<scalar dataType="xsd:string">b3lyp</scalar>
</parameter>
<parameter dictRef="g:keyword">
<scalar dataType="xsd:string">def2svp</scalar>
</parameter>
<parameter dictRef="g:keyword">
<scalar dataType="xsd:string">em=gd3bj</scalar>
</parameter>
</parameterList>
<molecule cmlx:templateRef="mol" formalCharge="0" id="zmat" spinMultiplicity="1">
<atomArray>
<atom elementType="N" id="a1" x3="-0.84559" y3="1.58703" z3="-1.05481"/>
<atom elementType="N" id="a2" x3="1.90791" y3="1.56982" z3="-0.11054"/>
<atom elementType="N" id="a3" x3="2.02526" y3="-1.30841" z3="-0.50745"/>
<atom elementType="N" id="a4" x3="-0.72241" y3="-1.29224" z3="-1.45771"/>
<atom elementType="C" id="a5" x3="-2.10345" y3="1.39252" z3="-1.56298"/>
<atom elementType="C" id="a6" x3="-2.79932" y3="2.66223" z3="-1.60794"/>
<atom elementType="C" id="a7" x3="-1.93719" y3="3.60733" z3="-1.1318"/>
<atom elementType="C" id="a8" x3="-0.70335" y3="2.92583" z3="-0.79506"/>
<atom elementType="C" id="a9" x3="0.4510" y3="3.53798" z3="-0.31317"/>
<atom elementType="C" id="a10" x3="1.65815" y3="2.91396" z3="-0.00989"/>
<atom elementType="C" id="a11" x3="2.85076" y3="3.58634" z3="0.46251"/>
<atom elementType="C" id="a12" x3="3.81159" y3="2.63191" z3="0.62487"/>
<atom elementType="C" id="a13" x3="3.21505" y3="1.36439" z3="0.2543"/>
<atom elementType="C" id="a14" x3="3.87108" y3="0.13634" z3="0.24459"/>
<atom elementType="C" id="a15" x3="3.32795" y3="-1.0946" z3="-0.12166"/>
<atom elementType="C" id="a16" x3="4.03287" y3="-2.35702" z3="-0.11622"/>
<atom elementType="C" id="a17" x3="3.13892" y3="-3.31871" z3="-0.49993"/>
<atom elementType="C" id="a18" x3="1.88151" y3="-2.65264" z3="-0.75583"/>
<atom elementType="C" id="a19" x3="0.71539" y3="-3.27086" z3="-1.20876"/>
<atom elementType="C" id="a20" x3="-0.47918" y3="-2.64056" z3="-1.55101"/>
<atom elementType="C" id="a21" x3="-1.65306" y3="-3.29883" z3="-2.08813"/>
<atom elementType="C" id="a22" x3="-2.58122" y3="-2.32625" z3="-2.32813"/>
<atom elementType="C" id="a23" x3="-1.99058" y3="-1.06622" z3="-1.92927"/>
<atom elementType="C" id="a24" x3="-2.62907" y3="0.17062" z3="-1.97569"/>
<atom elementType="H" id="a25" x3="-3.81911" y3="2.79536" z3="-1.96472"/>
<atom elementType="H" id="a26" x3="-2.10189" y3="4.67764" z3="-1.01981"/>
<atom elementType="H" id="a27" x3="0.40739" y3="4.61801" z3="-0.16379"/>
<atom elementType="H" id="a28" x3="2.92528" y3="4.65747" z3="0.6414"/>
<atom elementType="H" id="a29" x3="4.83904" y3="2.75675" z3="0.96219"/>
<atom elementType="H" id="a30" x3="4.91965" y3="0.13808" z3="0.54778"/>
<atom elementType="H" id="a31" x3="5.08154" y3="-2.47882" z3="0.15004"/>
<atom elementType="H" id="a32" x3="3.30862" y3="-4.38767" z3="-0.61857"/>
<atom elementType="H" id="a33" x3="0.75734" y3="-4.35268" z3="-1.34892"/>
<atom elementType="H" id="a34" x3="-1.73437" y3="-4.36962" z3="-2.26794"/>
<atom elementType="H" id="a35" x3="-3.58385" y3="-2.43592" z3="-2.73784"/>
<atom elementType="H" id="a36" x3="-3.64938" y3="0.18115" z3="-2.36225"/>
<atom elementType="Ir" id="a37" x3="0.58054" y3="0.13092" z3="-0.74643"/>
<atom elementType="C" id="a38" x3="1.2192" y3="0.51207" z3="-2.70362"/>
<atom elementType="H" id="a39" x3="1.41283" y3="1.58746" z3="-2.83595"/>
<atom elementType="H" id="a40" x3="2.14848" y3="-0.04462" z3="-2.9042"/>
<atom elementType="H" id="a41" x3="0.44751" y3="0.19701" z3="-3.42282"/>
<atom elementType="C" id="a42" x3="-0.27769" y3="-0.05835" z3="1.36162"/>
<atom elementType="C" id="a43" x3="-1.74132" y3="-0.15751" z3="1.40392"/>
<atom elementType="C" id="a44" x3="-2.53352" y3="0.97349" z3="1.68321"/>
<atom elementType="C" id="a45" x3="-2.39024" y3="-1.37148" z3="1.11333"/>
<atom elementType="C" id="a46" x3="-3.92261" y3="0.88939" z3="1.63076"/>
<atom elementType="H" id="a47" x3="-2.04611" y3="1.9240" z3="1.90017"/>
<atom elementType="C" id="a48" x3="-3.77856" y3="-1.45092" z3="1.10332"/>
<atom elementType="H" id="a49" x3="-1.79626" y3="-2.25801" z3="0.88387"/>
<atom elementType="C" id="a50" x3="-4.57409" y3="-0.31897" z3="1.3411"/>
<atom elementType="H" id="a51" x3="-4.5159" y3="1.78811" z3="1.82027"/>
<atom elementType="H" id="a52" x3="-4.25557" y3="-2.40828" z3="0.87772"/>
<atom elementType="C" id="a53" x3="0.38588" y3="0.82004" z3="2.35674"/>
<atom elementType="O" id="a54" x3="0.30621" y3="2.0047" z3="2.50261"/>
<atom elementType="O" id="a55" x3="1.18799" y3="0.01422" z3="3.15188"/>
<atom elementType="C" id="a56" x3="0.71713" y3="-1.28164" z3="2.95601"/>
<atom elementType="H" id="a57" x3="0.25288" y3="-1.14997" z3="1.66723"/>
<atom elementType="C" id="a58" x3="-0.4181" y3="-1.68039" z3="3.85649"/>
<atom elementType="H" id="a59" x3="-0.89154" y3="-2.60813" z3="3.50413"/>
<atom elementType="H" id="a60" x3="-0.0143" y3="-1.86048" z3="4.86805"/>
<atom elementType="H" id="a61" x3="-1.18586" y3="-0.89865" z3="3.92267"/>
<atom elementType="C" id="a62" x3="1.81591" y3="-2.28395" z3="2.75768"/>
<atom elementType="H" id="a63" x3="2.27207" y3="-2.49624" z3="3.74139"/>
<atom elementType="H" id="a64" x3="1.42719" y3="-3.22708" z3="2.34901"/>
<atom elementType="H" id="a65" x3="2.5911" y3="-1.89123" z3="2.09234"/>
<atom elementType="C" id="a66" x3="-6.07639" y3="-0.3896" z3="1.25114"/>
<atom elementType="H" id="a67" x3="-6.55736" y3="0.30245" z3="1.95943"/>
<atom elementType="H" id="a68" x3="-6.42428" y3="-0.11203" z3="0.24031"/>
<atom elementType="H" id="a69" x3="-6.44758" y3="-1.4051" z3="1.45598"/>
</atomArray>
<bondArray/>
<formula concise="C33H29IrN4O2"/>
<property dictRef="cml:molmass">
<scalar units="unit:dalton">676.5957000000003</scalar>
</property>
<list cmlx:templateRef="charge">
<list>
<scalar dataType="xsd:integer" dictRef="g:charge">0</scalar>
<scalar dataType="xsd:integer" dictRef="g:mult">1</scalar>
</list>
</list>
<formula convention="iupac:inchi" inline="InChI=1/33C.Ir.4N.2O.29H">
<scalar dataType="xsd:integer" id="auxInfo">AuxInfo=1/0/N:5;6;7;8;9;10;11;12;13;14;15;16;17;18;19;20;21;22;23;24;38;42;43;44;45;46;48;50;53;56;58;62;66;37;1;2;3;4;54;55;25;26;27;28;29;30;31;32;33;34;35;36;39;40;41;47;49;51;52;57;59;60;61;63;64;65;67;68;69/rA:69nN0N0N0N0C0C0C0C0C0C0C0C0C0C0C0C0C0C0C0C0C0C0C0C0H0H0H0H0H0H0H0H0H0H0H0H0IrC0H0H0H0C0C0C0C0C0H0C0H0C0H0H0C0O0O0C0H0C0H0H0H0C0H0H0H0C0H0H0H0/rB:;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/rC:-.8456,1.587,-1.0548;1.9079,1.5698,-.1105;2.0253,-1.3084,-.5074;-.7224,-1.2922,-1.4577;-2.1035,1.3925,-1.563;-2.7993,2.6622,-1.6079;-1.9372,3.6073,-1.1318;-.7034,2.9258,-.7951;.451,3.538,-.3132;1.6582,2.914,-.0099;2.8508,3.5863,.4625;3.8116,2.6319,.6249;3.2151,1.3644,.2543;3.8711,.1363,.2446;3.3279,-1.0946,-.1217;4.0329,-2.357,-.1162;3.1389,-3.3187,-.4999;1.8815,-2.6526,-.7558;.7154,-3.2709,-1.2088;-.4792,-2.6406,-1.551;-1.6531,-3.2988,-2.0881;-2.5812,-2.3262,-2.3281;-1.9906,-1.0662,-1.9293;-2.6291,.1706,-1.9757;-3.8191,2.7954,-1.9647;-2.1019,4.6776,-1.0198;.4074,4.618,-.1638;2.9253,4.6575,.6414;4.839,2.7567,.9622;4.9196,.1381,.5478;5.0815,-2.4788,.15;3.3086,-4.3877,-.6186;.7573,-4.3527,-1.3489;-1.7344,-4.3696,-2.2679;-3.5838,-2.4359,-2.7378;-3.6494,.1812,-2.3622;.5805,.1309,-.7464;1.2192,.5121,-2.7036;1.4128,1.5875,-2.8359;2.1485,-.0446,-2.9042;.4475,.197,-3.4228;-.2777,-.0583,1.3616;-1.7413,-.1575,1.4039;-2.5335,.9735,1.6832;-2.3902,-1.3715,1.1133;-3.9226,.8894,1.6308;-2.0461,1.924,1.9002;-3.7786,-1.4509,1.1033;-1.7963,-2.258,.8839;-4.5741,-.319,1.3411;-4.5159,1.7881,1.8203;-4.2556,-2.4083,.8777;.3859,.82,2.3567;.3062,2.0047,2.5026;1.188,.0142,3.1519;.7171,-1.2816,2.956;.2529,-1.15,1.6672;-.4181,-1.6804,3.8565;-.8915,-2.6081,3.5041;-.0143,-1.8605,4.8681;-1.1859,-.8986,3.9227;1.8159,-2.2839,2.7577;2.2721,-2.4962,3.7414;1.4272,-3.2271,2.349;2.5911,-1.8912,2.0923;-6.0764,-.3896,1.2511;-6.5574,.3024,1.9594;-6.4243,-.112,.2403;-6.4476,-1.4051,1.456;</scalar>
</formula>
</molecule>
<module dictRef="cc:userDefinedModule" id="otherComponents">
<module cmlx:templateRef="entering" dictRef="cc:userDefinedModule">
<scalar dataType="xsd:string" dictRef="g:link0">g16</scalar>
<array dataType="xsd:string" dictRef="g:command" size="1">Output=4_ts_r.log</array>
</module>
<module cmlx:templateRef="l1" dictRef="cc:userDefinedModule">
<module cmlx:templateRef="l1.end">
<array dataType="xsd:string" dictRef="g:kk" size="1">mem=64GB</array>
<array dataType="xsd:string" dictRef="g:kk" size="1">nprocshared=32</array>
<scalar cmlx:templateRef="title" dataType="xsd:string" dictRef="cc:title"># opt=(ts,modredundant,noeigen,gdiis,maxstep=10,recalc=30) freq b3lyp</scalar>
<list cmlx:templateRef="control">
<scalar dataType="xsd:string" dictRef="g:control">1/5=1,8=10,10=4,11=1,18=120,19=11,26=3,38=1,71=30/1,3</scalar>
<scalar dataType="xsd:string" dictRef="g:control">2/9=110,12=2,17=6,18=5,40=1/2</scalar>
<scalar dataType="xsd:string" dictRef="g:control">3/5=43,7=101,11=2,25=1,30=1,71=2,74=-5,124=41,140=1/1,2,3</scalar>
<scalar dataType="xsd:string" dictRef="g:control">4//1</scalar>
<scalar dataType="xsd:string" dictRef="g:control">5/5=2,38=5/2</scalar>
<scalar dataType="xsd:string" dictRef="g:control">8/6=4,10=90,11=11/1</scalar>
<scalar dataType="xsd:string" dictRef="g:control">11/6=1,8=1,9=11,15=111,16=1/1,2,10</scalar>
<scalar dataType="xsd:string" dictRef="g:control">10/6=1,13=1/2</scalar>
<scalar dataType="xsd:string" dictRef="g:control">6/7=2,8=2,9=2,10=2,28=1/1</scalar>
<scalar dataType="xsd:string" dictRef="g:control">7/10=1,25=1/1,2,3,16</scalar>
<scalar dataType="xsd:string" dictRef="g:control">1/5=1,8=10,10=4,11=1,18=20,19=11,26=3,71=30/3(3)</scalar>
<scalar dataType="xsd:string" dictRef="g:control">2/9=110/2</scalar>
<scalar dataType="xsd:string" dictRef="g:control">7/9=1,25=1,44=-1/16</scalar>
<scalar dataType="xsd:string" dictRef="g:control">99//99</scalar>
</list>
<list cmlx:templateRef="control">
<scalar dataType="xsd:string" dictRef="g:control">2/9=110/2</scalar>
<scalar dataType="xsd:string" dictRef="g:control">3/5=43,7=101,11=2,25=1,30=1,71=2,74=-5,124=41,140=1/1,2,3</scalar>
<scalar dataType="xsd:string" dictRef="g:control">4/5=5,16=3,69=1/1</scalar>
<scalar dataType="xsd:string" dictRef="g:control">5/5=2,38=5/2</scalar>
<scalar dataType="xsd:string" dictRef="g:control">8/6=4,10=90,11=11/1</scalar>
<scalar dataType="xsd:string" dictRef="g:control">11/6=1,8=1,9=11,15=111,16=1/1,2,10</scalar>
<scalar dataType="xsd:string" dictRef="g:control">10/6=1,13=1/2</scalar>
<scalar dataType="xsd:string" dictRef="g:control">7/10=1,25=1/1,2,3,16</scalar>
<scalar dataType="xsd:string" dictRef="g:control">1/5=1,8=10,11=1,18=20,19=11,26=3,71=30/3(-8)</scalar>
<scalar dataType="xsd:string" dictRef="g:control">2/9=110/2</scalar>
<scalar dataType="xsd:string" dictRef="g:control">6/7=2,8=2,9=2,10=2,19=2,28=1/1</scalar>
<scalar dataType="xsd:string" dictRef="g:control">7/9=1,25=1,44=-1/16</scalar>
<scalar dataType="xsd:string" dictRef="g:control">99/9=1/99</scalar>
</list>
</module>
</module>
<module cmlx:templateRef="l101" dictRef="cc:userDefinedModule">
<module cmlx:templateRef="l101.title">
<scalar cmlx:templateRef="title" dataType="xsd:string" dictRef="cc:title">Title Card Required</scalar>
</module>
<list cmlx:templateRef="rest">
<scalar dataType="xsd:string" dictRef="x:l101"/>
<scalar dataType="xsd:string" dictRef="x:l101">The following ModRedundant input section has been read:</scalar>
<scalar dataType="xsd:string" dictRef="x:l101">B      42      57 B</scalar>
<scalar dataType="xsd:string" dictRef="x:l101">B      56      57 B</scalar>
<scalar dataType="xsd:string" dictRef="x:l101">B      42      56 B</scalar>
<scalar dataType="xsd:string" dictRef="x:l101"/>
<scalar dataType="xsd:string" dictRef="x:l101"/>
</list>
</module>
<module cmlx:templateRef="l103" dictRef="cc:userDefinedModule">
<list cmlx:templateRef="berny">
<scalar dataType="xsd:string" dictRef="g:optimization">Berny optimization.</scalar>
</list>
<module cmlx:templateRef="l103.init">
<list cmlx:templateRef="length">
<array dataType="xsd:string" dictRef="g:symbol" size="79">R1 R2 R3 R4 R5 R6 R7 R8 R9 R10 R11 R12 R13 R14 R15 R16 R17 R18 R19 R20 R21 R22 R23 R24 R25 R26 R27 R28 R29 R30 R31 R32 R33 R34 R35 R36 R37 R38 R39 R40 R41 R42 R43 R44 R45 R46 R47 R48 R49 R50 R51 R52 R53 R54 R55 R56 R57 R58 R59 R60 R61 R62 R63 R64 R65 R66 R67 R68 R69 R70 R71 R72 R73 R74 R75 R76 R77 R78 R79</array>
<array dataType="xsd:integer" dictRef="g:atom1" size="79">1 1 1 2 2 2 3 3 3 4 4 4 5 5 6 6 7 7 8 9 9 10 11 11 12 12 13 14 14 15 16 16 17 17 18 19 19 20 21 21 22 22 23 24 37 37 38 38 38 42 42 42 42 43 43 44 44 45 45 46 46 48 48 50 53 53 55 56 56 56 58 58 58 62 62 62 66 66 66</array>
<array dataType="xsd:integer" dictRef="g:atom2" size="79">5 8 37 10 13 37 15 18 37 20 23 37 6 24 7 25 8 26 9 10 27 11 12 28 13 29 14 15 30 16 17 31 18 32 19 20 33 21 22 34 23 35 24 36 38 42 39 40 41 43 53 56 57 44 45 46 47 48 49 50 51 50 52 66 54 55 56 57 58 62 59 60 61 63 64 65 67 68 69</array>
<array dataType="xsd:double" dictRef="cc:distance" size="79">1.3705 1.3712 2.0614 1.3709 1.3726 2.0583 1.3753 1.3745 2.0533 1.3732 1.3717 2.0565 1.4486 1.3927 1.365 1.0886 1.4492 1.0887 1.3927 1.3923 1.0912 1.4483 1.364 1.0885 1.4491 1.0886 1.3923 1.3944 1.0915 1.4459 1.3679 1.0888 1.4458 1.0888 1.3954 1.3933 1.0917 1.4491 1.3656 1.0888 1.4476 1.0886 1.3927 1.0911 2.0937 2.2839 1.1007 1.1017 1.1009 1.4676 1.484 2.2424 1.2516 1.4088 1.4069 1.3926 1.09 1.3906 1.0915 1.403 1.0934 1.4038 1.0932 1.5067 1.1963 1.3874 1.3926 1.3762 1.5029 1.5004 1.0995 1.104 1.0977 1.1049 1.0989 1.0945 1.1009 1.1045 1.1004</array>
<array dataType="xsd:string" delimiter="|" dictRef="g:deriv" size="79">calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically</array>
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<array dataType="xsd:string" dictRef="g:symbol" size="148">A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 A11 A12 A13 A14 A15 A16 A17 A18 A19 A20 A21 A22 A23 A24 A25 A26 A27 A28 A29 A30 A31 A32 A33 A34 A35 A36 A37 A38 A39 A40 A41 A42 A43 A44 A45 A46 A47 A48 A49 A50 A51 A52 A53 A54 A55 A56 A57 A58 A59 A60 A61 A62 A63 A64 A65 A66 A67 A68 A69 A70 A71 A72 A73 A74 A75 A76 A77 A78 A79 A80 A81 A82 A83 A84 A85 A86 A87 A88 A89 A90 A91 A92 A93 A94 A95 A96 A97 A98 A99 A100 A101 A102 A103 A104 A105 A106 A107 A108 A109 A110 A111 A112 A113 A114 A115 A116 A117 A118 A119 A120 A121 A122 A123 A124 A125 A126 A127 A128 A129 A130 A131 A132 A133 A134 A135 A136 A137 A138 A139 A140 A141 A142 A143 A144 A145 A146 A147 A148</array>
<array dataType="xsd:integer" dictRef="g:atom1" size="148">5 5 8 10 10 13 15 15 18 20 20 23 1 1 6 5 5 7 6 6 8 1 1 7 8 8 10 2 2 9 10 10 12 11 11 13 2 2 12 13 13 15 3 3 14 15 15 17 16 16 18 3 3 17 18 18 20 4 4 19 20 20 22 21 21 23 4 4 22 5 5 23 1 1 1 1 2 2 2 3 3 3 4 4 37 37 37 39 39 40 37 37 37 37 43 43 43 53 53 42 42 44 43 43 46 43 43 48 44 44 50 45 45 50 46 46 48 42 42 54 53 42 42 42 55 55 55 57 57 58 56 56 56 59 59 60 56 56 56 63 63 64 50 50 50 67 67 68</array>
<array dataType="xsd:integer" dictRef="g:atom2" size="148">1 1 1 2 2 2 3 3 3 4 4 4 5 5 5 6 6 6 7 7 7 8 8 8 9 9 9 10 10 10 11 11 11 12 12 12 13 13 13 14 14 14 15 15 15 16 16 16 17 17 17 18 18 18 19 19 19 20 20 20 21 21 21 22 22 22 23 23 23 24 24 24 37 37 37 37 37 37 37 37 37 37 37 37 38 38 38 38 38 38 42 42 42 42 42 42 42 42 42 43 43 43 44 44 44 45 45 45 46 46 46 48 48 48 50 50 50 53 53 53 55 56 56 56 56 56 56 56 56 56 58 58 58 58 58 58 62 62 62 62 62 62 66 66 66 66 66 66</array>
<array dataType="xsd:integer" dictRef="g:atom3" size="148">8 37 37 13 37 37 18 37 37 23 37 37 6 24 24 7 25 25 8 26 26 7 9 9 10 27 27 9 11 11 12 28 28 13 29 29 12 14 14 15 30 30 14 16 16 17 31 31 18 32 32 17 19 19 20 33 33 19 21 21 22 34 34 23 35 35 22 24 24 23 36 36 2 4 38 42 3 38 42 4 38 42 38 42 39 40 41 40 41 41 43 53 56 57 53 56 57 56 57 44 45 45 46 47 47 48 49 49 50 51 51 50 52 52 48 66 66 54 55 55 56 55 58 62 57 58 62 58 62 62 59 60 61 60 61 61 63 64 65 64 65 65 67 68 69 68 69 69</array>
<array dataType="xsd:double" dictRef="cc:angle" size="148">107.7001 126.1703 126.1288 107.5025 126.2021 126.2727 107.5647 126.1653 126.2225 107.5882 126.2105 126.201 109.1469 125.5061 125.3466 107.0172 124.5683 128.4143 107.0492 128.3917 124.5565 109.0759 125.501 125.4089 126.6566 116.6991 116.6431 125.5504 109.2158 125.2338 107.0999 124.5281 128.3719 106.9555 128.4263 124.618 109.2146 125.3717 125.4027 126.6495 116.6988 116.6501 125.4401 109.0928 125.4409 107.1069 124.6223 128.2708 107.105 128.237 124.6501 109.1241 125.4032 125.461 126.5676 116.6542 116.7242 125.4028 109.1303 125.4554 106.9897 124.6426 128.36 107.1069 128.3414 124.5516 109.1776 125.5652 125.2232 126.6029 116.7069 116.6848 89.9175 89.929 86.709 86.3675 90.0192 87.9839 90.8658 90.0541 91.2483 95.675 89.7665 91.3644 110.1153 109.6029 110.1673 108.8699 108.928 109.1301 114.014 113.6949 122.3288 97.9526 117.815 112.6496 110.9032 69.3736 99.3789 120.8152 120.8209 118.3144 120.3276 119.2145 120.4101 120.7482 119.5551 119.6941 121.5306 119.0162 119.4533 121.2298 119.1535 119.5937 117.7938 121.0442 121.141 129.6553 107.4003 122.9412 105.3292 75.0707 103.6306 126.5366 99.0187 114.7099 113.1162 109.3714 100.7882 117.0728 110.923 108.4222 112.055 108.2697 108.6051 108.4663 108.2405 111.3109 111.0597 108.1941 108.5274 109.4161 111.577 110.9123 111.6214 107.0523 108.239 107.2192</array>
<array dataType="xsd:string" delimiter="|" dictRef="g:deriv" size="148">calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically</array>
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<array dataType="xsd:string" dictRef="g:symbol" size="6">A149 A150 A151 A152 A153 A154</array>
<array dataType="xsd:integer" dictRef="g:atom1" size="6">1 2 38 1 2 38</array>
<array dataType="xsd:integer" dictRef="g:atom2" size="6">37 37 37 37 37 37</array>
<array dataType="xsd:integer" dictRef="g:atom3" size="6">3 4 42 3 4 42</array>
<array dataType="xsd:integer" dictRef="g:atom4" size="6">2 1 1 2 1 1</array>
<array dataType="xsd:integer" dictRef="g:atom5" size="6">-1 -1 -1 -2 -2 -2</array>
<scalar dataType="xsd:double" dictRef="g:lll">179.9368</scalar>
<array dataType="xsd:string" delimiter="|" dictRef="g:deriv" size="6">calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically</array>
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<scalar dataType="xsd:double" dictRef="g:lll">179.8466</scalar>
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<list cmlx:templateRef="lll">
<scalar dataType="xsd:double" dictRef="g:lll">173.0765</scalar>
</list>
<list cmlx:templateRef="lll">
<scalar dataType="xsd:double" dictRef="g:lll">182.0417</scalar>
</list>
<list cmlx:templateRef="lll">
<scalar dataType="xsd:double" dictRef="g:lll">177.7556</scalar>
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<list cmlx:templateRef="lll">
<scalar dataType="xsd:double" dictRef="g:lll">181.1419</scalar>
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<list cmlx:templateRef="dihed">
<array dataType="xsd:string" dictRef="g:symbol" size="257">D1 D2 D3 D4 D5 D6 D7 D8 D9 D10 D11 D12 D13 D14 D15 D16 D17 D18 D19 D20 D21 D22 D23 D24 D25 D26 D27 D28 D29 D30 D31 D32 D33 D34 D35 D36 D37 D38 D39 D40 D41 D42 D43 D44 D45 D46 D47 D48 D49 D50 D51 D52 D53 D54 D55 D56 D57 D58 D59 D60 D61 D62 D63 D64 D65 D66 D67 D68 D69 D70 D71 D72 D73 D74 D75 D76 D77 D78 D79 D80 D81 D82 D83 D84 D85 D86 D87 D88 D89 D90 D91 D92 D93 D94 D95 D96 D97 D98 D99 D100 D101 D102 D103 D104 D105 D106 D107 D108 D109 D110 D111 D112 D113 D114 D115 D116 D117 D118 D119 D120 D121 D122 D123 D124 D125 D126 D127 D128 D129 D130 D131 D132 D133 D134 D135 D136 D137 D138 D139 D140 D141 D142 D143 D144 D145 D146 D147 D148 D149 D150 D151 D152 D153 D154 D155 D156 D157 D158 D159 D160 D161 D162 D163 D164 D165 D166 D167 D168 D169 D170 D171 D172 D173 D174 D175 D176 D177 D178 D179 D180 D181 D182 D183 D184 D185 D186 D187 D188 D189 D190 D191 D192 D193 D194 D195 D196 D197 D198 D199 D200 D201 D202 D203 D204 D205 D206 D207 D208 D209 D210 D211 D212 D213 D214 D215 D216 D217 D218 D219 D220 D221 D222 D223 D224 D225 D226 D227 D228 D229 D230 D231 D232 D233 D234 D235 D236 D237 D238 D239 D240 D241 D242 D243 D244 D245 D246 D247 D248 D249 D250 D251 D252 D253 D254 D255 D256 D257</array>
<array dataType="xsd:integer" dictRef="g:atom1" size="257">8 8 37 37 5 5 37 37 5 5 5 5 8 8 8 8 13 13 37 37 10 10 37 37 10 10 10 10 13 13 13 13 18 18 37 37 15 15 37 37 15 15 15 15 18 18 18 18 23 23 37 37 20 20 37 37 20 20 20 20 23 23 23 23 1 1 24 24 1 1 6 6 5 5 25 25 6 6 26 26 1 1 7 7 8 8 27 27 2 2 9 9 10 10 28 28 11 11 29 29 2 2 12 12 13 13 30 30 3 3 14 14 15 15 31 31 16 16 32 32 3 3 17 17 18 18 33 33 4 4 19 19 20 20 34 34 21 21 35 35 4 4 22 22 1 1 1 2 2 2 3 3 3 4 4 4 1 1 1 1 2 2 2 2 3 3 3 3 4 4 4 4 37 37 53 53 56 56 57 57 37 37 43 43 56 56 57 57 37 37 37 43 43 43 53 53 53 42 42 45 45 42 42 44 44 43 43 47 47 43 43 49 49 44 44 51 51 45 45 52 52 46 46 46 48 48 48 42 54 53 53 53 53 42 42 42 55 55 55 57 57 57 62 62 62 42 42 42 55 55 55 57 57 57 58 58 58</array>
<array dataType="xsd:integer" dictRef="g:atom2" size="257">1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 5 5 5 5 5 5 5 5 6 6 6 6 7 7 7 7 8 8 8 8 9 9 9 9 10 10 10 10 11 11 11 11 12 12 12 12 13 13 13 13 14 14 14 14 15 15 15 15 16 16 16 16 17 17 17 17 18 18 18 18 19 19 19 19 20 20 20 20 21 21 21 21 22 22 22 22 23 23 23 23 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 43 43 43 43 43 43 43 43 44 44 44 44 45 45 45 45 46 46 46 46 48 48 48 48 50 50 50 50 50 50 53 53 55 55 55 55 56 56 56 56 56 56 56 56 56 56 56 56 56 56 56 56 56 56 56 56 56 56 56 56</array>
<array dataType="xsd:integer" dictRef="g:atom3" size="257">5 5 5 5 8 8 8 8 37 37 37 37 37 37 37 37 10 10 10 10 13 13 13 13 37 37 37 37 37 37 37 37 15 15 15 15 18 18 18 18 37 37 37 37 37 37 37 37 20 20 20 20 23 23 23 23 37 37 37 37 37 37 37 37 6 6 6 6 24 24 24 24 7 7 7 7 8 8 8 8 9 9 9 9 10 10 10 10 11 11 11 11 12 12 12 12 13 13 13 13 14 14 14 14 15 15 15 15 16 16 16 16 17 17 17 17 18 18 18 18 19 19 19 19 20 20 20 20 21 21 21 21 22 22 22 22 23 23 23 23 24 24 24 24 38 38 38 38 38 38 38 38 38 38 38 38 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 43 43 43 43 43 43 43 43 53 53 53 53 53 53 53 53 56 56 56 56 56 56 56 56 56 44 44 44 44 45 45 45 45 46 46 46 46 48 48 48 48 50 50 50 50 50 50 50 50 66 66 66 66 66 66 55 55 56 56 56 56 58 58 58 58 58 58 58 58 58 58 58 58 62 62 62 62 62 62 62 62 62 62 62 62</array>
<array dataType="xsd:integer" dictRef="g:atom4" size="257">6 24 6 24 7 9 7 9 2 4 38 42 2 4 38 42 9 11 9 11 12 14 12 14 1 3 38 42 1 3 38 42 14 16 14 16 17 19 17 19 2 4 38 42 2 4 38 42 19 21 19 21 22 24 22 24 1 3 38 42 1 3 38 42 7 25 7 25 23 36 23 36 8 26 8 26 1 9 1 9 10 27 10 27 2 11 2 11 12 28 12 28 13 29 13 29 2 14 2 14 15 30 15 30 3 16 3 16 17 31 17 31 18 32 18 32 3 19 3 19 20 33 20 33 4 21 4 21 22 34 22 34 23 35 23 35 4 24 4 24 5 36 5 36 39 40 41 39 40 41 39 40 41 39 40 41 43 53 56 57 43 53 56 57 43 53 56 57 43 53 56 57 44 45 44 45 44 45 44 45 54 55 54 55 54 55 54 55 55 58 62 55 58 62 55 58 62 46 47 46 47 48 49 48 49 50 51 50 51 50 52 50 52 48 66 48 66 46 66 46 66 67 68 69 67 68 69 56 56 42 57 58 62 59 60 61 59 60 61 59 60 61 59 60 61 63 64 65 63 64 65 63 64 65 63 64 65</array>
<array dataType="xsd:double" dictRef="cc:dihed" size="257">-0.9527 178.8242 179.3726 -0.8505 1.0734 -177.6113 -179.2518 2.0635 177.4925 -0.2631 89.5071 -91.6348 -2.1238 -179.8794 -90.1092 88.7489 178.8919 -1.0865 0.5423 -179.4361 1.0491 -177.7954 179.3973 0.5527 0.9082 178.8664 87.618 -85.4576 -177.1394 0.8189 -90.4295 96.4948 -178.6773 -0.4586 3.7117 -178.0696 0.7803 -178.0249 178.3896 -0.4156 -2.807 174.9445 85.1768 -93.679 -179.9835 -2.232 -91.9997 89.1445 177.9926 -0.8299 -1.8074 179.3701 0.502 178.4678 -179.698 -1.7322 -178.7688 3.2738 94.5219 -92.4041 1.4674 -176.4899 -85.2418 87.8322 0.4605 -179.6844 -179.3168 0.5383 1.0923 -179.7869 -179.1661 -0.0454 0.1946 179.6331 -179.6531 -0.2146 -0.7895 177.8967 179.7448 -1.5689 0.0082 179.5934 -178.4666 1.1186 -1.4204 178.5545 178.9941 -1.0309 0.7118 -179.3324 -179.2666 0.6892 -0.0602 179.7855 179.9862 -0.168 -0.6089 178.2353 179.538 -1.6179 -0.5288 179.0005 -179.1902 0.3391 -1.7734 -179.7071 178.6972 0.7634 -0.0526 179.9425 178.166 -1.8388 0.5156 179.5224 -179.4793 -0.4726 -0.8186 177.9858 -179.8702 -1.0658 3.3992 -179.3783 -175.2148 2.0077 -2.1965 176.4377 -179.4173 -0.7831 0.856 179.9209 -177.9657 1.0992 -0.5258 179.5697 -179.5447 0.5507 0.0338 -177.9407 179.9429 1.9685 0.3041 -178.8168 177.9521 -1.1688 52.807 172.5465 -67.3607 -37.2264 82.5132 -157.394 -127.2016 -7.4621 112.6307 142.7493 -97.5111 22.5817 47.8171 -91.0674 -170.8416 164.9869 137.6795 -1.205 -80.9792 -105.1507 -132.2152 88.9004 9.1262 -15.0453 -42.0252 179.0904 99.3162 75.1447 -98.7461 78.6543 38.3473 -144.2523 116.141 -66.4586 151.8459 -30.7537 73.4394 -105.9205 -63.7848 116.8553 -169.2494 11.3907 176.4791 -2.8808 94.4558 -153.1789 -13.4911 -123.7359 -11.3706 128.3172 -11.2051 101.1603 -119.1519 175.5851 -1.9102 -1.8791 -179.3744 -177.4989 1.9081 -0.0348 179.3721 1.9234 -178.075 179.3885 -0.6099 1.9734 -179.7785 -177.4327 0.8154 -0.0097 -178.362 179.9887 1.6364 -1.9336 176.417 179.8259 -1.8236 -33.9348 85.3197 -155.1857 147.7683 -92.9772 26.5174 -17.9752 162.6121 11.636 29.5312 -86.7469 135.4229 87.3011 -153.9419 -34.2615 166.9181 -74.3249 45.3555 56.7545 175.5116 -64.808 -56.9823 61.7747 -178.5449 164.309 -76.9108 45.269 76.1623 -165.0574 -42.8777 -179.0731 -60.2929 61.8869 -60.6094 58.1708 -179.6494</array>
<array dataType="xsd:string" delimiter="|" dictRef="g:deriv" size="257">calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 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analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically</array>
</list>
</module>
</module>
<module cmlx:templateRef="l301.basis" dictRef="g:primbasis">
<list cmlx:templateRef="symmadaptcart">
<array dataType="xsd:integer" dictRef="cc:adapted" size="1">767</array>
<array dataType="xsd:string" dictRef="cc:symm" size="1">A</array>
</list>
<list cmlx:templateRef="symmadapt">
<array dataType="xsd:integer" dictRef="cc:adapted" size="1">723</array>
<array dataType="xsd:string" dictRef="cc:symm" size="1">A</array>
</list>
<scalar dataType="xsd:integer" dictRef="g:primbasis">1243</scalar>
<scalar dataType="xsd:integer" dictRef="cc:cartesianbasis">767</scalar>
<scalar dataType="xsd:double" dictRef="cc:nucrepener">5307.4113018481</scalar>
<scalar dataType="xsd:integer" dictRef="cc:uniqatoms">69</scalar>
<scalar dataType="xsd:double" dictRef="g:sfac">1.00e+00</scalar>
<scalar dataType="xsd:integer" dictRef="g:natfmm">60</scalar>
<scalar dataType="xsd:string" dictRef="g:big">T</scalar>
</module>
<module cmlx:templateRef="l103" dictRef="cc:userDefinedModule">
<list cmlx:templateRef="berny">
<scalar dataType="xsd:string" dictRef="g:optimization">Berny optimization.</scalar>
</list>
<module cmlx:templateRef="l103.localminsaddle">
<scalar cmlx:templateRef="r" dataType="xsd:string" dictRef="cc:minmaxts">saddle point</scalar>
<array cmlx:templateRef="junk" dataType="xsd:string" dictRef="x:junk1" size="9">Step number 4 out of a maximum of 414</array>
<array cmlx:templateRef="junk" dataType="xsd:string" dictRef="x:junk1" size="7">All quantities printed in internal units (Hartrees-Bohrs-Radians)</array>
<array cmlx:templateRef="eigenvaluelist" dataType="xsd:double" dictRef="" size="201">-0.01230 0.00003 0.00010 0.00089 0.00110 0.00159 0.00560 0.00641 0.00747 0.00869 0.00912 0.00957 0.01026 0.01084 0.01125 0.01181 0.01411 0.01423 0.01425 0.01433 0.01516 0.01554 0.01571 0.01586 0.01602 0.01680 0.01707 0.01805 0.01817 0.01892 0.01970 0.01981 0.01999 0.02007 0.02018 0.02109 0.02124 0.02137 0.02211 0.02305 0.02370 0.02408 0.02523 0.02630 0.02635 0.02825 0.02862 0.02879 0.02995 0.03044 0.03317 0.03387 0.03442 0.03481 0.03511 0.03550 0.03669 0.03724 0.03966 0.04226 0.04317 0.04344 0.04408 0.04665 0.04998 0.05509 0.05515 0.05680 0.05706 0.05771 0.06453 0.06956 0.08944 0.09013 0.09257 0.09292 0.09346 0.09392 0.09421 0.09458 0.10208 0.10227 0.10239 0.10246 0.10454 0.11283 0.11359 0.11440 0.11509 0.11551 0.11679 0.11695 0.11903 0.11977 0.12085 0.12126 0.12407 0.12675 0.13188 0.13607 0.13900 0.14055 0.14063 0.14131 0.14180 0.14199 0.14336 0.14977 0.16016 0.16542 0.16569 0.16619 0.16670 0.17218 0.18127 0.18178 0.18630 0.19115 0.19358 0.19534 0.19851 0.19918 0.20962 0.21192 0.21285 0.21325 0.21355 0.21476 0.21910 0.22116 0.24583 0.26400 0.27065 0.27179 0.27462 0.28972 0.29037 0.30263 0.30458 0.30543 0.31688 0.32155 0.32265 0.32741 0.33009 0.33055 0.33279 0.33480 0.33618 0.33893 0.33953 0.34008 0.34097 0.34299 0.34385 0.34506 0.34604 0.34703 0.34776 0.34906 0.35375 0.35502 0.35739 0.35865 0.36034 0.36074 0.36147 0.36180 0.36356 0.36370 0.36718 0.36829 0.36853 0.36874 0.36940 0.36960 0.37054 0.37079 0.37277 0.37915 0.40216 0.40309 0.41038 0.42230 0.43088 0.43183 0.43363 0.44402 0.44498 0.46232 0.46473 0.46577 0.46627 0.46650 0.47303 0.51987 0.53707 0.54315 0.54579 0.54625 0.92356</array>
<module cmlx:templateRef="negativeeigenvaluelist">
<scalar cmlx:templateRef="grot" dataType="xsd:string" dictRef="x:stuffff">R68       R53       R46      D180      D179</scalar>
<scalar cmlx:templateRef="grot" dataType="xsd:string" dictRef="x:stuffff">1                   -0.52554   0.38289  -0.24946  -0.22939  -0.21384</scalar>
<scalar cmlx:templateRef="grot" dataType="xsd:string" dictRef="x:stuffff">A94       A99      D188      D183      D187</scalar>
</module>
<list cmlx:templateRef="iterationList">
<array dataType="xsd:integer" dictRef="cc:serial" size="2">1 2</array>
<array dataType="xsd:double" dictRef="g:rmscart" size="2">0.00048287 0.00000072</array>
<array dataType="xsd:double" dictRef="g:rmsint" size="2">0.00000070 0.00000001</array>
</list>
</module>
<module cmlx:templateRef="l103.deltas">
<list cmlx:templateRef="delta">
<array dataType="xsd:string" dictRef="cc:variable" size="490">R1 R2 R3 R4 R5 R6 R7 R8 R9 R10 R11 R12 R13 R14 R15 R16 R17 R18 R19 R20 R21 R22 R23 R24 R25 R26 R27 R28 R29 R30 R31 R32 R33 R34 R35 R36 R37 R38 R39 R40 R41 R42 R43 R44 R45 R46 R47 R48 R49 R50 R51 R52 R53 R54 R55 R56 R57 R58 R59 R60 R61 R62 R63 R64 R65 R66 R67 R68 R69 R70 R71 R72 R73 R74 R75 R76 R77 R78 R79 A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 A11 A12 A13 A14 A15 A16 A17 A18 A19 A20 A21 A22 A23 A24 A25 A26 A27 A28 A29 A30 A31 A32 A33 A34 A35 A36 A37 A38 A39 A40 A41 A42 A43 A44 A45 A46 A47 A48 A49 A50 A51 A52 A53 A54 A55 A56 A57 A58 A59 A60 A61 A62 A63 A64 A65 A66 A67 A68 A69 A70 A71 A72 A73 A74 A75 A76 A77 A78 A79 A80 A81 A82 A83 A84 A85 A86 A87 A88 A89 A90 A91 A92 A93 A94 A95 A96 A97 A98 A99 A100 A101 A102 A103 A104 A105 A106 A107 A108 A109 A110 A111 A112 A113 A114 A115 A116 A117 A118 A119 A120 A121 A122 A123 A124 A125 A126 A127 A128 A129 A130 A131 A132 A133 A134 A135 A136 A137 A138 A139 A140 A141 A142 A143 A144 A145 A146 A147 A148 A149 A150 A151 A152 A153 A154 D1 D2 D3 D4 D5 D6 D7 D8 D9 D10 D11 D12 D13 D14 D15 D16 D17 D18 D19 D20 D21 D22 D23 D24 D25 D26 D27 D28 D29 D30 D31 D32 D33 D34 D35 D36 D37 D38 D39 D40 D41 D42 D43 D44 D45 D46 D47 D48 D49 D50 D51 D52 D53 D54 D55 D56 D57 D58 D59 D60 D61 D62 D63 D64 D65 D66 D67 D68 D69 D70 D71 D72 D73 D74 D75 D76 D77 D78 D79 D80 D81 D82 D83 D84 D85 D86 D87 D88 D89 D90 D91 D92 D93 D94 D95 D96 D97 D98 D99 D100 D101 D102 D103 D104 D105 D106 D107 D108 D109 D110 D111 D112 D113 D114 D115 D116 D117 D118 D119 D120 D121 D122 D123 D124 D125 D126 D127 D128 D129 D130 D131 D132 D133 D134 D135 D136 D137 D138 D139 D140 D141 D142 D143 D144 D145 D146 D147 D148 D149 D150 D151 D152 D153 D154 D155 D156 D157 D158 D159 D160 D161 D162 D163 D164 D165 D166 D167 D168 D169 D170 D171 D172 D173 D174 D175 D176 D177 D178 D179 D180 D181 D182 D183 D184 D185 D186 D187 D188 D189 D190 D191 D192 D193 D194 D195 D196 D197 D198 D199 D200 D201 D202 D203 D204 D205 D206 D207 D208 D209 D210 D211 D212 D213 D214 D215 D216 D217 D218 D219 D220 D221 D222 D223 D224 D225 D226 D227 D228 D229 D230 D231 D232 D233 D234 D235 D236 D237 D238 D239 D240 D241 D242 D243 D244 D245 D246 D247 D248 D249 D250 D251 D252 D253 D254 D255 D256 D257</array>
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</atomArray>
<bondArray/>
<formula concise="C33H29IrN4O2"/>
<property dictRef="cml:molmass">
<scalar units="unit:dalton">676.5957000000003</scalar>
</property>
<formula convention="iupac:inchi" inline="InChI=1/33C.Ir.4N.2O.29H">
<scalar dataType="xsd:integer" id="auxInfo">AuxInfo=1/0/N:5;6;7;8;9;10;11;12;13;14;15;16;17;18;19;20;21;22;23;24;38;42;43;44;45;46;48;50;53;56;58;62;66;37;1;2;3;4;54;55;25;26;27;28;29;30;31;32;33;34;35;36;39;40;41;47;49;51;52;57;59;60;61;63;64;65;67;68;69/rA:69nN0N0N0N0C0C0C0C0C0C0C0C0C0C0C0C0C0C0C0C0C0C0C0C0H0H0H0H0H0H0H0H0H0H0H0H0IrC0H0H0H0C0C0C0C0C0H0C0H0C0H0H0C0O0O0C0H0C0H0H0H0C0H0H0H0C0H0H0H0/rB:;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/rC:-.8456,1.587,-1.0548;1.9079,1.5698,-.1105;2.0253,-1.3084,-.5074;-.7224,-1.2922,-1.4577;-2.1035,1.3925,-1.563;-2.7993,2.6622,-1.6079;-1.9372,3.6073,-1.1318;-.7034,2.9258,-.7951;.451,3.538,-.3132;1.6582,2.914,-.0099;2.8508,3.5863,.4625;3.8116,2.6319,.6249;3.215,1.3644,.2543;3.8711,.1363,.2446;3.3279,-1.0946,-.1217;4.0329,-2.357,-.1162;3.1389,-3.3187,-.4999;1.8815,-2.6526,-.7558;.7154,-3.2709,-1.2088;-.4792,-2.6406,-1.551;-1.6531,-3.2988,-2.0881;-2.5812,-2.3263,-2.3281;-1.9906,-1.0662,-1.9293;-2.6291,.1706,-1.9757;-3.8191,2.7954,-1.9647;-2.1019,4.6776,-1.0198;.4074,4.618,-.1638;2.9253,4.6575,.6414;4.839,2.7567,.9622;4.9197,.1381,.5478;5.0815,-2.4788,.15;3.3086,-4.3877,-.6186;.7573,-4.3527,-1.3489;-1.7344,-4.3696,-2.2679;-3.5838,-2.4359,-2.7378;-3.6494,.1811,-2.3622;.5805,.1309,-.7464;1.2192,.5121,-2.7036;1.4128,1.5875,-2.8359;2.1485,-.0446,-2.9042;.4475,.197,-3.4228;-.2777,-.0583,1.3616;-1.7413,-.1575,1.4039;-2.5335,.9735,1.6832;-2.3902,-1.3715,1.1133;-3.9226,.8894,1.6308;-2.0461,1.924,1.9002;-3.7786,-1.4509,1.1033;-1.7963,-2.258,.8839;-4.5741,-.319,1.3411;-4.5159,1.7881,1.8203;-4.2556,-2.4083,.8777;.3859,.82,2.3567;.3062,2.0047,2.5026;1.188,.0142,3.1519;.7171,-1.2816,2.956;.2529,-1.15,1.6672;-.4181,-1.6804,3.8565;-.8915,-2.6081,3.5041;-.0143,-1.8605,4.868;-1.1859,-.8986,3.9227;1.8159,-2.284,2.7577;2.2721,-2.4962,3.7414;1.4272,-3.2271,2.349;2.5911,-1.8912,2.0923;-6.0764,-.3896,1.2511;-6.5574,.3024,1.9594;-6.4243,-.112,.2403;-6.4476,-1.4051,1.456;</scalar>
</formula>
</molecule>
</module>
<module cmlx:templateRef="l202.rotconst">
<array cmlx:templateRef="rotconst" dataType="xsd:double" dictRef="cc:rotconst" size="3">0.1322948 0.1004148 0.0903659</array>
</module>
</module>
<module cmlx:templateRef="l601.popanal" dictRef="cc:userDefinedModule">
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<module cmlx:templateRef="l601.state">
<scalar dataType="xsd:string" dictRef="g:l601.state">1-A.</scalar>
</module>
<module cmlx:templateRef="mulliken">
<module cmlx:templateRef="l601.mullik">
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<list cmlx:templateRef="row">
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<array dataType="xsd:string" dictRef="cc:elementType" size="69">N N N N C C C C C C C C C C C C C C C C C C C C H H H H H H H H H H H H Ir C H H H C C C C C H C H C H H C O O C H C H H H C H H H C H H H</array>
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</list>
<scalar dataType="xsd:double" dictRef="x:chargesum">-0.00000</scalar>
</module>
</module>
<list cmlx:templateRef="multipole" dictRef="cc:multipole">
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<scalar dataType="xsd:double" dictRef="x:dipole">4.8847</scalar>
<array dataType="xsd:double" dictRef="cc:quadrupole" size="3">-225.8652 -229.0797 -254.9465</array>
<array dataType="xsd:double" dictRef="cc:quadrupole" size="3">-3.7389 7.4195 -9.0419</array>
<array dataType="xsd:double" dictRef="cc:quadrupole" size="6">10.7652 7.5508 -18.3160 -3.7389 7.4195 -9.0419</array>
<array dataType="xsd:double" dictRef="cc:octapole" size="10">55.8339 19.6698 -28.8996 30.2401 8.9286 -16.8310 5.7663 -40.7578 -25.6849 -8.0716</array>
<array dataType="xsd:double" dictRef="cc:hexadecapole" size="15">-8728.5959 -5651.8721 -4431.2078 -11.3080 113.6212 -10.7496 38.9075 2.2478 -141.8329 -2475.6900 -2328.7590 -1792.1126 27.1124 32.7536 -30.5428</array>
</list>
</module>
<module cmlx:templateRef="l202" dictRef="cc:userDefinedModule">
<module cmlx:templateRef="l202.orient">
<molecule cmlx:templateRef="atom" formalCharge="0" id="mol.l202.orient" spinMultiplicity="1">
<atomArray>
<atom elementType="N" id="a1" x3="-0.836889" y3="1.594893" z3="-1.051771">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="N" id="a2" x3="1.916666" y3="1.561125" z3="-0.108871">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="N" id="a3" x3="2.018018" y3="-1.31712" z3="-0.509921">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="N" id="a4" x3="-0.729741" y3="-1.28435" z3="-1.459412">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
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<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
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<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
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</property>
</atom>
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<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
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</property>
</atom>
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</property>
</atom>
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<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
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</property>
</atom>
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</property>
</atom>
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</property>
</atom>
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</property>
</atom>
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</property>
</atom>
<atom elementType="C" id="a17" x3="3.120105" y3="-3.333814" z3="-0.504061">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="C" id="a18" x3="1.866685" y3="-2.660234" z3="-0.759864">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="C" id="a19" x3="0.6972" y3="-3.271248" z3="-1.213979">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="C" id="a20" x3="-0.493844" y3="-2.633819" z3="-1.55524">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="C" id="a21" x3="-1.671466" y3="-3.284749" z3="-2.093122">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="C" id="a22" x3="-2.594497" y3="-2.306752" z3="-2.330849">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="C" id="a23" x3="-1.99695" y3="-1.050668" z3="-1.929785">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="C" id="a24" x3="-2.628881" y3="0.189641" z3="-1.973327">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a25" x3="-3.805101" y3="2.820467" z3="-1.956085">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a26" x3="-2.076646" y3="4.692153" z3="-1.010528">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a27" x3="0.433355" y3="4.617832" z3="-0.157901">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a28" x3="2.951775" y3="4.642165" z3="0.646159">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a29" x3="4.854751" y3="2.730212" z3="0.964596">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a30" x3="4.920352" y3="0.111633" z3="0.547693">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a31" x3="5.067307" y3="-2.505778" z3="0.147441">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a32" x3="3.283694" y3="-4.403607" z3="-0.623753">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a33" x3="0.733131" y3="-4.353079" z3="-1.355712">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a34" x3="-1.758622" y3="-4.354748" z3="-2.274893">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a35" x3="-3.597865" y3="-2.410289" z3="-2.740346">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a36" x3="-3.649428" y3="0.206404" z3="-2.359041">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="Ir" id="a37" x3="0.581407" y3="0.130635" z3="-0.746885">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="C" id="a38" x3="1.221147" y3="0.510335" z3="-2.703449">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a39" x3="1.425337" y3="1.584065" z3="-2.833344">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a40" x3="2.144438" y3="-0.055268" z3="-2.906685">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a41" x3="0.445259" y3="0.204771" z3="-3.422219">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="C" id="a42" x3="-0.279888" y3="-0.059039" z3="1.363923">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="C" id="a43" x3="-1.743399" y3="-0.155503" z3="1.404965">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="C" id="a44" x3="-2.534172" y3="0.975645" z3="1.683338">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="C" id="a45" x3="-2.393703" y3="-1.369441" z3="1.11307">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="C" id="a46" x3="-3.924239" y3="0.892843" z3="1.629714">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a47" x3="-2.046307" y3="1.92592" z3="1.900306">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="C" id="a48" x3="-3.781162" y3="-1.447437" z3="1.10171">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a49" x3="-1.800017" y3="-2.256129" z3="0.883349">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="C" id="a50" x3="-4.576254" y3="-0.314052" z3="1.339759">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a51" x3="-4.516812" y3="1.792059" z3="1.8184">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a52" x3="-4.258967" y3="-2.404186" z3="0.874593">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="C" id="a53" x3="0.38647" y3="0.820128" z3="2.355706">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="O" id="a54" x3="0.307718" y3="2.004726" z3="2.502171">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="O" id="a55" x3="1.191092" y3="0.013477" z3="3.148721">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="C" id="a56" x3="0.714937" y3="-1.280458" z3="2.957005">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a57" x3="0.249877" y3="-1.149196" z3="1.664655">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="C" id="a58" x3="-0.420977" y3="-1.673518" z3="3.858944">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a59" x3="-0.901702" y3="-2.597032" z3="3.505347">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a60" x3="-0.016303" y3="-1.859099" z3="4.86919">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a61" x3="-1.183109" y3="-0.886605" z3="3.928695">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="C" id="a62" x3="1.80837" y3="-2.287969" z3="2.75662">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a63" x3="2.267773" y3="-2.499124" z3="3.739105">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a64" x3="1.413826" y3="-3.23072" z3="2.352678">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a65" x3="2.58254" y3="-1.900632" z3="2.086989">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="C" id="a66" x3="-6.078267" y3="-0.391063" z3="1.250035">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a67" x3="-6.559217" y3="0.436245" z3="1.792894">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a68" x3="-6.414533" y3="-0.334203" z3="0.199643">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
<atom elementType="H" id="a69" x3="-6.460166" y3="-1.339306" z3="1.659431">
<property dictRef="g:atomicType">
<scalar dataType="xsd:integer">0</scalar>
</property>
</atom>
</atomArray>
<bondArray/>
<formula concise="C33H29IrN4O2"/>
<property dictRef="cml:molmass">
<scalar units="unit:dalton">676.5957000000003</scalar>
</property>
<formula convention="iupac:inchi" inline="InChI=1/33C.Ir.4N.2O.29H">
<scalar dataType="xsd:integer" id="auxInfo">AuxInfo=1/0/N:5;6;7;8;9;10;11;12;13;14;15;16;17;18;19;20;21;22;23;24;38;42;43;44;45;46;48;50;53;56;58;62;66;37;1;2;3;4;54;55;25;26;27;28;29;30;31;32;33;34;35;36;39;40;41;47;49;51;52;57;59;60;61;63;64;65;67;68;69/rA:69nN0N0N0N0C0C0C0C0C0C0C0C0C0C0C0C0C0C0C0C0C0C0C0C0H0H0H0H0H0H0H0H0H0H0H0H0IrC0H0H0H0C0C0C0C0C0H0C0H0C0H0H0C0O0O0C0H0C0H0H0H0C0H0H0H0C0H0H0H0/rB:;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/rC:-.8369,1.5949,-1.0518;1.9167,1.5611,-.1089;2.018,-1.3171,-.5099;-.7297,-1.2844,-1.4594;-2.0964,1.4079,-1.5589;-2.7855,2.6814,-1.601;-1.9178,3.6212,-1.1244;-.6872,2.9326,-.7902;.4709,3.5378,-.3087;1.6746,2.9066,-.0067;2.8711,3.5717,.4661;3.8266,2.6116,.6273;3.2228,1.3479,.2555;3.8718,.1162,.2444;3.3218,-1.1112,-.1234;4.0194,-2.3777,-.1191;3.1201,-3.3338,-.5041;1.8667,-2.6602,-.7599;.6972,-3.2712,-1.214;-.4938,-2.6338,-1.5552;-1.6715,-3.2847,-2.0931;-2.5945,-2.3068,-2.3308;-1.997,-1.0507,-1.9298;-2.6289,.1896,-1.9733;-3.8051,2.8205,-1.9561;-2.0766,4.6922,-1.0105;.4334,4.6178,-.1579;2.9518,4.6422,.6462;4.8548,2.7302,.9646;4.9204,.1116,.5477;5.0673,-2.5058,.1474;3.2837,-4.4036,-.6238;.7331,-4.3531,-1.3557;-1.7586,-4.3547,-2.2749;-3.5979,-2.4103,-2.7403;-3.6494,.2064,-2.359;.5814,.1306,-.7469;1.2211,.5103,-2.7034;1.4253,1.5841,-2.8333;2.1444,-.0553,-2.9067;.4453,.2048,-3.4222;-.2799,-.059,1.3639;-1.7434,-.1555,1.405;-2.5342,.9756,1.6833;-2.3937,-1.3694,1.1131;-3.9242,.8928,1.6297;-2.0463,1.9259,1.9003;-3.7812,-1.4474,1.1017;-1.8,-2.2561,.8833;-4.5763,-.3141,1.3398;-4.5168,1.7921,1.8184;-4.259,-2.4042,.8746;.3865,.8201,2.3557;.3077,2.0047,2.5022;1.1911,.0135,3.1487;.7149,-1.2805,2.957;.2499,-1.1492,1.6647;-.421,-1.6735,3.8589;-.9017,-2.597,3.5053;-.0163,-1.8591,4.8692;-1.1831,-.8866,3.9287;1.8084,-2.288,2.7566;2.2678,-2.4991,3.7391;1.4138,-3.2307,2.3527;2.5825,-1.9006,2.087;-6.0783,-.3911,1.25;-6.5592,.4362,1.7929;-6.4145,-.3342,.1996;-6.4602,-1.3393,1.6594;</scalar>
</formula>
</molecule>
</module>
<module cmlx:templateRef="l202.rotconst">
<array cmlx:templateRef="rotconst" dataType="xsd:double" dictRef="cc:rotconst" size="3">0.1322963 0.1003945 0.0903506</array>
</module>
</module>
<module cmlx:templateRef="l401"/>
<module cmlx:templateRef="l1102">
<list cmlx:templateRef="l1102">
<scalar dataType="xsd:string" dictRef="g:l1102">Symmetrizing basis deriv contribution to polar:</scalar>
<scalar dataType="xsd:string" dictRef="g:l1102">IMax=3 JMax=2 DiffMx= 0.00D+00</scalar>
</list>
</module>
<module cmlx:templateRef="l1002.minotr">
<list cmlx:templateRef="l1002">
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">IDoAtm=11111111111111111111111111111111111111111111111111</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">IDoAtm=1111111111111111111</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Differentiating once with respect to nuclear coordinates.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">CalDSu exits because no D1Ps are significant.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">There are   210 degrees of freedom in the 1st order CPHF.  IDoFFX=6 NUNeed=     0.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">204 vectors produced by pass  0 Test12= 8.34D-14 1.00D-09 XBig12= 2.01D-01 1.39D-01.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">AX will form    96 AO Fock derivatives at one time.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">204 vectors produced by pass  1 Test12= 8.34D-14 1.00D-09 XBig12= 5.95D-02 4.00D-02.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">204 vectors produced by pass  2 Test12= 8.34D-14 1.00D-09 XBig12= 7.62D-04 3.40D-03.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">204 vectors produced by pass  3 Test12= 8.34D-14 1.00D-09 XBig12= 4.07D-06 3.30D-04.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">204 vectors produced by pass  4 Test12= 8.34D-14 1.00D-09 XBig12= 1.00D-08 1.33D-05.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">186 vectors produced by pass  5 Test12= 8.34D-14 1.00D-09 XBig12= 1.37D-11 3.89D-07.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">63 vectors produced by pass  6 Test12= 8.34D-14 1.00D-09 XBig12= 1.52D-14 1.02D-08.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">InvSVY:  IOpt=1 It=  1 EMax= 5.00D-16</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Solved reduced A of dimension  1269 with   210 vectors.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">End of Minotr F.D. properties file   721 does not exist.</scalar>
</list>
</module>
<module cmlx:templateRef="l601.polariz">
<array dataType="xsd:double" dictRef="g:l601.pol.exact" size="6">0.000 0.000 0.000 0.000 0.000 0.000</array>
<array dataType="xsd:double" dictRef="g:l601.pol.approx" size="6">1242.912 -56.656 1265.960 241.121 65.235 638.874</array>
</module>
<module cmlx:templateRef="l716.forces">
<list cmlx:templateRef="force">
<array dataType="xsd:integer" dictRef="x:serial" size="69">1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69</array>
<array dataType="xsd:integer" dictRef="x:elementType" size="69">7 7 7 7 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 1 1 1 1 1 1 1 1 1 1 1 1 77 6 1 1 1 6 6 6 6 6 1 6 1 6 1 1 6 8 8 6 1 6 1 1 1 6 1 1 1 6 1 1 1</array>
<list>
<array dataType="xsd:double" dictRef="cc:force" size="3">0.000008991 0.000014721 0.000003678</array>
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<array dataType="xsd:double" dictRef="cc:force" size="3">-0.000002287 0.000002491 0.000010484</array>
<array dataType="xsd:double" dictRef="cc:force" size="3">0.000003452 0.000011804 0.000010309</array>
<array dataType="xsd:double" dictRef="cc:force" size="3">-0.000055849 -0.000029158 -0.000243240</array>
<array dataType="xsd:double" dictRef="cc:force" size="3">0.000196713 -0.000226336 0.000357459</array>
<array dataType="xsd:double" dictRef="cc:force" size="3">0.000017034 -0.000001500 0.000009594</array>
<array dataType="xsd:double" dictRef="cc:force" size="3">-0.000004844 0.000002082 -0.000003876</array>
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<array dataType="xsd:double" dictRef="cc:force" size="3">-0.000001712 -0.000005374 0.000002203</array>
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<array dataType="xsd:double" dictRef="cc:force" size="3">-0.000002949 0.000009059 -0.000019032</array>
<array dataType="xsd:double" dictRef="cc:force" size="3">0.000004241 0.000002635 0.000003206</array>
<array dataType="xsd:double" dictRef="cc:force" size="3">0.000005726 -0.000012573 0.000009408</array>
<array dataType="xsd:double" dictRef="cc:force" size="3">-0.000001660 -0.000002918 0.000014299</array>
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</list>
<list cmlx:templateRef="cartesianforce">
<scalar dataType="xsd:double" dictRef="cc:maxforce">0.000357459</scalar>
<scalar dataType="xsd:double" dictRef="cc:rmsforce">0.000044410</scalar>
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</module>
<module cmlx:templateRef="l1102">
<list cmlx:templateRef="l1102">
<scalar dataType="xsd:string" dictRef="g:l1102">Symmetrizing basis deriv contribution to polar:</scalar>
<scalar dataType="xsd:string" dictRef="g:l1102">IMax=3 JMax=2 DiffMx= 0.00D+00</scalar>
</list>
</module>
<module cmlx:templateRef="l1102">
<list cmlx:templateRef="l1102">
<scalar dataType="xsd:string" dictRef="g:l1102">Symmetrizing basis deriv contribution to polar:</scalar>
<scalar dataType="xsd:string" dictRef="g:l1102">IMax=3 JMax=2 DiffMx= 0.00D+00</scalar>
</list>
</module>
<module cmlx:templateRef="l50X">
<scalar dataType="xsd:integer" dictRef="cc:ncycle">7</scalar>
<scalar dataType="xsd:double" dictRef="g:rbhflyp" units="nonsi:hartree">-1747.88496987</scalar>
</module>
<module cmlx:templateRef="l1102">
<list cmlx:templateRef="l1102">
<scalar dataType="xsd:string" dictRef="g:l1102">Symmetrizing basis deriv contribution to polar:</scalar>
<scalar dataType="xsd:string" dictRef="g:l1102">IMax=3 JMax=2 DiffMx= 0.00D+00</scalar>
</list>
</module>
</module>
</module>
<module dictRef="cc:finalization" id="finalization">
<propertyList>
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<scalar dataType="xsd:string">PT92666.100S</scalar>
</property>
<property dictRef="cc:jobdatetime.end">
<scalar dataType="xsd:date">2025-04-17T21:08:08.000</scalar>
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<property>
<module cmlx:templateRef="l601.mullik">
<scalar dataType="xsd:string" dictRef="g:title">Mulliken charges with hydrogens summed into heavy atoms:</scalar>
<scalar dataType="xsd:integer" dictRef="cc:serial">1</scalar>
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<array dataType="xsd:integer" dictRef="cc:serial" size="40">1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 37 38 42 43 44 45 46 48 50 53 54 55 56 58 62 66</array>
<array dataType="xsd:string" dictRef="cc:elementType" size="40">N N N N C C C C C C C C C C C C C C C C C C C C Ir C C C C C C C C C O O C C C C</array>
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<scalar dataType="xsd:double" dictRef="x:chargesum">-0.00000</scalar>
</module>
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<property dictRef="cc:popanal">
<module cmlx:templateRef="l601.popanal">
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<module cmlx:templateRef="l601.state">
<scalar dataType="xsd:string" dictRef="g:l601.state">1-A.</scalar>
</module>
<module cmlx:templateRef="mulliken">
<module cmlx:templateRef="l601.mullik">
<scalar dataType="xsd:string" dictRef="g:title">Mulliken charges:</scalar>
<scalar dataType="xsd:integer" dictRef="cc:serial">1</scalar>
<list cmlx:templateRef="row">
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<array dataType="xsd:string" dictRef="cc:elementType" size="69">N N N N C C C C C C C C C C C C C C C C C C C C H H H H H H H H H H H H Ir C H H H C C C C C H C H C H H C O O C H C H H H C H H H C H H H</array>
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</list>
<scalar dataType="xsd:double" dictRef="x:chargesum">-0.00000</scalar>
</module>
</module>
</module>
</property>
<property>
<module cmlx:templateRef="l601.mullik">
<scalar dataType="xsd:string" dictRef="g:title">Mulliken charges with hydrogens summed into heavy atoms:</scalar>
<scalar dataType="xsd:integer" dictRef="cc:serial">1</scalar>
<list cmlx:templateRef="row">
<array dataType="xsd:integer" dictRef="cc:serial" size="40">1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 37 38 42 43 44 45 46 48 50 53 54 55 56 58 62 66</array>
<array dataType="xsd:string" dictRef="cc:elementType" size="40">N N N N C C C C C C C C C C C C C C C C C C C C Ir C C C C C C C C C O O C C C C</array>
<array dataType="xsd:double" dictRef="x:charge" size="40">-0.293103 -0.300239 -0.299035 -0.297117 0.174746 -0.030449 -0.032551 0.164599 -0.078947 0.182429 -0.020059 -0.029587 0.170723 -0.096143 0.135809 -0.033620 -0.036272 0.149006 -0.115440 0.152707 -0.040572 -0.031392 0.169932 -0.090392 0.316738 0.085876 -0.120761 0.016435 0.033789 0.021107 -0.047600 -0.067021 -0.028644 0.303306 -0.182134 -0.272251 -0.125873 0.233545 0.224053 0.134403</array>
</list>
<scalar dataType="xsd:double" dictRef="x:chargesum">-0.00000</scalar>
</module>
</property>
<property>
<module cmlx:templateRef="l601.polariz">
<array dataType="xsd:double" dictRef="g:l601.pol.exact" size="6">0.000 0.000 0.000 0.000 0.000 0.000</array>
<array dataType="xsd:double" dictRef="g:l601.pol.approx" size="6">1242.645 -56.166 1266.145 242.084 64.983 638.477</array>
</module>
</property>
<property dictRef="cc:forces">
<scalar dictRef="cc:linkToAtoms">./ancestor::cml:module[@dictRef='cc:finalization']/cml:molecule[@id='mol9999']</scalar>
</property>
<property dictRef="cc:multipole">
<list cmlx:templateRef="multipole">
<array dataType="xsd:double" dictRef="cc:dipole" size="3">-1.9069 -3.6588 2.6679</array>
<scalar dataType="xsd:double" dictRef="x:dipole">4.9133</scalar>
<array dataType="xsd:double" dictRef="cc:quadrupole" size="3">-225.9631 -229.0604 -254.8611</array>
<array dataType="xsd:double" dictRef="cc:quadrupole" size="3">-3.5520 7.4392 -9.1298</array>
<array dataType="xsd:double" dictRef="cc:quadrupole" size="6">10.6651 7.5678 -18.2329 -3.5520 7.4392 -9.1298</array>
<array dataType="xsd:double" dictRef="cc:octapole" size="10">56.1743 19.8115 -28.8291 30.1071 7.7961 -17.0354 5.9597 -41.0893 -25.4621 -7.8333</array>
<array dataType="xsd:double" dictRef="cc:hexadecapole" size="15">-8734.1926 -5652.3614 -4430.0782 -5.6643 115.1415 -10.6054 38.8160 3.1285 -143.1317 -2475.0059 -2330.1051 -1791.2912 24.8865 31.7145 -28.6955</array>
</list>
</property>
<property dictRef="cc:virtualorbs">
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</property>
<property dictRef="cc:virtualorbs">
<array dataType="xsd:string" delimiter="|" size="579">(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)</array>
</property>
<property dictRef="cc:occupiedorbs">
<array dataType="xsd:string" delimiter="|" size="144">(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)</array>
</property>
<property dictRef="cc:occupiedorbs">
<array dataType="xsd:string" delimiter="|" size="144">(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)|(A)</array>
</property>
</propertyList>
<module dictRef="cc:userDefinedModule" id="otherComponents">
<module cmlx:templateRef="l9999.archive" dictRef="cc:userDefinedModule">
<scalar dataType="xsd:string" dictRef="g:zmat">0</scalar>
<scalar dataType="xsd:string" dictRef="cc:electronicstate">1-A</scalar>
<scalar dataType="xsd:double" dictRef="cc:hfenergy" units="nonsi:hartree">-1747.8849699</scalar>
<scalar dataType="xsd:double" dictRef="cc:rmsd" units="nonsi:unknown">5.026E-9</scalar>
<scalar dataType="xsd:double" dictRef="cc:rmsf" units="nonsi:unknown">6.79E-7</scalar>
<scalar dataType="xsd:string" dictRef="x:Quadrupole">7.946829,5.6035411,-13.55037,-2.6296362,5.5604438,-6.7725218</scalar>
<scalar dataType="xsd:string" dictRef="cc:pointgroup">C01 [X(C33H29Ir1N4O2)]</scalar>
<array dataType="xsd:double" dictRef="cc:dipole" size="3" units="nonsi:debye">-0.7450667 -1.4419725 1.0498537</array>
<array dataType="xsd:double" delimiter="|" dictRef="cc:polarizability" size="6" units="nonsi:unknown">0.|0.|0.|0.|0.|0.</array>
</module>
</module>
<molecule formalCharge="0" id="mol9999" spinMultiplicity="1">
<atomArray>
<atom elementType="N" id="a1" x3="-0.84261089" y3="1.59271351" z3="-1.05244826">
<property dictRef="cc:force">
<array dataType="xsd:double" id="a1.0" size="3">0.000000417 0.000000247 0.000000285</array>
</property>
<property dictRef="cc:force">
<array dataType="xsd:double" id="a1.1" size="3">0.000000303 -0.000000597 0.000000041</array>
</property>
<property dictRef="cc:force">
<array dataType="xsd:double" id="a1.2" size="3">-0.000000395 -0.000000492 -0.000000380</array>
</property>
<property dictRef="cc:force">
<array dataType="xsd:double" id="a1.3" size="3">-0.000000440 0.000000281 -0.000000193</array>
</property>
<property dictRef="cc:force">
<array dataType="xsd:double" id="a1.4" size="3">0.000000048 0.000000520 0.000000276</array>
</property>
<property dictRef="cc:force">
<array dataType="xsd:double" id="a1.5" size="3">0.000000427 0.000000728 0.000000553</array>
</property>
<property dictRef="cc:force">
<array dataType="xsd:double" id="a1.6" size="3">0.000000709 0.000000550 0.000000641</array>
</property>
<property dictRef="cc:force">
<array dataType="xsd:double" id="a1.7" size="3">0.000000521 0.000000360 0.000000438</array>
</property>
<property dictRef="cc:force">
<array dataType="xsd:double" id="a1.8" size="3">0.000000752 -0.000000063 0.000000462</array>
</property>
<property dictRef="cc:force">
<array dataType="xsd:double" id="a1.9" size="3">0.000000623 -0.000000229 0.000000302</array>
</property>
<property dictRef="cc:force">
<array dataType="xsd:double" id="a1.10" size="3">0.000000765 -0.000000655 0.000000268</array>
</property>
<property dictRef="cc:force">
<array dataType="xsd:double" id="a1.11" size="3">0.000000626 -0.000000909 0.000000086</array>
</property>
<property dictRef="cc:force">
<array dataType="xsd:double" id="a1.12" size="3">0.000000414 -0.000000676 0.000000004</array>
</property>
<property dictRef="cc:force">
<array dataType="xsd:double" id="a1.13" size="3">0.000000071 -0.000000951 -0.000000271</array>
</property>
<property dictRef="cc:force">
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</property>
<property dictRef="cc:force">
<array dataType="xsd:double" id="a1.15" size="3">-0.000000482 -0.000000846 -0.000000594</array>
</property>
<property dictRef="cc:force">
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</property>
<property dictRef="cc:force">
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</property>
<property dictRef="cc:force">
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</property>
<property dictRef="cc:force">
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</property>
<property dictRef="cc:force">
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</property>
<property dictRef="cc:force">
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</property>
<property dictRef="cc:force">
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</property>
<property dictRef="cc:force">
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</property>
<property dictRef="cc:force">
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</property>
<property dictRef="cc:force">
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</property>
<property dictRef="cc:force">
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</property>
<property dictRef="cc:force">
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</property>
<property dictRef="cc:force">
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</property>
<property dictRef="cc:force">
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<property dictRef="cc:force">
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<property dictRef="cc:force">
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</property>
<property dictRef="cc:force">
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</property>
<property dictRef="cc:force">
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<property dictRef="cc:force">
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</property>
<property dictRef="cc:force">
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</property>
<property dictRef="cc:force">
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</property>
<property dictRef="cc:force">
<array dataType="xsd:double" id="a1.37" size="3">-0.000000097 0.000000035 -0.000000052</array>
</property>
<property dictRef="cc:force">
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<scalar cmlx:templateRef="title" dataType="xsd:string" dictRef="cc:title">Title Card Required</scalar>
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<scalar cmlx:templateRef="redundant" dataType="xsd:string" dictRef="g:redundant">Redundant internal coordinates found in file.  (old form).</scalar>
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<module cmlx:templateRef="l103" dictRef="cc:userDefinedModule">
<list cmlx:templateRef="berny">
<scalar dataType="xsd:string" dictRef="g:optimization">Berny optimization.</scalar>
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<list cmlx:templateRef="length">
<array dataType="xsd:string" dictRef="g:symbol" size="79">R1 R2 R3 R4 R5 R6 R7 R8 R9 R10 R11 R12 R13 R14 R15 R16 R17 R18 R19 R20 R21 R22 R23 R24 R25 R26 R27 R28 R29 R30 R31 R32 R33 R34 R35 R36 R37 R38 R39 R40 R41 R42 R43 R44 R45 R46 R47 R48 R49 R50 R51 R52 R53 R54 R55 R56 R57 R58 R59 R60 R61 R62 R63 R64 R65 R66 R67 R68 R69 R70 R71 R72 R73 R74 R75 R76 R77 R78 R79</array>
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<array dataType="xsd:integer" dictRef="g:atom2" size="79">5 8 37 10 13 37 15 18 37 20 23 37 6 24 7 25 8 26 9 10 27 11 12 28 13 29 14 15 30 16 17 31 18 32 19 20 33 21 22 34 23 35 24 36 38 42 39 40 41 43 53 56 57 44 45 46 47 48 49 50 51 50 52 66 54 55 56 57 58 62 59 60 61 63 64 65 67 68 69</array>
<array dataType="xsd:double" dictRef="cc:distance" size="79">1.3705 1.3712 2.0612 1.3709 1.3726 2.0582 1.3754 1.3745 2.0533 1.3733 1.3717 2.0564 1.4486 1.3927 1.365 1.0886 1.4492 1.0887 1.3926 1.3923 1.0912 1.4483 1.364 1.0885 1.4491 1.0886 1.3923 1.3944 1.0915 1.4459 1.3679 1.0888 1.4458 1.0888 1.3954 1.3933 1.0917 1.4491 1.3656 1.0888 1.4476 1.0886 1.3927 1.0911 2.0932 2.2876 1.1007 1.1017 1.1009 1.4673 1.4834 2.2404 1.2488 1.4079 1.4077 1.3936 1.09 1.3897 1.0915 1.4021 1.0933 1.4048 1.0933 1.5067 1.1962 1.3882 1.392 1.3797 1.5028 1.5003 1.0995 1.104 1.0977 1.1049 1.0989 1.0944 1.1002 1.1044 1.1012</array>
<array dataType="xsd:string" delimiter="|" dictRef="g:deriv" size="79">calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically</array>
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<list cmlx:templateRef="angle">
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<array dataType="xsd:integer" dictRef="g:atom2" size="148">1 1 1 2 2 2 3 3 3 4 4 4 5 5 5 6 6 6 7 7 7 8 8 8 9 9 9 10 10 10 11 11 11 12 12 12 13 13 13 14 14 14 15 15 15 16 16 16 17 17 17 18 18 18 19 19 19 20 20 20 21 21 21 22 22 22 23 23 23 24 24 24 37 37 37 37 37 37 37 37 37 37 37 37 38 38 38 38 38 38 42 42 42 42 42 42 42 42 42 43 43 43 44 44 44 45 45 45 46 46 46 48 48 48 50 50 50 53 53 53 55 56 56 56 56 56 56 56 56 56 58 58 58 58 58 58 62 62 62 62 62 62 66 66 66 66 66 66</array>
<array dataType="xsd:integer" dictRef="g:atom3" size="148">8 37 37 13 37 37 18 37 37 23 37 37 6 24 24 7 25 25 8 26 26 7 9 9 10 27 27 9 11 11 12 28 28 13 29 29 12 14 14 15 30 30 14 16 16 17 31 31 18 32 32 17 19 19 20 33 33 19 21 21 22 34 34 23 35 35 22 24 24 23 36 36 2 4 38 42 3 38 42 4 38 42 38 42 39 40 41 40 41 41 43 53 56 57 53 56 57 56 57 44 45 45 46 47 47 48 49 49 50 51 51 50 52 52 48 66 66 54 55 55 56 55 58 62 57 58 62 58 62 62 59 60 61 60 61 61 63 64 65 64 65 65 67 68 69 68 69 69</array>
<array dataType="xsd:double" dictRef="cc:angle" size="148">107.6954 126.1684 126.1354 107.4982 126.2064 126.2718 107.5629 126.1658 126.2251 107.5873 126.2137 126.1986 109.1489 125.5075 125.3431 107.0173 124.5656 128.4169 107.0492 128.3929 124.5554 109.0781 125.4995 125.4083 126.6526 116.7016 116.6448 125.5485 109.2183 125.2332 107.0999 124.5272 128.3729 106.9566 128.4261 124.6171 109.2154 125.3727 125.401 126.6502 116.6984 116.6499 125.4384 109.0937 125.4417 107.1067 124.6227 128.2706 107.1052 128.2367 124.6501 109.1249 125.4016 125.4618 126.5692 116.653 116.7245 125.4014 109.1304 125.4574 106.9898 124.6426 128.3599 107.1073 128.3394 124.5532 109.1781 125.5635 125.2244 126.6026 116.7044 116.6877 89.915 89.9334 86.7425 86.3488 90.0212 88.0173 90.9085 90.0529 91.2571 95.6514 89.7599 91.2952 110.1186 109.5997 110.1525 108.8804 108.9328 109.13 114.0038 113.4924 122.2845 97.7506 117.9248 112.7785 111.039 69.4052 99.5439 120.859 120.7745 118.3164 120.3246 119.2345 120.3923 120.7503 119.5301 119.7167 121.5321 119.0208 119.4471 121.2259 119.1535 119.597 117.7966 121.3267 120.8582 129.7312 107.3325 122.9335 105.26 75.1114 103.5167 126.4957 98.967 114.773 113.1614 109.4069 100.6286 117.0919 110.9252 108.4282 112.0517 108.2611 108.6019 108.473 108.2154 111.3181 111.0755 108.1903 108.5161 109.4318 111.591 110.9503 111.5684 107.3063 108.2083 106.9983</array>
<array dataType="xsd:string" delimiter="|" dictRef="g:deriv" size="148">calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically</array>
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<array dataType="xsd:string" dictRef="g:symbol" size="6">A149 A150 A151 A152 A153 A154</array>
<array dataType="xsd:integer" dictRef="g:atom1" size="6">1 2 38 1 2 38</array>
<array dataType="xsd:integer" dictRef="g:atom2" size="6">37 37 37 37 37 37</array>
<array dataType="xsd:integer" dictRef="g:atom3" size="6">3 4 42 3 4 42</array>
<array dataType="xsd:integer" dictRef="g:atom4" size="6">2 1 1 2 1 1</array>
<array dataType="xsd:integer" dictRef="g:atom5" size="6">-1 -1 -1 -2 -2 -2</array>
<scalar dataType="xsd:double" dictRef="g:lll">179.9362</scalar>
<array dataType="xsd:string" delimiter="|" dictRef="g:deriv" size="6">calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically</array>
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<scalar dataType="xsd:double" dictRef="g:lll">179.8484</scalar>
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<list cmlx:templateRef="lll">
<scalar dataType="xsd:double" dictRef="g:lll">173.0913</scalar>
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<list cmlx:templateRef="lll">
<scalar dataType="xsd:double" dictRef="g:lll">181.9994</scalar>
</list>
<list cmlx:templateRef="lll">
<scalar dataType="xsd:double" dictRef="g:lll">177.7822</scalar>
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<list cmlx:templateRef="lll">
<scalar dataType="xsd:double" dictRef="g:lll">181.0654</scalar>
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<list cmlx:templateRef="dihed">
<array dataType="xsd:string" dictRef="g:symbol" size="257">D1 D2 D3 D4 D5 D6 D7 D8 D9 D10 D11 D12 D13 D14 D15 D16 D17 D18 D19 D20 D21 D22 D23 D24 D25 D26 D27 D28 D29 D30 D31 D32 D33 D34 D35 D36 D37 D38 D39 D40 D41 D42 D43 D44 D45 D46 D47 D48 D49 D50 D51 D52 D53 D54 D55 D56 D57 D58 D59 D60 D61 D62 D63 D64 D65 D66 D67 D68 D69 D70 D71 D72 D73 D74 D75 D76 D77 D78 D79 D80 D81 D82 D83 D84 D85 D86 D87 D88 D89 D90 D91 D92 D93 D94 D95 D96 D97 D98 D99 D100 D101 D102 D103 D104 D105 D106 D107 D108 D109 D110 D111 D112 D113 D114 D115 D116 D117 D118 D119 D120 D121 D122 D123 D124 D125 D126 D127 D128 D129 D130 D131 D132 D133 D134 D135 D136 D137 D138 D139 D140 D141 D142 D143 D144 D145 D146 D147 D148 D149 D150 D151 D152 D153 D154 D155 D156 D157 D158 D159 D160 D161 D162 D163 D164 D165 D166 D167 D168 D169 D170 D171 D172 D173 D174 D175 D176 D177 D178 D179 D180 D181 D182 D183 D184 D185 D186 D187 D188 D189 D190 D191 D192 D193 D194 D195 D196 D197 D198 D199 D200 D201 D202 D203 D204 D205 D206 D207 D208 D209 D210 D211 D212 D213 D214 D215 D216 D217 D218 D219 D220 D221 D222 D223 D224 D225 D226 D227 D228 D229 D230 D231 D232 D233 D234 D235 D236 D237 D238 D239 D240 D241 D242 D243 D244 D245 D246 D247 D248 D249 D250 D251 D252 D253 D254 D255 D256 D257</array>
<array dataType="xsd:integer" dictRef="g:atom1" size="257">8 8 37 37 5 5 37 37 5 5 5 5 8 8 8 8 13 13 37 37 10 10 37 37 10 10 10 10 13 13 13 13 18 18 37 37 15 15 37 37 15 15 15 15 18 18 18 18 23 23 37 37 20 20 37 37 20 20 20 20 23 23 23 23 1 1 24 24 1 1 6 6 5 5 25 25 6 6 26 26 1 1 7 7 8 8 27 27 2 2 9 9 10 10 28 28 11 11 29 29 2 2 12 12 13 13 30 30 3 3 14 14 15 15 31 31 16 16 32 32 3 3 17 17 18 18 33 33 4 4 19 19 20 20 34 34 21 21 35 35 4 4 22 22 1 1 1 2 2 2 3 3 3 4 4 4 1 1 1 1 2 2 2 2 3 3 3 3 4 4 4 4 37 37 53 53 56 56 57 57 37 37 43 43 56 56 57 57 37 37 37 43 43 43 53 53 53 42 42 45 45 42 42 44 44 43 43 47 47 43 43 49 49 44 44 51 51 45 45 52 52 46 46 46 48 48 48 42 54 53 53 53 53 42 42 42 55 55 55 57 57 57 62 62 62 42 42 42 55 55 55 57 57 57 58 58 58</array>
<array dataType="xsd:integer" dictRef="g:atom2" size="257">1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 5 5 5 5 5 5 5 5 6 6 6 6 7 7 7 7 8 8 8 8 9 9 9 9 10 10 10 10 11 11 11 11 12 12 12 12 13 13 13 13 14 14 14 14 15 15 15 15 16 16 16 16 17 17 17 17 18 18 18 18 19 19 19 19 20 20 20 20 21 21 21 21 22 22 22 22 23 23 23 23 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 37 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 43 43 43 43 43 43 43 43 44 44 44 44 45 45 45 45 46 46 46 46 48 48 48 48 50 50 50 50 50 50 53 53 55 55 55 55 56 56 56 56 56 56 56 56 56 56 56 56 56 56 56 56 56 56 56 56 56 56 56 56</array>
<array dataType="xsd:integer" dictRef="g:atom3" size="257">5 5 5 5 8 8 8 8 37 37 37 37 37 37 37 37 10 10 10 10 13 13 13 13 37 37 37 37 37 37 37 37 15 15 15 15 18 18 18 18 37 37 37 37 37 37 37 37 20 20 20 20 23 23 23 23 37 37 37 37 37 37 37 37 6 6 6 6 24 24 24 24 7 7 7 7 8 8 8 8 9 9 9 9 10 10 10 10 11 11 11 11 12 12 12 12 13 13 13 13 14 14 14 14 15 15 15 15 16 16 16 16 17 17 17 17 18 18 18 18 19 19 19 19 20 20 20 20 21 21 21 21 22 22 22 22 23 23 23 23 24 24 24 24 38 38 38 38 38 38 38 38 38 38 38 38 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 43 43 43 43 43 43 43 43 53 53 53 53 53 53 53 53 56 56 56 56 56 56 56 56 56 44 44 44 44 45 45 45 45 46 46 46 46 48 48 48 48 50 50 50 50 50 50 50 50 66 66 66 66 66 66 55 55 56 56 56 56 58 58 58 58 58 58 58 58 58 58 58 58 62 62 62 62 62 62 62 62 62 62 62 62</array>
<array dataType="xsd:integer" dictRef="g:atom4" size="257">6 24 6 24 7 9 7 9 2 4 38 42 2 4 38 42 9 11 9 11 12 14 12 14 1 3 38 42 1 3 38 42 14 16 14 16 17 19 17 19 2 4 38 42 2 4 38 42 19 21 19 21 22 24 22 24 1 3 38 42 1 3 38 42 7 25 7 25 23 36 23 36 8 26 8 26 1 9 1 9 10 27 10 27 2 11 2 11 12 28 12 28 13 29 13 29 2 14 2 14 15 30 15 30 3 16 3 16 17 31 17 31 18 32 18 32 3 19 3 19 20 33 20 33 4 21 4 21 22 34 22 34 23 35 23 35 4 24 4 24 5 36 5 36 39 40 41 39 40 41 39 40 41 39 40 41 43 53 56 57 43 53 56 57 43 53 56 57 43 53 56 57 44 45 44 45 44 45 44 45 54 55 54 55 54 55 54 55 55 58 62 55 58 62 55 58 62 46 47 46 47 48 49 48 49 50 51 50 51 50 52 50 52 48 66 48 66 46 66 46 66 67 68 69 67 68 69 56 56 42 57 58 62 59 60 61 59 60 61 59 60 61 59 60 61 63 64 65 63 64 65 63 64 65 63 64 65</array>
<array dataType="xsd:double" dictRef="cc:dihed" size="257">-0.9644 178.7978 179.3511 -0.8868 1.0822 -177.6118 -179.2331 2.0729 177.5414 -0.2408 89.5225 -91.5429 -2.0865 -179.8687 -90.1054 88.8292 178.9136 -1.0879 0.5983 -179.4032 1.0511 -177.7957 179.365 0.5182 0.8403 178.8409 87.5838 -85.5067 -177.1667 0.8339 -90.4232 96.4863 -178.6785 -0.4635 3.6788 -178.1062 0.7901 -178.0206 178.431 -0.3797 -2.7906 174.9876 85.2266 -93.7056 179.9956 -2.2261 -91.9871 89.0806 178.0389 -0.8154 -1.7444 179.4013 0.4865 178.4517 -179.7301 -1.7649 -178.7786 3.2217 94.4786 -92.4323 1.4773 -176.5223 -85.2655 87.8237 0.4707 -179.6631 -179.2919 0.5742 1.105 -179.7642 -179.1705 -0.0397 0.19 179.6334 -179.6693 -0.2259 -0.792 177.9035 179.7377 -1.5668 -0.041 179.5778 -178.5266 1.0921 -1.4064 178.5954 178.9747 -1.0235 0.7122 -179.3319 -179.2893 0.6666 -0.0594 179.7885 179.9869 -0.1652 -0.6107 178.2358 179.5341 -1.6194 -0.5076 179.023 -179.1717 0.3589 -1.7581 -179.6876 178.7111 0.7816 -0.0546 179.9425 178.1603 -1.8426 0.5234 179.522 -179.4736 -0.475 -0.8297 177.9801 -179.8736 -1.0637 3.3569 -179.4016 -175.2636 1.9779 -2.2076 176.4635 -179.4474 -0.7763 0.848 179.9172 -178.0055 1.0637 -0.5273 179.569 -179.5507 0.5456 0.0444 -177.9294 179.9526 1.9789 0.3288 -178.8021 177.976 -1.1549 53.07 172.8225 -67.0961 -36.9577 82.7947 -157.1239 -126.9354 -7.183 112.8984 143.017 -97.2306 22.8508 48.037 -90.7733 -170.4576 165.245 137.8939 -0.9164 -80.6007 -104.8982 -131.9949 89.1948 9.5105 -14.787 -41.8135 179.3762 99.6919 75.3944 -98.7004 78.6816 38.1771 -144.4409 116.1006 -66.5174 152.0637 -30.5543 73.5997 -105.7953 -63.4878 117.1172 -169.0889 11.5161 176.4375 -2.9575 94.1033 -153.4378 -13.9297 -123.973 -11.5141 127.994 -11.3411 101.1178 -119.3741 175.5995 -1.8746 -1.8455 -179.3196 -177.5051 1.8711 -0.0579 179.3183 1.92 -178.0618 179.3647 -0.6171 1.9552 -179.8177 -177.4199 0.8073 -0.0468 -178.4978 179.9349 1.4839 -1.8858 176.5728 179.8948 -1.6466 -21.8239 97.7861 -143.0079 159.7724 -80.6176 38.5884 -18.1663 162.3881 11.7655 29.8203 -86.4944 135.5201 86.9462 -154.3023 -34.6115 166.5702 -74.6783 45.0125 56.4139 175.1653 -65.1439 -57.156 61.5954 -178.7138 164.303 -76.9329 45.2831 76.0868 -165.1491 -42.9331 -179.2717 -60.5076 61.7085 -60.8642 57.8999 -179.884</array>
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analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically|calculate D2E/DX2 analytically</array>
</list>
</module>
</module>
<module cmlx:templateRef="l103" dictRef="cc:userDefinedModule">
<list cmlx:templateRef="berny">
<scalar dataType="xsd:string" dictRef="g:optimization">Berny optimization.</scalar>
</list>
<module cmlx:templateRef="l103.localminsaddle">
<scalar cmlx:templateRef="r" dataType="xsd:string" dictRef="cc:minmaxts">saddle point</scalar>
<array cmlx:templateRef="junk" dataType="xsd:string" dictRef="x:junk1" size="9">Step number 1 out of a maximum of 2</array>
<array cmlx:templateRef="junk" dataType="xsd:string" dictRef="x:junk1" size="7">All quantities printed in internal units (Hartrees-Bohrs-Radians)</array>
<array cmlx:templateRef="junk" dataType="xsd:string" dictRef="x:junk1" size="9">Second derivative matrix not updated -- analytic derivatives used.</array>
<array cmlx:templateRef="eigenvaluelist" dataType="xsd:double" dictRef="" size="201">-0.01232 0.00002 0.00010 0.00087 0.00108 0.00158 0.00561 0.00641 0.00747 0.00868 0.00913 0.00957 0.01025 0.01085 0.01124 0.01180 0.01411 0.01423 0.01425 0.01433 0.01515 0.01541 0.01570 0.01584 0.01595 0.01665 0.01692 0.01804 0.01816 0.01892 0.01967 0.01980 0.01997 0.02007 0.02017 0.02110 0.02120 0.02136 0.02203 0.02293 0.02366 0.02409 0.02520 0.02626 0.02638 0.02824 0.02861 0.02879 0.02995 0.03045 0.03315 0.03385 0.03442 0.03482 0.03512 0.03549 0.03666 0.03713 0.03959 0.04226 0.04317 0.04344 0.04408 0.04644 0.04986 0.05503 0.05505 0.05672 0.05700 0.05755 0.06448 0.06956 0.08948 0.09025 0.09282 0.09308 0.09346 0.09393 0.09421 0.09465 0.10208 0.10227 0.10239 0.10246 0.10492 0.11287 0.11352 0.11446 0.11509 0.11554 0.11679 0.11695 0.11908 0.11970 0.12084 0.12124 0.12406 0.12672 0.13172 0.13608 0.13894 0.14019 0.14063 0.14128 0.14190 0.14199 0.14324 0.14981 0.16000 0.16542 0.16569 0.16618 0.16670 0.17250 0.18132 0.18176 0.18632 0.19110 0.19332 0.19533 0.19847 0.19919 0.20961 0.21187 0.21285 0.21324 0.21343 0.21467 0.21910 0.22116 0.24643 0.26382 0.27063 0.27176 0.27461 0.29004 0.29037 0.30264 0.30453 0.30538 0.31723 0.32155 0.32263 0.32742 0.33009 0.33048 0.33270 0.33481 0.33619 0.33816 0.33993 0.34026 0.34098 0.34308 0.34387 0.34511 0.34606 0.34710 0.34776 0.34910 0.35374 0.35506 0.35738 0.35864 0.36033 0.36070 0.36146 0.36180 0.36356 0.36369 0.36717 0.36829 0.36853 0.36874 0.36940 0.36960 0.37056 0.37080 0.37322 0.37913 0.40215 0.40309 0.41036 0.42226 0.43089 0.43184 0.43321 0.44406 0.44499 0.46232 0.46476 0.46580 0.46630 0.46674 0.47325 0.51991 0.53704 0.54315 0.54580 0.54621 0.92371</array>
<module cmlx:templateRef="negativeeigenvaluelist">
<scalar cmlx:templateRef="grot" dataType="xsd:string" dictRef="x:stuffff">R68       R53       R46      D180      D179</scalar>
<scalar cmlx:templateRef="grot" dataType="xsd:string" dictRef="x:stuffff">1                   -0.52920   0.37744  -0.24942  -0.23073  -0.21478</scalar>
<scalar cmlx:templateRef="grot" dataType="xsd:string" dictRef="x:stuffff">A94       A99      D188      D187      D183</scalar>
</module>
<array cmlx:templateRef="junk" dataType="xsd:string" dictRef="x:junk1" size="8">Angle between quadratic step and forces= 44.94 degrees.</array>
<list cmlx:templateRef="iterationList">
<array dataType="xsd:integer" dictRef="cc:serial" size="3">1 2 3</array>
<array dataType="xsd:double" dictRef="g:rmscart" size="3">0.01048789 0.00034297 0.00000028</array>
<array dataType="xsd:double" dictRef="g:rmsint" size="3">0.00033092 0.00000026 0.00000015</array>
</list>
</module>
<module cmlx:templateRef="l103.deltas">
<list cmlx:templateRef="delta">
<array dataType="xsd:string" dictRef="cc:variable" size="490">R1 R2 R3 R4 R5 R6 R7 R8 R9 R10 R11 R12 R13 R14 R15 R16 R17 R18 R19 R20 R21 R22 R23 R24 R25 R26 R27 R28 R29 R30 R31 R32 R33 R34 R35 R36 R37 R38 R39 R40 R41 R42 R43 R44 R45 R46 R47 R48 R49 R50 R51 R52 R53 R54 R55 R56 R57 R58 R59 R60 R61 R62 R63 R64 R65 R66 R67 R68 R69 R70 R71 R72 R73 R74 R75 R76 R77 R78 R79 A1 A2 A3 A4 A5 A6 A7 A8 A9 A10 A11 A12 A13 A14 A15 A16 A17 A18 A19 A20 A21 A22 A23 A24 A25 A26 A27 A28 A29 A30 A31 A32 A33 A34 A35 A36 A37 A38 A39 A40 A41 A42 A43 A44 A45 A46 A47 A48 A49 A50 A51 A52 A53 A54 A55 A56 A57 A58 A59 A60 A61 A62 A63 A64 A65 A66 A67 A68 A69 A70 A71 A72 A73 A74 A75 A76 A77 A78 A79 A80 A81 A82 A83 A84 A85 A86 A87 A88 A89 A90 A91 A92 A93 A94 A95 A96 A97 A98 A99 A100 A101 A102 A103 A104 A105 A106 A107 A108 A109 A110 A111 A112 A113 A114 A115 A116 A117 A118 A119 A120 A121 A122 A123 A124 A125 A126 A127 A128 A129 A130 A131 A132 A133 A134 A135 A136 A137 A138 A139 A140 A141 A142 A143 A144 A145 A146 A147 A148 A149 A150 A151 A152 A153 A154 D1 D2 D3 D4 D5 D6 D7 D8 D9 D10 D11 D12 D13 D14 D15 D16 D17 D18 D19 D20 D21 D22 D23 D24 D25 D26 D27 D28 D29 D30 D31 D32 D33 D34 D35 D36 D37 D38 D39 D40 D41 D42 D43 D44 D45 D46 D47 D48 D49 D50 D51 D52 D53 D54 D55 D56 D57 D58 D59 D60 D61 D62 D63 D64 D65 D66 D67 D68 D69 D70 D71 D72 D73 D74 D75 D76 D77 D78 D79 D80 D81 D82 D83 D84 D85 D86 D87 D88 D89 D90 D91 D92 D93 D94 D95 D96 D97 D98 D99 D100 D101 D102 D103 D104 D105 D106 D107 D108 D109 D110 D111 D112 D113 D114 D115 D116 D117 D118 D119 D120 D121 D122 D123 D124 D125 D126 D127 D128 D129 D130 D131 D132 D133 D134 D135 D136 D137 D138 D139 D140 D141 D142 D143 D144 D145 D146 D147 D148 D149 D150 D151 D152 D153 D154 D155 D156 D157 D158 D159 D160 D161 D162 D163 D164 D165 D166 D167 D168 D169 D170 D171 D172 D173 D174 D175 D176 D177 D178 D179 D180 D181 D182 D183 D184 D185 D186 D187 D188 D189 D190 D191 D192 D193 D194 D195 D196 D197 D198 D199 D200 D201 D202 D203 D204 D205 D206 D207 D208 D209 D210 D211 D212 D213 D214 D215 D216 D217 D218 D219 D220 D221 D222 D223 D224 D225 D226 D227 D228 D229 D230 D231 D232 D233 D234 D235 D236 D237 D238 D239 D240 D241 D242 D243 D244 D245 D246 D247 D248 D249 D250 D251 D252 D253 D254 D255 D256 D257</array>
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</module>
<module cmlx:templateRef="l103.itemconverge">
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<array dataType="xsd:string" delimiter="|" dictRef="g:item" size="4">|Maximum Force|RMS     Force|Maximum Displacement|RMS     Displacement|</array>
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<array dataType="xsd:double" dictRef="g:threshold" size="4">0.000450 0.000300 0.001800 0.001200</array>
<array dataType="xsd:string" dictRef="g:converged" size="4">YES YES NO NO</array>
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</module>
<module cmlx:templateRef="preddelta">
<list cmlx:templateRef="predicted">
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<module cmlx:templateRef="l103.optimizedparam">
<list cmlx:templateRef="completed">
<scalar dataType="xsd:string" dictRef="g:optimization">Optimization completed on the basis of negligible forces.</scalar>
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<array dataType="xsd:string" delimiter="|" dictRef="g:deriv" size="256">-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0|-DE/DX =    0.0</array>
</list>
</module>
</module>
</module>
</module>
<module dictRef="cc:calculation" id="calculation">
<module dictRef="cc:userDefinedModule" id="otherComponents">
<module cmlx:templateRef="l301">
<module cmlx:templateRef="l301.basis">
<scalar dataType="xsd:string" dictRef="cc:basis">def2SVP</scalar>
<scalar dataType="xsd:string" dictRef="cc:diffuse">(5D, 7F)</scalar>
<list cmlx:templateRef="symmadaptcart">
<array dataType="xsd:integer" dictRef="cc:adapted" size="1">767</array>
<array dataType="xsd:string" dictRef="cc:symm" size="1">A</array>
</list>
<list cmlx:templateRef="symmadapt">
<array dataType="xsd:integer" dictRef="cc:adapted" size="1">723</array>
<array dataType="xsd:string" dictRef="cc:symm" size="1">A</array>
</list>
<scalar dataType="xsd:integer" dictRef="cc:basiscount">723</scalar>
<scalar dataType="xsd:integer" dictRef="g:primbasis">1243</scalar>
<scalar dataType="xsd:integer" dictRef="cc:cartesianbasis">767</scalar>
<scalar dataType="xsd:integer" dictRef="cc:alphae">144</scalar>
<scalar dataType="xsd:integer" dictRef="cc:betae">144</scalar>
<scalar dataType="xsd:double" dictRef="cc:nucrepener">5307.2642107029</scalar>
<scalar dataType="xsd:integer" dictRef="cc:natoms">69</scalar>
<scalar dataType="xsd:integer" dictRef="cc:nactiveatoms">69</scalar>
<scalar dataType="xsd:integer" dictRef="cc:uniqatoms">69</scalar>
<scalar dataType="xsd:double" dictRef="g:sfac">1.00e+00</scalar>
<scalar dataType="xsd:integer" dictRef="g:natfmm">60</scalar>
<scalar dataType="xsd:string" dictRef="g:big">T</scalar>
</module>
</module>
<module cmlx:templateRef="l202" dictRef="cc:userDefinedModule">
<module cmlx:templateRef="l202.rotconst">
<array cmlx:templateRef="rotconst" dataType="xsd:double" dictRef="cc:rotconst" size="3">0.1322963 0.1003945 0.0903506</array>
</module>
</module>
<module cmlx:templateRef="l50X">
<scalar dataType="xsd:integer" dictRef="cc:ncycle">1</scalar>
<scalar dataType="xsd:double" dictRef="g:rbhflyp" units="nonsi:hartree">-1747.88496987</scalar>
</module>
<module cmlx:templateRef="l1102">
<list cmlx:templateRef="l1102">
<scalar dataType="xsd:string" dictRef="g:l1102">Symmetrizing basis deriv contribution to polar:</scalar>
<scalar dataType="xsd:string" dictRef="g:l1102">IMax=3 JMax=2 DiffMx= 0.00D+00</scalar>
</list>
</module>
<module cmlx:templateRef="l1002.minotr">
<list cmlx:templateRef="l1002">
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">IDoAtm=11111111111111111111111111111111111111111111111111</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">IDoAtm=1111111111111111111</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Differentiating once with respect to electric field.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">with respect to dipole field.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Differentiating once with respect to nuclear coordinates.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">CalDSu exits because no D1Ps are significant.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Defaulting to unpruned grid for atomic number  77.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">There are   210 degrees of freedom in the 1st order CPHF.  IDoFFX=6 NUNeed=     3.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">207 vectors produced by pass  0 Test12= 8.34D-14 1.00D-09 XBig12= 1.78D+03 1.63D+01.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">AX will form    96 AO Fock derivatives at one time.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">207 vectors produced by pass  1 Test12= 8.34D-14 1.00D-09 XBig12= 6.31D+02 3.94D+00.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">207 vectors produced by pass  2 Test12= 8.34D-14 1.00D-09 XBig12= 7.26D+00 3.05D-01.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">207 vectors produced by pass  3 Test12= 8.34D-14 1.00D-09 XBig12= 3.49D-02 1.33D-02.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">207 vectors produced by pass  4 Test12= 8.34D-14 1.00D-09 XBig12= 8.10D-05 7.45D-04.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">189 vectors produced by pass  5 Test12= 8.34D-14 1.00D-09 XBig12= 1.11D-07 2.70D-05.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">58 vectors produced by pass  6 Test12= 8.34D-14 1.00D-09 XBig12= 1.16D-10 9.14D-07.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">3 vectors produced by pass  7 Test12= 8.34D-14 1.00D-09 XBig12= 1.12D-13 3.87D-08.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">1 vectors produced by pass  8 Test12= 8.34D-14 1.00D-09 XBig12= 9.31D-17 1.35D-09.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">InvSVY:  IOpt=1 It=  1 EMax= 4.26D-14</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Solved reduced A of dimension  1286 with   210 vectors.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">Isotropic polarizability for W=    0.000000      480.37 Bohr**3.</scalar>
<scalar dataType="xsd:string" dictRef="g:l1002.minotr">End of Minotr F.D. properties file   721 does not exist.</scalar>
</list>
</module>
</module>
</module>
<module dictRef="cc:finalization" id="finalization">
<propertyList>
<property dictRef="cc:jobtime">
<scalar dataType="xsd:string">PT79418.100S</scalar>
</property>
<property dictRef="cc:jobdatetime.end">
<scalar dataType="xsd:date">2025-04-17T21:50:11.000</scalar>
</property>
<property dictRef="cc:popanal">
<module cmlx:templateRef="l601.popanal">
<array dataType="xsd:double" dictRef="g:alphaocc" size="144">-19.18571 -19.12504 -14.34234 -14.33910 -14.33742 -14.33732 -10.31504 -10.30578 -10.22851 -10.21938 -10.21868 -10.21826 -10.21584 -10.21578 -10.21517 -10.21433 -10.21282 -10.21117 -10.20739 -10.20318 -10.19716 -10.19708 -10.19546 -10.19305 -10.19189 -10.19145 -10.19107 -10.19008 -10.18951 -10.18865 -10.18789 -10.18767 -10.18705 -10.18700 -10.18450 -10.18393 -10.18246 -10.18190 -10.13627 -3.69081 -2.02906 -2.02637 -2.01974 -1.10943 -1.02675 -0.95979 -0.94956 -0.94802 -0.94147 -0.85758 -0.81113 -0.80680 -0.79376 -0.78036 -0.77983 -0.76513 -0.75803 -0.75525 -0.75344 -0.73917 -0.73658 -0.73150 -0.72004 -0.70753 -0.67179 -0.64748 -0.64678 -0.63334 -0.62620 -0.60800 -0.59042 -0.58609 -0.57271 -0.57147 -0.56946 -0.56833 -0.54779 -0.54588 -0.54477 -0.52483 -0.52367 -0.51958 -0.51764 -0.50516 -0.49472 -0.49411 -0.49321 -0.47006 -0.46083 -0.45133 -0.44692 -0.44153 -0.44075 -0.43698 -0.43254 -0.42839 -0.42543 -0.42363 -0.42310 -0.42273 -0.42182 -0.41996 -0.41543 -0.41314 -0.41100 -0.40803 -0.40108 -0.39825 -0.39466 -0.39305 -0.39282 -0.38811 -0.38537 -0.38276 -0.38187 -0.37629 -0.37481 -0.36706 -0.36576 -0.36470 -0.35771 -0.35690 -0.35110 -0.34119 -0.33754 -0.32284 -0.31736 -0.31549 -0.31159 -0.29002 -0.28336 -0.28049 -0.27720 -0.27415 -0.27170 -0.25404 -0.25262 -0.24790 -0.23654 -0.21371 -0.20077 -0.19859 -0.19660 -0.18856</array>
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<module cmlx:templateRef="l601.state">
<scalar dataType="xsd:string" dictRef="g:l601.state">1-A.</scalar>
</module>
<module cmlx:templateRef="mulliken">
<module cmlx:templateRef="l601.mullik">
<scalar dataType="xsd:string" dictRef="g:title">Mulliken charges:</scalar>
<scalar dataType="xsd:integer" dictRef="cc:serial">1</scalar>
<list cmlx:templateRef="row">
<array dataType="xsd:integer" dictRef="cc:serial" size="69">1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69</array>
<array dataType="xsd:string" dictRef="cc:elementType" size="69">N N N N C C C C C C C C C C C C C C C C C C C C H H H H H H H H H H H H Ir C H H H C C C C C H C H C H H C O O C H C H H H C H H H C H H H</array>
<array dataType="xsd:double" dictRef="x:charge" size="69">-0.293103 -0.300238 -0.299035 -0.297117 0.174746 0.001688 -0.003618 0.164600 -0.042069 0.182429 0.007852 0.000437 0.170722 -0.059263 0.135809 -0.005784 -0.006770 0.149006 -0.076262 0.152706 -0.009606 0.000041 0.169931 -0.050216 -0.032137 -0.028933 -0.036878 -0.027912 -0.030024 -0.036880 -0.027836 -0.029502 -0.039178 -0.030967 -0.031433 -0.040177 0.316740 -0.020932 0.041126 0.032290 0.033391 -0.242339 0.016435 0.034280 0.042385 -0.014512 -0.000490 -0.029658 -0.021277 -0.028645 -0.033088 -0.037363 0.303308 -0.182135 -0.272251 -0.125873 0.121579 0.118915 0.028296 0.039129 0.047204 0.103836 0.033133 0.033304 0.053780 0.078947 0.011585 0.027740 0.016130</array>
</list>
<scalar dataType="xsd:double" dictRef="x:chargesum">-0.00000</scalar>
</module>
</module>
</module>
</property>
<property>
<module cmlx:templateRef="l601.mullik">
<scalar dataType="xsd:string" dictRef="g:title">Mulliken charges with hydrogens summed into heavy atoms:</scalar>
<scalar dataType="xsd:integer" dictRef="cc:serial">1</scalar>
<list cmlx:templateRef="row">
<array dataType="xsd:integer" dictRef="cc:serial" size="40">1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 37 38 42 43 44 45 46 48 50 53 54 55 56 58 62 66</array>
<array dataType="xsd:string" dictRef="cc:elementType" size="40">N N N N C C C C C C C C C C C C C C C C C C C C Ir C C C C C C C C C O O C C C C</array>
<array dataType="xsd:double" dictRef="x:charge" size="40">-0.293103 -0.300238 -0.299035 -0.297117 0.174746 -0.030449 -0.032551 0.164600 -0.078947 0.182429 -0.020060 -0.029587 0.170722 -0.096143 0.135809 -0.033620 -0.036272 0.149006 -0.115440 0.152706 -0.040573 -0.031392 0.169931 -0.090393 0.316740 0.085875 -0.120761 0.016435 0.033790 0.021107 -0.047599 -0.067021 -0.028645 0.303308 -0.182135 -0.272251 -0.125873 0.233545 0.224053 0.134403</array>
</list>
<scalar dataType="xsd:double" dictRef="x:chargesum">-0.00000</scalar>
</module>
</property>
<property>
<module cmlx:templateRef="l601.polariz">
<array dataType="xsd:double" dictRef="g:l601.pol.exact" size="6">577.817 -14.518 523.120 61.879 10.054 340.179</array>
<array dataType="xsd:double" dictRef="g:l601.pol.approx" size="6">1242.645 -56.166 1266.145 242.084 64.983 638.477</array>
</module>
</property>
<property dictRef="cc:frequencies">
<module cmlx:templateRef="l716.forcematrix">
<module cmlx:templateRef="lowfreq">
<array cmlx:templateRef="lowfreq" dataType="xsd:double" dictRef="g:1716.lowfreq" size="9">-593.5000 -4.8238 -2.5436 0.0003 0.0003 0.0005 1.6623 9.8423 18.7628</array>
</module>
<module cmlx:templateRef="l716.freq.chunkx" dictRef="cc:vibrations" id="default">
<array dataType="xsd:integer" dictRef="x:serial" size="201">1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200 201</array>
<array dataType="xsd:string" delimiter="|" dictRef="cc:irrep" size="201">A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A|A</array>
<array dataType="xsd:double" dictRef="cc:frequency" size="201">-593.4999 9.8225 18.7619 41.0291 50.0249 60.4227 63.6433 69.7566 80.5400 83.0125 90.1510 99.1751 100.3120 115.8360 149.3828 152.1072 161.6181 164.3791 169.7254 177.1829 179.8157 180.7356 214.4556 217.9241 225.1086 244.3720 247.1054 270.6899 280.1814 289.6243 293.3383 294.9982 298.9950 324.4840 334.7380 348.6618 380.0794 382.8960 390.8179 390.9442 405.1757 407.9969 411.5433 412.2627 419.3478 428.3726 442.5430 443.6349 444.9446 471.6239 487.7063 494.7307 509.1453 544.7562 578.1667 606.3248 652.5588 681.5694 682.1146 688.6469 689.6828 697.4537 706.4819 722.9718 723.2591 730.2643 735.1099 739.4955 762.1245 763.7374 766.5607 777.8797 793.1108 796.7606 798.0279 804.7493 806.1545 820.2018 822.2800 823.7739 836.6344 838.0936 846.5968 852.7596 862.0962 874.1928 877.2641 884.3150 885.5031 886.0222 892.8708 929.2835 932.3660 933.5173 934.7365 937.6084 941.0829 974.4125 987.2858 999.1118 1005.3050 1017.6566 1033.8129 1034.2161 1041.6131 1042.4101 1043.5473 1044.3794 1049.6478 1058.3905 1059.6352 1064.8963 1069.9409 1074.8553 1075.2648 1080.3922 1083.6349 1142.3571 1173.8075 1178.1106 1183.2981 1183.6359 1202.2577 1214.4938 1222.7313 1242.9968 1244.4272 1257.7504 1267.8980 1292.5388 1294.0550 1311.4195 1325.0979 1339.5103 1347.8581 1351.2218 1365.0120 1368.6834 1375.3737 1391.4111 1395.4128 1396.8358 1400.2759 1411.4167 1428.4794 1432.4068 1434.8933 1436.1754 1437.3074 1441.2023 1443.3405 1443.8040 1459.7662 1460.3767 1462.8951 1468.8256 1496.2910 1501.2521 1503.4344 1536.6774 1542.3592 1543.1384 1588.6185 1591.8334 1610.9724 1611.5905 1624.5311 1630.7693 1644.2260 1668.9345 1674.6189 1876.8766 1991.5125 3013.7522 3021.6835 3024.3283 3032.1252 3091.1519 3113.8472 3116.1038 3119.4598 3122.2921 3124.8380 3157.4156 3170.6725 3173.3638 3191.9701 3192.1163 3194.4774 3194.6393 3197.3385 3198.7996 3217.9182 3226.9356 3227.1366 3228.8118 3230.3201 3245.7899 3246.3675 3247.9553 3249.4933</array>
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